Composite heat-resisting enhance titanium alloy

A titanium alloy, heat-resistant technology, applied in the field of titanium alloys, can solve the problems of high specific strength, low room temperature plasticity and fracture toughness, and can not meet the requirements, and achieve the effect of good high temperature stretching, good room temperature plasticity, and low deformation resistance.

Inactive Publication Date: 2007-11-21
浙江嘉钛金属科技有限公司
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  • Application Information

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Problems solved by technology

[0003] According to the literature search, Mao Xiaonan et al. wrote the article "Properties and Microstructure Characteristics of TP_650 Particle Reinforced Titanium Matrix Composites" in "Rare Metal Materials and Engineering", June 2004, Volume 33, No. 6, 620-623, TP650 alloy is expected to become a 650°C titanium alloy, which has the characteristics of easy processing, low cost, stable interface, heat resistance, corrosion resistance, and wear resistance, but its strength at 700°C is only equivalent to that of IMI834 and Ti1100 at 650°C. Thermal temperature cannot be increased further
Ti 3 Al-based intermetallic compounds, which are characterized by high specific strength, high specific modulus and resistance to combustion, but low room temperature plasticity and fracture toughness
However, compared with the 600°C high-temperature titanium alloys that have been practically used abroad, there is still a gap between the comprehensive performance of the domestic 600°C high-temperature titanium alloys and foreign countries, and it cannot meet the needs of the national aerospace and aviation fields.
The thermal stability of titanium alloys between 600°C and 700°C is mainly related to the brittle phase Ti 3 The precipitation of X (X=Al, Ge, In, Sn, etc.), and the usual method of increasing the alloy’s service temperature by increasing the alloy content may cause brittle phase Ti 3 Precipitation of X, thereby reducing the thermal stability of the alloy

Method used

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  • Composite heat-resisting enhance titanium alloy
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  • Composite heat-resisting enhance titanium alloy

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] Weigh first-grade sponge titanium (79.8%), LaB by mass percentage x (70% by mass of La) compound (0.7%), AlNb (53% by mass of Nb) master alloy powder (1.6%), aluminum powder (4.2%), AlMo (50% by mass of Al and Mo) Master alloy powder (2.0%), TiSn (65% by mass of Sn) master alloy powder (6.9%), sponge zirconium (4.5%), crystalline silicon (0.3%), the mass percentage of preparation is Al6%-Sn4.5% -Zr4.5%-Mo1%-Nb0.9%-Si0.3%-La0.5%-B0.2% composite strengthened heat-resistant titanium alloy. The uniformly mixed raw materials are pressed into electrode rods; then the electrodes are put into a vacuum consumable electric arc furnace for one melting to obtain a primary ingot; after two primary ingots are welded by an argon arc welding machine or in a furnace, they are placed in a self-consumable electric arc furnace. The electric arc furnace is used for secondary smelting to obtain secondary ingots; the third smelting process is the same as that of the secondary smelting. The ...

Embodiment 2

[0021] Weigh first-grade sponge titanium (85.05%), LaB by mass percentage 4 (76% by mass of La) compound (0.65%), AlNb (40% by mass of Nb) master alloy powder (1.25%), aluminum powder (2.35%), AlMo (40% by mass of Mo) master alloy powder (1.5%), TiSn (50% by mass of Sn) master alloy powder (6%), sponge zirconium (3%), crystalline silicon (0.2%), the preparation mass percentage is Al4%-Sn3%-Zr3%-Mo0 .6%-Nb0.5%-Si0.2%-La0.4%-B0.15% composite strengthened heat-resistant titanium alloy. According to the same three-time smelting process and thermal processing process as in Example 1, a heat-treatable rod was obtained. Using the recommended heat treatment process: 1100 ° C, 1 hour, air-cooled solution treatment + 650 ° C, 2 hours, air-cooled aging treatment, the overall performance of the heat-resistant titanium alloy obtained is similar to that of Example 1, and the plasticity and thermal stability at room temperature The resistance is slightly better, but the strength and perman...

Embodiment 3

[0023] Weigh first-grade sponge titanium (77.35%), LaB by mass percentage 6 (67% by mass of La) compound (1.3%), AlNb (65% by mass of Nb) master alloy powder (1.5%), aluminum powder (5.7%), AlMo (65% by mass of Mo) master alloy powder (2.3%), TiSn (80% by mass percent of Sn) master alloy powder (6.25%), sponge zirconium (5%), crystalline silicon (0.6%), the mass percent of preparation is Al7%-Sn5%-Zr5%-Mo1 .5%-Nb1%-Si0.6%-La0.9%-B0.4% composite strengthened heat-resistant titanium alloy. According to the same three-time smelting process and thermal processing process as in Example 1, a heat-treatable rod was obtained. Using the recommended heat treatment process: 1100 ° C, 1 hour, air-cooled solution treatment + 650 ° C, 2 hours, air-cooled aging treatment, the overall performance of the heat-resistant titanium alloy obtained is similar to that of Example 1, and the strength and durable creep The performance is slightly better, but the room temperature plasticity and thermal...

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Abstract

A composite enhanced heat-resisting titanium-alloy consists of Al 3-8%, Sn 1-6%, Zr 1-6%, Mo 0.5-2%, Nb 0.5-1.5%, Si 0.1-0.8%, La 0.3-1%, B 0.1-0.5% and Ti residue. It has excellent heat, creep resistances and thermal stability at 650-700 degree. It can be used for aviation and aerospace.

Description

technical field [0001] The invention relates to a titanium alloy in the technical field of metal materials, in particular to a composite strengthened heat-resistant titanium alloy. Background technique [0002] High-temperature titanium alloys are mainly used in aerospace, aviation and other fields that require high temperature resistance. For example, aero-engines have strict requirements on high-temperature titanium alloys, which require materials to have good matching of room temperature performance, high temperature strength, creep performance, thermal stability, fatigue performance and fracture toughness. The improvement of engine performance largely depends on the improvement of high-temperature performance of materials, and engine design engineers have higher and higher requirements for the performance of high-temperature titanium alloys. IMI834 (UK), Ti-1100 (USA), BT36 (Russia) and other alloys have been used as 600°C titanium alloys in the aerospace field. my coun...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C14/00
Inventor 吕维洁覃继宁肖旅李云钢张荻
Owner 浙江嘉钛金属科技有限公司
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