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Phase-change heat conductive material and preparation method thereof

A phase-change heat-conducting and heat-conducting powder technology, used in heat exchange materials, chemical instruments and methods, etc., can solve the problems of increasing thermal resistance, drying out, loss, etc., to achieve accelerated heat transfer, high thermal conductivity, and easy disassembly. the effect of

Inactive Publication Date: 2009-10-21
NANJING KAIHUI IND TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the use of heat-conducting silicone grease is inconvenient, and it is easy to contaminate the circuit board and cause short-circuit and other faults. After many cycles of cold and heat, it will be lost and dry, which will increase the thermal resistance instead.
Although cross-linked and vulcanized silicone rubber heat-conducting gap-filling materials and heat-conducting insulating materials are convenient to use, they have large thermal resistance and cannot meet the requirements of high thermal conductivity, such as applications in graphics processor chips, central processing unit chips, etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] (1) Put 20g of EPDM, 10g of paraffin wax, 18.5g of polyborosiloxane tackifier, and 10g of silicone resin with a viscosity of 60cps into the heating and stirring tank to stir and mix them evenly at a temperature of 150°C.

[0041] (2) Take by weighing 40g of aluminum oxide with an average particle diameter of 40 microns after impregnating and drying the ethanol solution containing 1.5g of n-hexyltrimethoxysilane, put into the stirring tank in step (1) and vacuumize and stir for 1 hours to make the raw material mixture.

[0042] (3) The raw material mixture is roll-coated on a 0.025mm thick Kapton MT film at 80°C, and it becomes a phase-change thermally conductive material after cooling.

[0043] (4) Put the phase-change heat-conducting material in step (3) into the device for testing the hardness for testing.

[0044] (5) Put the phase-change thermally conductive material in step (3) into a device for detecting thermal conductivity to detect thermal conductivity.

[00...

Embodiment 2

[0047] (1) Put 2g of EPDM, 18g of paraffin wax, 5g of polyborosiloxane tackifier, and 10g of silicone resin with a viscosity of 3000cps into a heating and stirring tank to stir and mix them evenly at a temperature of 150°C.

[0048] (2) Weighing 64g of aluminum nitride with an average particle diameter of 40 microns and magnesium oxide with an average particle diameter of 60 microns, impregnated with an ethanol solution containing 1g of n-decyltriethoxysilane, dried, and put Vacuumize and stir in the stirring tank of step (1) for 1 hour to make a raw material mixture.

[0049] (3) Roll coat the raw material mixture on a 0.013mm thick PEN film at 80°C, and form a phase-change thermally conductive material after cooling.

[0050](4) Put the phase-change heat-conducting material in step (3) into the device for testing the hardness for testing.

[0051] (5) Put the phase-change thermally conductive material in step (3) into a device for detecting thermal conductivity to detect th...

Embodiment 3

[0054] (1) Put 10g of EPDM, 5g of paraffin wax, 5g of polyborosiloxane tackifier, and 39g of silicone resin with a viscosity of 5000cps into a heating and stirring tank to stir and mix them evenly at a temperature of 150°C.

[0055] (2) Take 40g mean particle diameter and be that boron nitride of 80 microns is impregnated in the ethanol solution containing n-octyltriethoxysilane 1g, after drying, put into the stirring tank of step (1) and vacuum stir for 1 hours to make the raw material mixture.

[0056] (3) After the raw material mixture is pressed into tablets and cooled, it becomes a phase-change heat-conducting material.

[0057] (4) Put the phase-change heat-conducting material in step (3) into the device for testing the hardness for testing.

[0058] (5) Put the phase-change thermally conductive material in step (3) into a device for detecting thermal conductivity to detect thermal conductivity.

[0059] The test data shows that the thickness is 0.1mm, and the thermal ...

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Abstract

The invention discloses a phase-change heat conducting material and the preparation method, mainly comprising the silicone 10 to 40 wt percent, the ethylene propylene diene rubber 2 to 20 wt percent, the heat conducting powder 40 to 70 wt percent, the paraffin 5 to 25 wt percent, the tackifier 5 to 35 wt percent and the resin acceptor 0.1 to 1.5 wt percent. The phase-change heat conducting material can be coated on the copper foil, the aluminum foil, the polyethylene naphthalatc film or the polyimide film in solution state in order to increasing the strength. The dissolved with the mixed refrigerant is solid in ambient temperature, so can be conveniently fixed between the radiator and the electronic device, GPU and CPU. When the temperature of the device is up to 40 to 70 degree C, the dissolved with the mixed refrigerant starts to soften and flow, so can fill with the air gap between the interfaces well, reduce the thermal resistance and accelerate the heat transference. The phase-change heat conducting material can be perfectly peeled off when maintaining or replacing the device and also can reuse.

Description

technical field [0001] The invention belongs to the field of organosilicon chemical industry, and relates to a heat-conducting phase-change material that can soften and flow under heating and a preparation method thereof. Background technique [0002] The circuit design of modern electronic instruments and equipment is becoming more and more complex, and the integration level is getting higher and higher. Design engineers strive to install more devices in a smaller area in order to realize the miniaturization of instruments and equipment. To ensure the stable operation of these highly integrated devices, the heat generated by each electronic component must be effectively and timely transferred to the surrounding environment. The usual method is to install metal radiators with high thermal conductivity such as copper and aluminum on the surface of the device, and at the same time increase the heat dissipation area. Further, a fan is installed above the radiator to force air...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K5/06C08L83/04C08L23/16C08L91/06
Inventor 黄和韩毓旺欧阳金强胡学超孙鹏
Owner NANJING KAIHUI IND TECH
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