48results about How to "The polymerization process is controllable" patented technology

The invention discloses a novel biological pollution-resistant polyamide reverse osmosis composite membrane and a preparation method thereof. The preparation method comprises carrying out graft modification on a polyamide reverse osmosis membrane through atom transfer radical polymerization (ATRP), carrying out sterilization particle loading to obtain a reverse osmosis composite membrane with bioattachment resistance and antibacterial properties. The reverse osmosis composite membrane polymerization process is carried out at the room temperature and has high controllability. The reverse osmosis composite membrane can be conveniently and fast prepared, has stable performances, effectively improves use efficiency and a use life and reduces a seawater desalination cost.

The invention relates to an acrylics / SiO2 nano-composite tanning agent. The nano-composite tanning agent appears to be light yellow or yellow semitransparent ropy liquid, the mass concentration is 20 to 35%, the viscosity is 500 to 1000MPa.s, the pH value is 5 to 8, and the storage stable period is over 12 months. With only 2% (relative to the leather weight) chromium powder, the nano-composite tanning agent can thicken the leather by 124.5%, the shrinkage temperature reaches to 95 DEG C.; compared with a chrome tanned leather, a leather tanned by the nano-composite tanning agent has a tensile strength, peeling strength and elongation at break improved by 51.8%, 8.2% and 13.3% respectively, has no obvious stratification or sedimentation during over 12 months of storage period. Water is used as solvent when prepared, which is low-cost and pollution-free; the preparing technology is simple, the reaction is mild, the polymerization process is easy to control, so that the nano-composite tanning agent is easy to realize industrial production, the synthesized material is inexpensive and easy to obtain as well.

The invention discloses a long carbon-chain semi-aromatic polyamide and preparation method of the same. The long carbon-chain semi-aromatic polyamide has good heat resistance, rigidity at high temperature, chemical resistance and size stability, and low water absorption. The synthetic method of the invention comprises: first, adding dried diamine monomer, 11-aminoundecanoic acid, and terephthalic acid into a stirred polymerization reactor according to a certain mol ratio, after vacuum-pumping, feeding in inert gas, heating the reactor hermetically to 120-170 DEG C, and maintaining the temperature and the condition of self pressure for the reactants for 0.5-24 hours before venting to normal pressure; and then reheating to 300-350 DEG C, and keeping vacuum-pumping after reaching the constant temperature. The polyamide of the invention is simple in preparation technology, controllable in polymerization process, and can replace steels by being applied to the fields such as automobiles, machinery, and electronic and electrical equipment.

The invention relates to a method for synthesizing polyaspartic acid by maleic anhydride and ammonia gas. The method comprises the following steps: performing substitution reaction of molten maleic anhydride and ammonia gas in a closed reactor and absorbing the residual gas after the completion of the substitution reaction; adding sodium hydrate solution into the reacted maleic anhydride and ammonia gas to perform neutrallzation reaction, so as to obtain a mixture of maleamic acid sodium and maleamic acid ammonium; directly heating the product in the closed reactor and performing condensation polymerization by stirring; steaming and drying the moisture after the completion of the condensation polymerization, so as to obtain the polysuccinimide solid; adding water in another reaction kettle and starting stirring; then adding the polysuccinimide solid into the reaction kettle and slowly adding sodium hydrate solution and heating to perform hydrolysis reaction, so as to obtain the polyaspartic acid solution. According to the method for synthesizing polyaspartic acid by maleic anhydride and ammonia gas, the production process is simplified and the polyaspartic acid prepared according to the method has a weight-average molecular weight of 2000-15000 and a molecular weight distribution index of 1.5-1.65, so that molecular weight requirements of various application domains are met and environment-friendly production process is realized.

