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47results about How to "Improve heat and humidity stability" patented technology

Method for preparing basic chromium sulfate-chrome tanning agent by using lignite wax as reducing agent

The invention discloses a method for preparing a basic chromium sulfate-chrome tanning agent by using lignite wax as a reducing agent. The method comprises the processes of primary oxidation, secondary oxidation and oxidation liquid modulation, wherein the primary oxidation comprises the steps of acidizing the lignite wax for 1 hour and then stirring and oxidizing for 4-6 hours; the secondary oxidation comprises the steps of acidizing the primary oxidation liquid for 20-40 minutes and then stirring and oxidizing for 2-3 hours; the method further comprises the steps of adding the primary oxidation liquid and the secondary oxidation liquid into a reaction kettle, determining the adding amount of an oxidizing agent and a reducing agent, adding the oxidizing agent and the reducing agent into the reaction kettle sequentially and slowly, strictly controlling the reaction temperature at 105-115 DEG C, stirring and oxidizing for 1-2 hours, standing, ageing, spray-drying and forming to obtain the basic chromium sulfate-chrome tanning agent. Compared with the pure sugar reducing agent, the neutral salt content of the basic chromium sulfate-chrome tanning agent is reduced by above 30 percent, the chrome absorption quantity of leather is enhanced, and the plumpness and humidity-resistant and heat-resistant stability of the leather are improved. The basic chromium sulfate-chrome tanning agent comprises organic micromolecular acid with a good masking effect, particularly sulfonated phthalic acid, so that the leather is plump and soft, and has elasticity, natural brightness and wax feel.
Owner:南通金庆美术图案设计有限公司

Preparation method of amino resin retanning agent, retanning agent and application of retanning agent

ActiveCN111961173AGood water solubilityThere will be no precipitation of salt crystalsTanning treatmentTextile/flexible product manufacturePolymer scienceEther
The invention discloses a preparation method of an amino resin retanning agent. The preparation method comprises the following steps: firstly, modifying a dialdehyde monomer by using amino-terminatedpolyoxyethylene ether to obtain a dialdehyde modifier, then carrying out nucleophilic addition reaction with an amino monomer to generate a non-ionic amino resin prepolymer, finally adding an etherifying agent to seal free aldehyde groups, and adjusting the pH value to be neutral so that the amino resin retanning agent is obtained, wherein the molar ratio of primary amino in the amino monomer to aldehyde groups in the dialdehyde monomer is 1: 1.3-1: 3, and the proportion of unreacted aldehyde groups in the dialdehyde modifier is 40%-90%. The invention further discloses the retanning agent andan application thereof. According to the amino resin retanning agent provided by the invention, salt reactants are not involved in the whole process, the product quality is good, the comprehensive performance is high, the retanning performance can be comparable with that of a traditional amino resin retanning agent, formaldehyde is not used as a raw material in the preparation process, and the risk of residual formaldehyde brought by the retanning agent in finished leather processing is fundamentally eliminated.
Owner:科凯精细化工(上海)有限公司

Ultrathin metal based transparent conductive film

The invention discloses an ultrathin metal based transparent conductive film. The ultrathin metal based transparent conductive film comprises a bottom dielectric layer, an ultrathin metal layer and atop dielectric layer which are sequentially arranged from bottom to top, wherein the ultrathin metal layer is a silver layer; the bottom dielectric layer and the top dielectric layer both comprise thechemical components of MxZn1-xO; the average surface roughness of the bottom dielectric layer is 0.1-0.3 nm; M is a doped element and is any one of Mg, In and Gd; x is the mass ratio of the doping amount of M to the total quantity of M and Zn, and x is 0.005-0.5. The transparent conductive film is provided with a three-layer structure; compared with existing common transparent conductive films with the same structures, the ultrathin conductive film has the advantages that the high-temperature stability, the hydrothermal stability, the chemical stability, the in-air stability, the scraping resisting stability and other performances are greatly improved on the premise that the average optical transmission rate is not less than 80% under the wavelength of 400-800nm, and the film sheet resistance is not beyond 7 ohms / sq; and the application demands of a plurality of flexible photoelectric appliances can be met.
Owner:NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI

