The invention discloses a
rosin-base half alicyclic
polyamide imide copolymer and a synthetic method thereof. According to the invention,
maleopimaric acid dianhydride, 11- amino undecanoic acid and (1, 6) -hexanediamine, which are prepared by taking gum
rosin and
castor oil as raw materials, are added into stirring
polymer reactor together, and the
polymer reactor is vacuumized and then fed with
inert gases; the
polymer reactor is heated hermetically, the stirring rate of the polymer reactor is adjusted, then reactants are thermal insulated and pressurized, and the polymer reactor is released to normal pressure; the polymer reactor is heated once more, the stirring rate of the polymer reactor is adjusted, the polymer reactor is vacuumized continuously after reaching the constant temperature, the reaction is over, and the
copolymer is obtained. The synthetic method disclosed by the invention is based on the fusion
polymerization principle, and no
organic solvent is used during the whole
polymerization process, therefore, additional steps for recovering the
organic solvent are avoided, and hazards on the
human body and the environement are prevented. The polymerized
polyamide imide copolymer has good
thermal resistance, high-temperature rigidity, size stability and low water absorption, and can be applied to
engineering plastics, membrane materials and the like.