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36results about How to "Aggregation condition reached" patented technology

Semi-aromatic polyamide and synthesis method thereof

ActiveCN105348520AImprove mechanical properties and heat resistanceLow water absorptionPolyamideSynthesis methods
The invention relates to semi-aromatic polyamide and a synthesis method thereof. The semi-aromatic polyamide has the structure shown in the formula I (shown in the description); in the formula I, a is equal to 10-200, b is equal to 10-200, c is equal to 10-100 and R is polyesteramide. The semi-aromatic polyamide has a relatively high mechanical property, relatively high heat resistance, low water absorption, excellent processability and biologically-derived characteristics, and can be applied to the fields of electronics and electrical appliances, LEDs, automobiles, aerospace, military and the like.
Owner:ZHONGBEI UNIV

Bio-based long-carbon-chain semi-alicyclic polyamide-imide PA10I and synthesizing method thereof

The invention discloses a synthesizing method for bio-based long-carbon-chain semi- alicyclic polyimide-imide. Maleopimaric acid acyl chloride and 1,10-decamethylene diamine respectively made of gum rosin and castor oil as raw materials are put into a stirring-type polymerization reaction container; inert gases are fed after the stirring-type polymerization reaction container is vacuumized; the polymerization reaction container is heated hermetically; after the stirring speed of the polymerization reaction container is adjusted, the reactants are thermally insulated and pressurized, and the gases are discharged so as to obtain ordinary pressure; the polymerization reaction container is heated again, the stirring speed of the polymerization reaction container is adjusted, and the polymerization reaction container is continually vacuumized after constant temperature is obtained; and the bio-based long-carbon-chain semi-alicyclic polyimide is obtained after the reaction is over. The synthesizing method of the invention is based on the principle of melt polycondensation and the whole synthesis process does not require any organic solvent, so that no additional steps to recover organic solvent are needed , and no toxin or harm is generated to people and the environment. The synthesized polyamide-imide PA10I has the advantages of good heat resistance, high-temperature rigidity, dimensional stability and low water absorption. The polyamide-imide PA10I can be used for engineering plastics or film materials and the like.
Owner:SINOPLAST NEW MATERIAL

Rosin-base half alicyclic polyamide imide copolymer and synthetic method thereof

The invention discloses a rosin-base half alicyclic polyamide imide copolymer and a synthetic method thereof. According to the invention, maleopimaric acid dianhydride, 11- amino undecanoic acid and (1, 6) -hexanediamine, which are prepared by taking gum rosin and castor oil as raw materials, are added into stirring polymer reactor together, and the polymer reactor is vacuumized and then fed with inert gases; the polymer reactor is heated hermetically, the stirring rate of the polymer reactor is adjusted, then reactants are thermal insulated and pressurized, and the polymer reactor is released to normal pressure; the polymer reactor is heated once more, the stirring rate of the polymer reactor is adjusted, the polymer reactor is vacuumized continuously after reaching the constant temperature, the reaction is over, and the copolymer is obtained. The synthetic method disclosed by the invention is based on the fusion polymerization principle, and no organic solvent is used during the whole polymerization process, therefore, additional steps for recovering the organic solvent are avoided, and hazards on the human body and the environement are prevented. The polymerized polyamide imide copolymer has good thermal resistance, high-temperature rigidity, size stability and low water absorption, and can be applied to engineering plastics, membrane materials and the like.
Owner:SINOPLAST NEW MATERIAL

Semi-aromatic transparent polyamide and synthesis method thereof

ActiveCN105482102AReduced crystallization abilityImprove notched impact strength and antistatic abilityPolyamideOptical instrument
The invention discloses a semi-aromatic transparent polyamide and a synthesis method thereof. The semi-aromatic transparent polyamide has a structure shown in a formula I, wherein a equals to 10-100, b equals to 10-200, c equals to 10-100, d equals to 10-100, and R is a polyester amide. The semi-aromatic transparent polyamide has high mechanical properties and transmittance, low water absorption and excellent processing performance, can be applied in the mechanical parts around the fuel oil, electrical and mechanical components, precision optical instruments, pressure-resistant windows, viewers, special light fixture housing, food packaging films, and high-end sports equipment.
Owner:ZHONGBEI UNIV