Internal wall thermal insulation building with high thermal resistance and thermal stability

The invention relates to an internal wall thermal insulation building with high thermal resistance and thermal stability. The building comprises a building internal wall and a thermal insulation board, wherein the thermal insulation board is arranged on an internal wall of the building; the thermal insulation board comprises a thermal insulation and heat protection board with high thermal resistance; and the thermal insulation and heat protection board is used for thermally separating a wall with high thermal inertia from indoor air with low thermal inertia. The building has an internal wall thermal insulation structure, namely the thermal insulation and heat protection board is decorated on the internal wall (comprising an inner wall, a ceiling and a ground), so that the wall is separated out thermally, and the thermal inertia of a room is substantially reduced; and the intensity of leakage of heat in the air to the wall is greatly reduced while the temperature, humidity and comfortableness of the indoor air are improved, so that the air in the room is quickly heated, an extremely obvious temperature rising effect is achieved, and the technical problem of low temperature rising effects of the air in the room due to the high thermal inertia of the wall in the prior art is solved.
Owner:浙江鼎美智装股份有限公司

Green silicate fluorescent powder with narrow half peak width and preparation method thereof

The invention discloses green silicate fluorescent powder with a narrow half peak width. The silicate fluorescent powder has a general chemical formula of (M1xBa2-x-u-k)(SiyM21-y)O4:uMn<2+>, kM3<2+>, wherein M1 is at least one of Sr, Ca, Mg and Cu, M2 is at least one of Ti, Zr, Ge and Sn, and M3 is one of Eu, Sm and Yb; x is greater than 0 and less than or equal to 0.2, y is greater than 0.8 and less than 1.0, u is greater than 0.05 and less than or equal to 0.15, and k is greater than 0 and less than or equal to 0.05. The invention also discloses a preparation method comprising: weighing raw materials and a fluxing agent, and performing mixing and grinding to obtain a mixture; performing high-temperature sintering on the mixture in a reducing atmosphere, and performing crushing, screening, alcohol washing and drying on the sintered mixture after cooling to obtain the narrow-half-peak wide-green silicate fluorescent powder. The preparation method of the fluorescent powder provided by the invention is simple and easy to control, needs a low sintering temperature during preparation, has a wide process window, and is suitable for large-scale industrial production; the obtained fluorescent powder has a narrow half peak width and a small particle size, is uniform in distribution, narrow in distribution range, good in chemical stability and strong in resistance to heat and humidity, and can be widely applied to LED illumination or display systems.
Owner:HEBEI LIFU CHEM TECH

Method for improving collagen heat stability by utilizing hydroxyapatite

The invention relates to a method for improving collagen heat stability by utilizing hydroxyapatite, and belongs to the technical field of tanning. The method comprises the following steps that according to the weight of limed skin, 3-5 parts of hydroxyapatite and 50-80 parts of water at the temperature of 20-30 DEG C are added in 100 parts of softening naked skin rotating drum, the softening naked skin rotating drum rotates for 40-60 minutes and stands for 60 minutes, water is drained, and the obtained naked skin is obtained. According to the method for improving the collagen heat stability by utilizing the hydroxyapatite, a nano-scale hydroxyapatite micro-core precursor is prepared by a hydrothermal method, and the micro-core precursor is permeated into the softened naked skin, so that the naked skin can be shaped to a certain degree. The physical and chemical properties, and especially the humidity resistance and heat stability are improved. The utilization value includes that the loss of the leather is reduced as the protection when the acid leaching temperature is too high; and also the pre-treatment of the hydroxyapatite can be used for degreasing the multi-fat skin at a hightemperature, so that a guarantee is provided for effective degreasing of sheep skin and pig skin before tanning.
Owner:SICHUAN UNIV