The invention discloses a function prepolymer and a preparation method and application thereof. The function prepolymer is a butyl acrylate polymer and prepared from a monomer, modified matter and an emulsifying agent through emulsion polymerization. A synthetic thickener, liquid disperse dye and the function prepolymer are mixed with water and evenly stirred to obtain printing paste; printing and drying of a polyester fabric are achieved through the obtained printing paste on a rotary screen printing machine or a mobile screen printing machine, then high-temperature processing is carried out on a tentering heat setting machine, and a printed polyester fabric is obtained. According to the technical scheme, the printing process is short, the hand feeling of the fabric is soft, postprocessing is not needed, a large amount of water and energy are saved, almost no wastewater is drained, processing equipment is conventional, and the printing processing technology is environmentally friendly.

The invention discloses a preparation method of polyester-polycarbonate-polyester multi-block copolymer and belongs to the technical field of high molecular materials. The preparation method comprises the steps that a multi-block polymerization is completed through a 'one-pot method', in another word, a Bronsted acid catalyst sequentially catalyzes cyclic lactone and cyclic carbonate for achieving ring opening polymerization, then a preset amount of tertiary amine R<3>N which is excessive relative to acid is input, wherein conjugate acid R<3>N<+>-H<delta+> formed by alkali which is equal to acid in a system in proton number serves as a hydrogen bond donor, spare alkali serves as a hydrogen bond receptor, ring opening polymerization of lactide which is finally input is catalyzed in a bifunctional mode, and the polyester-polycarbonate-polyester triple-block copolymer is finally synthesized. The preparation method has the advantages that the catalyst is simple in structure and easy to obtain, the reaction is mild and high in efficiency, the 'one-pot method' is easy and convenient to operate, the whole polymerization reaction exhibits active characteristics, the polymer molecular weight is controllable, and molecular weight distribution is narrow.

The invention relates to a multi-responsive polymer nanocarrier with a rapid cell penetrating characteristic. The nanocarrier is formed by self-assembling of a multi-responsive amphipathic triblock copolymer, the nanocarrier adopts an onion structure sequentially comprising an acid-responsive PLLA core, cyanine molecules with a near infrared absorption characteristic, a hydrogen-peroxide-responsive PPI (polyphenyl isocyanide) intermediate layer and a left-handed spiral hydrophilic PPI hydrophilic chain from inside to outside sequentially, wherein the structure of the multi-responsive amphipathic triblock copolymer is shown in the general formula in the specification, R1 is a group with stimulation responsiveness, and R2 is a chiral PEG hydrophilic chain; x ranges from 20 to 50, y ranges from 20 to 50, and z ranges from 30 to 80. The multi-responsive polymer nanocarrier can be used for transporting hydrophobic dye molecules and medicine molecules, can rapidly and efficiently penetrate cell membranes, has multiple stimuli-responsiveness, realizes programmable controlled release of medicines and has a chemical-photothermal collaborative treatment characteristic.

The invention relates to a synthesizing method of cross-linked zinc polyacrylic acid and a representative using method of the cross-linked zinc polyacrylic acid, in particular to a synthesizing method of reticular cross-linked zinc polyacrylic acid and a using method of the cross-linked zinc polyacrylic acid in batteries. According to the synthesizing method, acrylic acid serves as a monomer, zinc oxide serves as a neutralizing agent, and synthesizing of the reticular cross-linked zinc polyacrylic acid is achieved in an aqueous system under the action of a cross-linking agent and a one-component initiator. A synthesized product is used for replacing an anode active material of a nickel-zinc secondary battery, in this way, the representative using method of the cross-linked zinc polyacrylic acid is achieved, and the practicability of the cross-linked zinc polyacrylic acid in improving low-temperature power performance and self-discharge control of a nickel-zinc rechargeable battery and the like is achieved. A reference is provided for application of the cross-linked zinc polyacrylic acid in silver-zinc batteries, MnO2-zinc batteries, Edison batteries and the like. The polymerization method has the advantages of being short in process, easy to operate, high in safety, low in product cost and the like, and a basis is laid for application of the synthesized product in the fields such as non-toxic preservation of potatoes, efficient utilization of feminine sanitary towels, green mildew preventives for leather, micro-element fertilizers and accelerants.

