Process and System for the Addition of Promoter Metal In Situ in a Catalytic Reforming Unit

a technology of catalytic reforming unit and promoter metal, which is applied in the direction of catalyst regeneration/reactivation, thermal naphtha reforming, physical/chemical process catalysts, etc., can solve the cost of replacing a large volume of catalyst, and achieve the effect of improving the selectivity of catalyst particles, improving the activity of catalyst particles, and improving the conversion rate of hydrocarbon feed

Inactive Publication Date: 2010-05-13
UOP LLC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Benefits of technology

[0005]One exemplary embodiment can be a process for adding a promoter metal catalyst component in situ in a catalytic naphtha reforming unit. The process can include introducing a compound comprising the promoter metal catalyst component to the catalytic reforming process under conditions to effect deposition of the promoter metal onto the catalyst particle and improve a conversion of a hydrocarbon feed. Selectivity of the catalyst particle may be improved, activity of the catalyst particle may be improved, deactivation of the catalyst particle may be reduced, undesired coking behavior of the catalyst particle may be reduced, or any combination of the above.

Problems solved by technology

Generally, one drawback of replacing an existing catalyst with a new catalyst is the cost of replacing a large volume of catalyst, especially if the existing catalyst is not at its useful end of life.

Method used

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  • Process and System for the Addition of Promoter Metal In Situ in a Catalytic Reforming Unit

Examples

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example

[0055]200 cc of a fresh commercial continuous regeneration catalyst comprising Pt, Sn, and Cl on gamma alumina was loaded into a quartz reactor in four beds containing 50 cc each of the catalyst. The beds were numbered sequentially with Bed 5 located nearest to the top of the reactor, and bed 2 located nearest to the bottom of the reactor. The beds were separated by quartz wool. At the bottom of the reactor, in bed 1, a bed of 200 cc of the gamma alumina support was loaded. The initial indium levels of the catalyst and of the support were zero wt. %. Spacers were located above the top bed.

[0056]A regeneration procedure was conducted in the reactor. The steps of the regeneration procedure included (1) a heat up period in air ramping the temperature from ambient to 510° C. at 1.4° C. / min. (2) introduction of Cl2 and a HCl-containing solution as described below, during an oxychlorination step for 8 hours at 510° C. (3) Cool down period with full air to reach 93° C. (4) a reheat / ramp pe...

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Abstract

One exemplary embodiment can be a process for facilitating adding a promoter metal to at least one catalyst particle in situ in a catalytic naphtha reforming unit. The process can include introducing a compound comprising the promoter metal to the catalyst naphtha reforming unit and adding an effective amount of the promoter metal from the compound comprising the promoter metal to the catalyst particle under conditions to effect such addition and improve a conversion of a hydrocarbon feed.

Description

FIELD OF THE INVENTION[0001]The field of this invention generally relates to a process for conversion of hydrocarbons in a catalytic reforming unit.DESCRIPTION OF THE RELATED ART[0002]Numerous hydrocarbon conversion processes can be used to alter the structure or properties of hydrocarbon streams. Generally, such processes include: isomerization from straight chain paraffinic or olefinic hydrocarbons to more highly branched hydrocarbons, dehydrogenation for producing olefinic or aromatic compounds, dehydrocyclization to produce aromatics and motor fuels, alkylation to produce commodity chemicals and motor fuels, transalkylation, and others.[0003]Typically such processes use catalysts to promote hydrocarbon conversion reactions. As the catalysts deactivate, it is generally desirable to regenerate them and / or add new catalyst to improve yields and profitability.[0004]Various catalysts and processes have been developed to convert hydrocarbons. Often, such processes require periodic reg...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C10G35/06
CPCC10G35/06C10G35/085B01J38/02B01J38/10B01J38/44B01J38/48B01J38/60B01J23/08B01J27/13B01J27/32C10G2300/1044C10G2300/70C10G35/12C10G35/02
Inventor LAPINSKI, MARK P.ROSIN, RICHARD R.SCHREIER, MARC R.
Owner UOP LLC
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