Method for preparing CsPbI3 perovskite thin film and high-efficiency solar cell thereof in high-humidity environment and application of CsPbI3 perovskite thin film and high-efficiency solar cell thereof

PendingCN114284439AGood energy conversion efficiencyReduce the harsh environmental requirements of the preparationSolid-state devicesSemiconductor/solid-state device manufacturingMetallic electrodeHole transport layer
The invention relates to a method for preparing a CsPbI3 perovskite thin film and a high-efficiency perovskite solar cell in a high-humidity environment and application, and belongs to the field of optoelectronic materials and devices. According to preparation of the full-inorganic CsPbI3 thin film, a precursor solution with methylamine acetate as a solvent is spin-coated on an FTO conductive substrate with an electron transport layer by adopting a hot spin-coating technology, a compact and uniform perovskite thin film is prepared through gradient annealing, and the whole process is completed in air with the relative humidity of 40%-80%. And then spin-coating an interface modification layer and Spiro-OMeTAD on the thin film as a hole transport layer, and evaporating a MoO3 modification layer and a metal electrode by using a vacuum evaporation technology to complete the preparation of the device. The CsPbI3 all-inorganic perovskite solar cell prepared by the method in high-humidity air has excellent photoelectric conversion efficiency.
Owner:NANJING UNIV OF TECH

A kind of method that carbodiimide catalyzed amino-terminated hyperbranched polymer is used for leather tanning

The invention discloses a method for using carbodiimide catalyzed amino-terminated hyperbranched polymers for leather tanning, and particularly relates to a method which is characterized in that the carbodiimide catalyzed amino-terminated hyperbranched polymers and a raw leather collagen fiber net generate multi-point covalent cross-linking; in the tanning step, the carbodiimide catalyzed amino-terminated hyperbranched polymers and the raw leather collagen fiber net are used for generating multi-point covalent cross-linking, so that the amino-terminated hyperbranched polymers and the raw leather collagen fiber net are used for generating multi-point covalent cross-linking, and thus the damp heat resistance stability and other physical mechanical performance of finished product leather tanned by the amino-terminated hyperbranched polymers can be improved. Under the catalysis of the carbodiimide, the amino-terminated hyperbranched polymers have the capability of singly bearing a tanningagent; a filling agent is re-tanned; the application range of the amino-terminated hyperbranched polymers to leather chemical engineering is expanded. The tanning method provided by the invention usescarbodiimide as the tanning catalyst, and uses the amino-terminated hyperbranched polymers as basic materials; when the method is applied to the leather tanning work section, the finished product leather has the advantages of good damp heat resistance stability, excellent physical mechanical performance, richness, softness and the like are realized.
Owner:SHAANXI UNIV OF SCI & TECH

Surface-functionalized spherical nano silicon dioxide-graphene oxide/polymer-based compound tanning agent and preparation method thereof

The invention discloses a surface-functionalized spheroidal nano SiO2-graphene oxide/polymer-based compound tanning agent and a preparation method of the surface-functionalized spheroidal nano SiO2-graphene oxide/polymer-based compound tanning agent. The prepared novel nano compound tanning agent is good in solubleness in a water phase and is quite beneficial to permeation and absorption of tanning agent molecules. The spherical nano compound tanning agent can more easily permeate in and fill in gaps of leather collagen fibers under the effect of mechanical force of a revolving drum due to small friction resistance. When the tanning agent is used for tanning sheep wet white leather, the thickening rate of the leather can reach 189%, and the leather utilization rate is greatly improved. Theshrinkage temperature of the tanned leather can reach 80 DEG C or above, after compounding of 0.5% chrome tanning, the shrinkage temperature can reach 95 DEG C or above, hydrothermal stability of theleather is remarkably improved, and the requirement for using performance of the finished leather is met. The tanned leather has the certain electrical resistance and fire resistance. The novel nanocompound tanning agent can partially replace chrome tanning, and a novel thought and a novel method are provided for clean chrome-free tanning research.
Owner:HENAN UNIVERSITY
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