A core-shell polymer of acrylate with high adhesive between core and shell for modifying polyvinyl chloride features that the alkyl acrylate is used as its core, methyl methylacrylate is used as its shell, and the alkyl acrylate-methyl methylacrylate is used to link core with shell.

The invention provides a reaction type dispersing agent and a preparation method for the polyacrylamide water emulsion. The method for preparing the water emulsion comprises the steps of preparing the reaction type dispersing agent; balancing the concentration of free radicals by multiple sections of composite initiating systems under the participation of a saline solution system and the dispersing agent, and performing water emulsion dispersing polymerization on acrylamide and cationic monomers. The water emulsion product can be quickly dissolved, has a high molecular weight, is high in flowability and high in stability and can be widely applied to the field of water treatment of all industries.

This invention relates to elasticity styrene - acrylate waterproof latices and its preparation method. It is polymerized by nine kind component and seed emulsion. The preparation method includes as follows steps: whip, vacuumize, whip, polymerization, thermal insulation, cooling, thermal insulation, cooling, filter, casing. This invention has low cost, stable color phase, moderate consistency, good acid and alkaline protection, and lower vitrification point. It can effectively eliminate liberation monomer, avoid enviroment pollution. This invention especially fit for cement group polymer waterproof, waterproofing work as well as impervious seal stuff.

The purpose of the invention to provide a polymeric acid solution thickener. The thickener has excellent resistance to a high temperature and shearing, and can meet high temperature and deep well construction requirements. The ternary copolymeric acidified fracturing thickener obtained in the invention can be used for thickening an acid solution with the hydrochloric acid concentration of 5-28%, the apparent viscosity of the thickener at room temperature is 100 mPa.s or above, the viscosity retention rate at 90 DEG C still reaches 60% or above, the viscosity at 110 DEG C can still reach 30 mPa. s or above, and the thickener has good thickening and temperature resisting performances. Compared with conventional preparation technologies, a technology disclosed in the invention has the advantages of high production efficiency, simplicity, mild production conditions, easiness in control of the polymerization process, great reduction of the production cost, and easiness in industrial promotion; and the above product has the advantages of good solubility, convenience in transportation, and good application prospect.

The invention discloses a method for preparing mesoporous material through microwave-assisted loading of nanometer silver oxide. The method specifically includes the first step of preparing a solution A, the second step of preparing a solution B, the third step of carrying out primary dipping, the fourth step of carrying out deep dipping, and the fifth step of preparing the finished product. According to the method, granules containing Zn and Ag and the graphite oxide component are attached to the surface of the mesoporous material through microwave ultrasonic loading, metal ions and graphite oxide form a double-layer structure on the surface of the mesoporous material, the loss rate of graphite oxide is low, and thus cost is reduced; by the adoption of microwave-assisted loading, the method has the advantages that reaction conditions are mild, the reaction speed is high, and the yield is high; the pH value is regulated to be 5-6 with a hydrogen chloride solution, the loading capacity of metallic oxide is improved, and the dispersity of metallic oxide is good; a titanium dioxide catalyst is sprayed on the surface of the mesoporous material blow-dried with nitrogen, integration of the mesoporous material and the surface-loaded material is achieved, and the titanium dioxide catalyst is high in loading efficiency, makes the polymerization process easy to control, accelerates the reaction process and improves productivity.

