Method for preparing high water absorbing resin in nutrition type for agricultural use
A super absorbent resin and nutritional technology, applied in the field of super absorbent resin, can solve the problems of high cost of water-retaining agent, low addition of water-retaining agent soil, inability to fundamentally reduce the cost of raw materials, etc., and achieve good biological and chemical stability. , the effect of facilitating industrial production and reducing costs
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Embodiment 1
[0009] Put 10 parts of acrylamide and 100 parts of acrylic acid in a 250ml beaker, add 400 parts of deionized water and stir to dissolve, adjust the pH value with potassium hydroxide to make the pH value of the system around 7.0, add 10 parts of urea, 100 parts of dihydrogen phosphate Stir and dissolve the ammonium and pass nitrogen for 30 minutes, add 0.05 part of oxidant ammonium persulfate, add 0.1 part of reducing agent sodium metabisulfite and stir evenly, then add 0.05 part of crosslinking agent N, N'-methylenebisacrylamide, in Polymerize at a temperature of 20°C, and the polymerization time is 2 hours. The product is granulated, dried, and pulverized to obtain an agricultural nutritional superabsorbent resin. The water absorption rate of the product is 500 times, and the absorption rate of physiological saline is 80 times.
Embodiment 2
[0011] Put 100 parts of acrylic acid in a 250ml beaker, add 350 parts of deionized water and stir evenly, adjust the pH value with potassium hydroxide, make the pH value of the system around 7.0, add 100 parts of urea, 10 parts of diammonium hydrogen phosphate, stir and dissolve, pass Nitrogen for 30 minutes, add 1.0 parts of potassium persulfate, add 1.0 parts of sodium sulfite, stir evenly, add 0.5 parts of crosslinking agent N, N'-methylene bisphenamide, and polymerize at a temperature of 10 ° C, the polymerization time After 1 hour, the product was dried and pulverized to obtain an agricultural nutritional superabsorbent resin. The water absorption rate of the product is 400 times, and the absorption rate of normal saline is 50 times.
Embodiment 3
[0013] Put 90 parts of acrylamide and 10 parts of acrylic acid in a 250ml beaker, add 400 parts of deionized water and stir to dissolve, adjust the pH value with potassium hydroxide to make the pH value of the system around 7.0, add 80 parts of urea, 80 parts of diammonium hydrogen phosphate After stirring and dissolving, pass nitrogen for 30 minutes, add 0.5 parts of hydrogen peroxide and 0.5 parts of ascorbic acid and stir evenly, add 0.5 parts of cross-linking agent N, N'-methylenebisacrylamide, polymerize at 40 °C, polymerize The time is 1 hour, and the product is granulated, dried and pulverized to obtain an agricultural nutritional superabsorbent resin. The water absorption rate of the product is 200 times, and the absorption rate of normal saline is 30 times.
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