Rosin-based semi-alicyclic polyamide-imide PA6I and synthesizing method thereof

The invention discloses a synthesizing method for rosin-based semi-alicyclic polyamide-imide PA6I. Maleopimaric acid acyl chloride is prepared by using gum rosin as raw materials, and the maleopimaric acid acyl chloride is dried through vacuumization; the dried maleopimaric acid acyl chloride and 1,6-hexanediamine are put into a stirring-type polymerization reaction container, and inert gases are fed after the stirring-type polymerization reaction container is vacuumized; the polymerization reaction container is heated hermetically; after the stirring speed is adjusted, the polymerization reaction container is thermally insulated and pressurized, and the gases are discharged so as to obtain ordinary pressure; and under ordinary pressure, the polymerization reaction container continues to be heated, the stirring speed is adjusted, and the polymerization reaction container is continually vacuumized after constant temperature is obtained; and the rosin-based semi-alicyclic polyamide-imidePA6I is obtained after the reaction is over. The rosin-based semi-alicyclic polyamide-imide produced by the invention is environment-friendly material, and has the advantages of good heat resistance, high-temperature rigidity, dimensional stability, and low water absorption; the preparation technique is simple, and the polymerization process is convenient, so that control and industrialization are easily achieved; and the synthesizing process is melt polycondensation with no organic solvent and no danger to people and the environment.
Owner:SINOPLAST NEW MATERIAL

Rosin-based semi-alicyclic polyamide-imide PA6I and synthesizing method thereof

The invention discloses a synthesizing method for rosin-based semi-alicyclic polyamide-imide PA6I. Maleopimaric acid acyl chloride is prepared by using gum rosin as raw materials, and the maleopimaric acid acyl chloride is dried through vacuumization; the dried maleopimaric acid acyl chloride and 1,6-hexanediamine are put into a stirring-type polymerization reaction container, and inert gases are fed after the stirring-type polymerization reaction container is vacuumized; the polymerization reaction container is heated hermetically; after the stirring speed is adjusted, the polymerization reaction container is thermally insulated and pressurized, and the gases are discharged so as to obtain ordinary pressure; and under ordinary pressure, the polymerization reaction container continues to be heated, the stirring speed is adjusted, and the polymerization reaction container is continually vacuumized after constant temperature is obtained; and the rosin-based semi-alicyclic polyamide-imidePA6I is obtained after the reaction is over. The rosin-based semi-alicyclic polyamide-imide produced by the invention is environment-friendly material, and has the advantages of good heat resistance, high-temperature rigidity, dimensional stability, and low water absorption; the preparation technique is simple, and the polymerization process is convenient, so that control and industrialization are easily achieved; and the synthesizing process is melt polycondensation with no organic solvent and no danger to people and the environment.
Owner:广东中塑新材料股份有限公司

Bio-based long carbon chain transparent polyamide and synthetic method thereof

ActiveCN105348517AReduced crystallization abilityImprove notched impact strength and antistatic abilityChemistryPolyester
The invention discloses bio-based long carbon chain transparent polyamide and a synthetic method thereof. The bio-based long carbon chain transparent polyamide adopts the structure in the formula I (shown in the description), wherein a=10-200, b=10-200, c=10-100 and R is polyesteramide. The bio-based long carbon chain transparent polyamide is relatively high in mechanical property and light transmittance, low in water absorption, and excellent in processability, has the biogenetic derivation property, and can be applied to the fields of fuel and oil surrounding mechanical parts and electric mechanical parts, precise optical instruments, pressure-resistant windows, observation mirrors, special lamp shades, food packaging films, high-grade sport instruments and the like.
Owner:ZHONGBEI UNIV

Biological based long-carbon-chain semi-alicyclic polyamidoimide copolymer and synthetic method of copolymer

The invention discloses a biological based long-carbon-chain semi-alicyclic polyamidoimide copolymer and a synthetic method of the copolymer. Gum rosin and castor oil are used as raw materials, maleopimaric acid anhydride, 1,10-decamethylene diamine and 11-aminoundecanoic acid are respectively prepared and are added into a stirring type polymerization reactor, and inert gas is introduced after vacuum pumping; the polymerization reactor is sealed for heating, the stirring speed of the polymerization reactor is regulated, reactants are subjected to heat insulation and pressure maintaining, and the air is released to normal pressure; and then, the polymerization reactor is heated, the stirring speed of the polymerization reactor is regulated, and the continuous vacuum pumping is carried out after the temperature is constant, and the copolymer is obtained after the reaction completion. The synthetic method disclosed by the invention is based on the melt polymerization principle, any organic solvent is not needed in the whole synthetic process, so additional steps for recovering the organic solvents are not needed, and in addition, no toxicity is generated on human bodies and environment. The synthetic polyamidoimide copolymer has good heat resistance performance, high-temperature rigidity, dimension stability and low water absorption rate and can be used for engineering plastics or film materials and the like.
Owner:深圳市中塑新材料有限公司
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