The invention discloses L-carnitine molecularly imprinted microspheres with a core-shell structure and a preparation method thereof, and relates to the field of intelligent high polymer materials. According to the invention, L-carnitine is taken as a template molecule and methacrylic acid is taken as a functional monomer, and the L-carnitine molecularly imprinted microspheres with the core-shell structure are prepared through reversible addition-fragmentation chain transfer and free radical polymerization in combination with the surface molecular imprinting technology; the preparation method of the L-carnitine molecularly imprinted microspheres with the core-shell structure comprises the following steps of: 1, preparing nano SiO2 microspheres by a Stober method; 2, performing surface activation on the nano SiO2 microspheres; 3, performing surface benzylation on the nano SiO2 microspheres; 4, synthesizing an RAFT (Reversible Addition-Fragmentation Chain Transfer Polymerization) reagent on the surface of the nano SiO2 microspheres; 5, preparing the L-carnitine molecularly imprinted microspheres with the core-shell structure; and 6, eluting the imprinted template molecules. The L-carnitine molecularly imprinted microspheres with the core-shell structure has the advantages of simple process, low cost, convenience in industrial popularization and application, and the like; the obtained imprinted microspheres have good adsorbability and selectivity for L-carnitine molecules, and can be applied to separating out carnitine enantiomers.

The invention provides cationic polyacrylamide aqueous emulsion and a preparation method of cationic polyacrylamide aqueous emulsion. The method for preparing the aqueous emulsion comprises the steps of preparing a reaction type dispersing agent; and balancing the free radical concentration through a multistage complex initiation system under the participation of a salt liquid system and the dispersing agent, and carrying out dispersion polymerization of acrylamide and cationic monomer aqueous emulsion. The aqueous emulsion can be dissolved rapidly, has high molecular weight, good mobility and high stability, and can be widely applied to the water treatment fields of all industries.

The invention relates to thermotropic liquid crystal block polyarylate as well as preparation and application thereof. The polyarylate is shown as a general formula I. The single-component thermotropic liquid crystal block polyarylate is obtained by utilizing chemical activity difference control product combination of diphenol monomers, and has two glass transition temperatures. A high-temperature-resistant multi-shape memory material is prepared by utilizing a plurality of glass transition temperature, and is applied to the wider fields of aerospace, robots and the like.

The invention discloses a preparation method of a polyester-polycarbonate-polyester multi-block copolymer, belonging to the technical field of polymer materials. In the present invention, the multi-block polymerization is accomplished by the "one-pot method", that is, the Bronsted acid catalyst sequentially catalyzes the ring-opening polymerization of cyclic lactones and cyclic carbonates, and then puts in a preset relative acid excess tertiary amine (R3N: ), wherein the acid in the system forms the conjugate acid R3N+-Hδ+ of the base itself as a hydrogen bond donor, and the excess base acts as a hydrogen bond acceptor, and the bifunctional catalyzes the ring-opening of the lactide that is finally put into Polymerization to finally synthesize polyester‑polycarbonate‑polyester triblock copolymers. The invention has the following advantages: the structure of the catalyst is simple and easy to obtain, the reaction is mild and efficient, the "one-pot method" is easy to operate, the whole polymerization reaction is active, the molecular weight of the polymer is controllable and the molecular weight distribution is narrow.

The invention discloses a composite material of polyortho-methyl - acryloylamino -benzoic acid as luminopolymer and nano metal sulfide. The preparation method comprises: with polyortho-methyl - acryloylamino -benzoic acid as template and metal salt and sulfide as mateials, original generating nano metal oxide in liquid, and obtaining the said material. Wherein, the metal salt is selected one or more from zinc acetate, manganese chloride, copper acetate, nickel sulfate, cadmium nitrate, and silver acetate; the sulfide is selected from sodium sulfide or thioacetamide. This invention has potential application value.

The invention discloses a restricted access type chiral chromatography MC (monolithic column) as well as a preparation method and an application thereof. The preparation process of the restricted access type chiral chromatography MC comprises steps as follows: (1), a framework of the chromatography MC is prepared with an RATRP (reverse atom transfer radical polymerization) method; (2), beta-CD (beta-cyclodextrin) is modified on the framework of MC to serve as a chiral selector; (3),DATRP (direct atom transfer radical polymerization) is initiated by active sites on the surface of the framework of the MC, and a hydrophilic restricted access layer is grafted. The restricted access type chiral chromatography MC has the advantages that the MC can be applied to direct injection analysis of biological samples, has high stability and is suitable for quick separation analysis of chiral drugs.

