Homogeneous titanium tungsten alloys produced by powder metal technology

a technology of titanium tungsten and powder metal technology, which is applied in the field of homogeneous titanium tungsten alloys and metal matrix composites, can solve the problems of only incremental improvement of specific properties of alloys, ti-6al-4v becomes difficult to fabricate, and the ductility is drastically lowered, so as to achieve high ductility and high strength. , the effect of high strength

Inactive Publication Date: 2008-02-07
DYNAMET TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0010] The present disclosure describes a method of making a heat treatable titanium base alloy that possesses combinations of properties that make them highly desirable. For example, in one embodiment of the invention there is described an alloy comprising titanium and 9 to less than 20% by weight of tungsten, wherein the alloy exhibits a yield strength of at least 120,000 psi and a ductility of at least 20% elongation. Applications for these highly ductile alloys include th...

Problems solved by technology

Early commercial titanium alloying elements Fe, Mn, and Cr improved strength but drastically lowered the ductility.
Although several later alloys were developed, such alloys achieved only incremental improvements in specific properties such as higher elevated strength, better weldability or improved fatigue strength.
For many metal working processes such as sheet bending, cold drawing and the manufacture of foil and thin wall tubing (e.g. aircraft hydraulic tubing), even Ti-6Al-4V becomes difficult to fabricate.
In this way the ductility is improved but at a significant sacrifice of strength.
However this heavy metal element caused severe segregation problems when incorporated in the ingot melting tec...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

Ti-15% W

[0052] A powder metallurgy (P / M) technique was used to produce a Ti-15% W alloy. The P / M process involved combining the tungsten and titanium powder by blending a titanium containing powder with a tungsten containing powder to form a blended powder comprising 15% by weight of tungsten powder. The blended powder was compacted by Cold Isostatic Pressed (CIP) at 379 MPa (55 ksi), to a density of approximately 85%. The compact was then consolidated to about 95% density by vacuum sintering at 1200° C. (2250° F.) for 150 minutes to a closed porosity ranging from 94-96% density. Next, the nearly dense material was subjected to hot isostatic pressing (HIP) at 899° C. (1650° F.) for 2 hours in argon gas at a pressure of 103 MPa (15 ksi), which produced the fully dense material.

[0053] The consolidated material was next hot worked by extrusion. The hot worked material was next subjected to a heat treatment at 1450° F. for 4 hours to develop the final product having the properties sho...

example 2

Ti-6Al-4V with an Addition of 15% W

[0056] A Ti-6Al-4V with an addition of 15% W was produced according to the following process. A titanium containing powder was blended with tungsten, Al and V containing powders to form a blended powder. The blended powder contained 15% by weight of tungsten, 4 to 6% Al and 3 to 4% V. The blended powder was compacted and consolidated to full density by the process described in Example 1.

[0057] The consolidated material was next hot worked by extrusion. The hot worked material was next subjected to a heat treatment at 2100° F. for 24 hours to develop the final product having the properties shown in Table 2.

TABLE 2UltimateTensileYieldElon-ReductionStrengthStrengthgationin Area(psi)(psi)(%)(%)Ti—15W—5.2Al—3.5V212,100196,000524AlloyTi—3Al—8V—6Cr—4Mo—4Zr210,000200,0007—

[0058] As shown in Table 2, after hot working, the Ti-6Al-4V with 15% W (Ti-15W-5.2Al-3.5V) alloy exhibited an ultimate tensile strength of 210,000 psi with useful ductility above 2%....

example 3

Ti-6Al-4V with an Addition of 15% W and 7.5% TiC

[0059] A hard, wear resistant alloy composite was produced by adding 7.5% TiC ceramic particles to the Ti-15W-5.2Al-3.5V described above, e.g., a Ti-6Al-4V with additions of 15% W and 7.5% TiC. The blended powder was compacted and consolidated to full density by the process described in Example 1.

[0060] The consolidated material was next hot worked by extrusion. The hot worked material was next subjected to a heat treatment at 1450° F. for 4 hours cooling and then heating at 950° F. for 4 hours to produce the final product having the properties shown in Table 3.

TABLE 3HardnessUTS (psi)YS (psi)EL (%)RA (%)RcTi—15W—4.8Al—3.2V—7.5TiC200,500188,0000.87.848

[0061] The resulting alloy, Ti-15W4.8Al-3.2V-7.5TiC, exhibited exceptional strength. After hot working and heat treatment this composite has an ultimate tensile strength of over 200,000 psi and a remarkably high hardness for a titanium alloy (Rc=48).

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Abstract

The present disclosure is related to homogeneous alloys comprising titanium and 9% to less than 20% by weight of tungsten, wherein the alloy has a yield strength of at least 120,000 psi and ductility of least 20% elongation; and with further alloying an ultimate tensile strength of at least 200,000 psi and useful ductility of at least 2% elongation; and with the addition of ceramic particulate reinforcements can exhibit an ultimate tensile strength of at least 180,000 psi. Products and metal matrix composites comprising such homogeneous alloys are also disclosed. The metal matrix composites further comprise a discontinuous reinforcement chosen from TiC, TiB2, or TiB, particles or combinations of such particles. Method of making such alloys and composites as well as products made from such alloys and composites are also disclosed.

Description

[0001] This application claims the benefit of priority to provisional application 60 / 772,896, filed Feb. 14, 2006, which is herein incorporated by reference in its entirety.[0002] Disclosed herein are homogeneous titanium-tungsten alloys and metal matrix composites having highly desirable properties. Also disclosed are methods of making such alloys and composites, as well as products comprising such alloys and composites. [0003] Titanium metal has typically been alloyed with other metallic elements to increase the tensile strength over the pure metal. Early commercial titanium alloying elements Fe, Mn, and Cr improved strength but drastically lowered the ductility. Good ductility is desired in the typical component both to be formable (malleable) enough to produce the final shape by metalworking and to possess sufficient fracture resistance to deformation for use in the end-use application. [0004] With the development of the Ti-6Al-4V alloy (U.S. Pat. No. 2,906,654), which is herein...

Claims

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Application Information

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IPC IPC(8): C22C14/00B22F3/02B22F3/15C22F1/16B22F3/24
CPCB22F3/02B22F2998/10C22C1/0458B22F2301/205B22F3/10B22F3/12B22F3/15C22C14/00C22C32/0047B22F1/0003B22F3/04B22F3/20B22F3/18B22F3/17A61L27/06A61L31/022B22F1/09
Inventor ABKOWITZ, STANLEYABKOWITZ, SUSAN M.FISHER, HARVEYSCHWARTZ, PATRICIA J.
Owner DYNAMET TECH
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