The invention provides a preparation method of a degradable poly-alpha-olefin material with controllable olefin insertion rate, which comprises the following step: reacting cycloenone acetal, an alpha-diimine palladium catalyst, a nucleophilic reagent and alpha olefin under the irradiation of visible light to obtain the degradable poly-alpha-olefin material. According to the application, the cycloenone acetal and the alpha olefin are copolymerized by combining free radical ring-opening polymerization of the cycloenone acetal and coordination polymerization of the alpha olefin, and degradable units (ester bonds) are introduced into all copolymer carbon skeletons. The preparation method is mild in reaction condition, heating is not needed, and the olefin insertion rate can be adjusted in a wide range with the mass ratio of 23-71%. By means of the preparation method, the production cost can be effectively reduced, and environmental pollution caused by polyolefin is avoided.

The invention relates to a preparation method of biochar with multiple heavy metal Cd adsorption sites. The method comprises the following steps: firstly, selecting raw materials for preparing biochar, and preparing biochar at a certain cracking temperature; then immobilizing an atom transfer radical polymerization (ATRP) initiation site on the biochar by adopting a surface chemical modification method to obtain biochar rich in the ATRP initiation site on the surface; and finally, selecting a functional monomer with Cd adsorption sites, and carrying out ATRP controllable grafting to obtain the biochar with multiple heavy metal Cd adsorption sites on the surface. Compared with an existing biochar grafting method, the biochar prepared through the method has the advantages that the types and the number of heavy metal adsorption sites on the surface are large, and the types and the number of the adsorption sites can be freely regulated and controlled.

The invention relates to a polymer debonding agent for ceramic slurry with good grinding aid effect. The invention adopts an unsaturated monomer containing two carboxyl groups as an anionic monomer, which has better anchoring effect on ceramic clay ions and better degumming effect. Better and more efficient. The molecular structure of the debonding agent of the present invention contains a large number of diethanolamine groups with good grinding effect and good degumming, which can effectively shorten the ball milling time and improve the degumming performance; it is synthesized by water-based free radical polymerization, and is simple to operate and easy to realize. Industrial production.

The invention relates to a new process for producing a polyacrylamide high-efficiency papermaking fiber dispersant. Its technical scheme includes the following production process steps: pure water, sodium carbonate, sodium bicarbonate with a mass of 1%-10% of acrylamide, nonionic surfactant and anionic surfactant are sequentially added into a preparation kettle equipped with acrylamide. , the mass is 0.5%-20% functional monomer of acrylamide, and the mass is 1%-30% functional auxiliary agent of acrylamide, and the prepared liquid is injected into the polymerization kettle, and nitrogen gas is introduced to fully drive out oxygen. , adding an initiator to initiate polymerization; to obtain a gel-like product, the gel is formed into colloidal particles by a granulator, dried in a fluidized bed, and sent to a grinder after drying to be crushed, graded and packaged to obtain a paper-making fiber dispersant. The beneficial effects are as follows: the produced papermaking fiber dispersant has the advantages of good dispersion effect, high molecular weight, good water solubility, non-toxicity and high efficiency, low cost and the like.

The invention discloses a luminous functional composite material, which is a composite material of polystyrene and inorganic nano-oxides, characterized in that: the polystyrene is polystyrene with carboxylic acid functional groups at both ends, The material is selected from nanometer titanium dioxide, composite oxide of nanometer titanium dioxide, copper and chromium, nanometer zinc oxide or nanometer zinc-aluminum composite oxide. The preparation method is to synthesize polystyrene with benzoic acid unit at one end and chlorine atom at the other end by atom transfer radical polymerization; Polystyrene; final modification with inorganic nano-oxides. The polymer / nanoparticle composite material obtained by the present invention has red shift or blue shift relative to the fluorescence emission spectrum of the polymer, and becomes a new way to adjust the emission spectrum; at the same time, the composite material has good solubility and film-forming properties , has potential application value in light-emitting devices.

The invention discloses a preparation method of self-adhesive conductive hydrogel, which belongs to the technical field of biological material preparation. The invention comprises the following steps: firstly, introducing double bonds on biomacromolecules through methacrylic anhydride to obtain double bonded biomacromolecules. Then polydopamine functionalized conductive nanomaterials are prepared, and finally the self-adhesive conductive hydrogel is prepared by photoinitiating free radical polymerization of the double-bonded biomacromolecule and the polydopamine functionalized conductive nanomaterials. The invention learns from the adhesion of imitation mussel materials, introduces adhesive phenolic hydroxyl functional groups, and realizes the regulation and control of hydrogel self-adhesive performance by changing the content of the phenolic hydroxyl functional groups. In addition, the self-adhesive conductive hydrogel prepared by the present invention has good electrical conductivity, mechanical properties and biocompatibility, which broadens the application range of the hydrogel; the preparation method of the present invention is simple and easy, and the polymerization process is controllable , fast polymerization, low energy consumption and other advantages.

The invention relates to a hydrogen peroxide responsive polymer nano-carrier with a fluorescence ratio characteristic. The nano-carrier is of a spherical micelle structure, and is formed by self-assembling of an amphiphilic block copolymer with hydrogen peroxide responsiveness and ratiometric fluorescence imaging characteristics. The structural formula of the amphiphilic block copolymer having hydrogen peroxide responsiveness and ratiometric fluorescence imaging characteristics is as follows: R1 is a group having hydrogen peroxide responsiveness; R2 is a group with an aggregation-induced emission effect; R3 is a PEG hydrophilic chain; and R5 is a group with strong positive charges. The nano-carrier disclosed by the invention can be used for loading, transporting and program releasing of hydrophobic dye molecules and drug molecules as well as cell imaging and fluorescent molecular probes.

The invention relates to a method for synthesizing polyaspartic acid by using maleic anhydride and ammonia gas. The molten maleic anhydride and ammonia gas are subjected to a substitution reaction in a closed reactor. After the substitution reaction is completed, the remaining gas is absorbed; Sodium solution, carry out neutralization reaction to obtain a mixture of sodium maleamate and ammonium maleamate; directly heat up the product in a closed reactor, and carry out polycondensation reaction under stirring. After the polycondensation reaction is completed, evaporate the water to obtain polysuccinate imide solid; add water to another reaction kettle, start stirring, add polysuccinimide solid, slowly add sodium hydroxide solution, heat up for hydrolysis reaction, and obtain polyaspartic acid solution; the present invention simplifies production The weight average molecular weight of the obtained polyaspartic acid is 2000-15000, and the molecular weight distribution index is 1.5-1.65, which can meet the molecular weight requirements of different application fields, and the production process is environmentally friendly.

The invention discloses a function prepolymer and a preparation method and application thereof. The function prepolymer is a butyl acrylate polymer and prepared from a monomer, modified matter and an emulsifying agent through emulsion polymerization. A synthetic thickener, liquid disperse dye and the function prepolymer are mixed with water and evenly stirred to obtain printing paste; printing and drying of a polyester fabric are achieved through the obtained printing paste on a rotary screen printing machine or a mobile screen printing machine, then high-temperature processing is carried out on a tentering heat setting machine, and a printed polyester fabric is obtained. According to the technical scheme, the printing process is short, the hand feeling of the fabric is soft, postprocessing is not needed, a large amount of water and energy are saved, almost no wastewater is drained, processing equipment is conventional, and the printing processing technology is environmentally friendly.