Channeling-preventing agent for extra-low permeation oil accumuiation carbonic anhydride oil displacement and application thereof

A technology of carbon dioxide and anti-channeling agent, applied in drilling compositions, chemical instruments and methods, etc., can solve the problems of uneven stress distribution, no improvement, and rising resistance coefficient of high-permeability layers of cores, so as to inhibit channeling , to expand the effect of carbon dioxide sweep volume

Active Publication Date: 2008-05-07
CHINA UNIV OF PETROLEUM (BEIJING)
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among these two methods, chemical expansion is mostly used in China, while inflatable expansion is used abroad. Chemical expansion is easier to see from the construction, but it is prone to side effects. The existing chemical expansion cannot solve the gas well. The problem of channeling, expansion is to offset part of the cement shrinkage caused by hydration. After offsetting, the cement stone does not shrink or expand, and the volume does not change. This method does not solve the problem of gelling weight loss, and the cement slurry itself does not shorten. The characteristics of excessive time do not compensate for the pressure loss caused by gelling. In this process, cement slurry only plays a basic role, and gelling weight loss is inevitable. However, this method does not have any improvement measures. During the gas channeling process, the role of the cement slurry itself and its factors are no longer the main factors in the whole process. The displacement efficiency and well environment conditions will become the absolute main factors affecting the channeling prevention. Th

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] An anti-channeling agent for effectively inhibiting the channeling of carbon dioxide according to the invention.

[0033] Ingredient: The main agent of blocking channels is ethylenediamine, and the release agent is ethanol (95% ethanol).

[0034] Ethylenediamine has a boiling point of 117°C and a specific gravity of 0.899(d 4 20 ), which is highly volatile in oil reservoirs with a temperature above 100°C, and the volatilized gas migrates along the channel of carbon dioxide escape, and after contacting with carbon dioxide, an acid-base reaction can occur to form salt crystals:

[0035] h 2 NCH 2 CH 2 NH 2 +CO 2 +H 2 O→(H 3NCH 2 CH 2 NH 3 )CO 3 ·xH 2 O (crystal)

[0036] Ethanol is set between ethylenediamine and carbon dioxide as an isolation slug. The ethanol isolation slug can not only completely remove the stagnation of carbon dioxide, but also thoroughly remove ethylenediamine to avoid blockage near the wellbore. Ethylenediamine is used as the main blo...

Embodiment 2

[0038] The application method of the anti-channeling agent for inhibiting carbon dioxide channeling of the present invention.

[0039] Composition: The organic amine is diethylamine, and the release agent is nitrogen.

[0040] After carbon dioxide has been injected into the ultra-low permeability reservoir for a period of time, it is found that there is a phenomenon of carbon dioxide channeling from the production well. At this time, the same injection process parameters are maintained, and nitrogen is continuously injected into the oil layer for 3 days as a spacer (daily injection 3 Tons), to establish the first isolation slug; then converted to the same volume injection rate, continuous injection of diethylamine for 5 days (daily injection 6 tons), followed by injection of nitrogen for 3 days as a spacer (daily injection 3 tons), Build a second isolation slug with a mass ratio of 1.67:1, and then resume normal carbon dioxide injection without shutting in the well. Main agen...

Embodiment 3

[0043] Experiment on the plugging performance of the anti-channeling agent for inhibiting carbon dioxide channeling of the present invention.

[0044] Experimental conditions:

[0045] (1) Simulated reservoir temperature: 60°C.

[0046] (2) Experimental water: ordinary injection water from the oil field.

[0047] (3) Carbon dioxide: purity 99.9%, reagent grade.

[0048] (4) Physical model: ultra-low permeability model tube (2.5×30cm) of consolidated outcrop sand, permeability 0.5×10 -3 μm 2 .

[0049] (5) Anti-channeling agent: diethylamine (industrial product, boiling point 55.9°C).

[0050] (6) Release agent: ethanol with a content of 95%.

[0051] (7) Pressure measurement system: The computer automatically collects the pressure change value through the pressure sensor (made in China).

[0052] (8) Injection pump: domestic constant speed injection pump.

[0053] Experimental purpose: In a physical model simulating normal reservoir conditions, investigate the channel...

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Abstract

The invention provides a fleeing proof agent for the carbon dioxide flooding of oil reservoirs with ultra-low permeability and the application of the fleeing proof agent. The invention is characterized in that: the main agent of the fleeing proof agent is the amine substance of organic compounds; the fleeing proof agent comprises at least one amine substance and a release agent; the release agent is the ethanol comprising a certain amount of water, a hydrocarbon substance or nitrogen; the release agent is used to prevent the chemical reaction caused by the premature contact between the amine and the carbon dioxide. The invention is suitable for the gas channeling inhibition during the carbon dioxide flooding process for oil reservoirs with ultra-low permeability. The invention has the advantages that: the fleeing proof agent mainly block the gas channeling channel by the salt precipitation generated by the reaction between the carbon dioxide and the amine; the generation time of the salt precipitation is controlled by the injection volume of the release agent; the swept volume displaced by the carbon dioxide is enlarged, and the improvement of the economic benefit of carbon dioxide flooding is favored.

Description

technical field [0001] The invention relates to an anti-channeling agent for enlarging the swept volume of carbon dioxide during carbon dioxide flooding, in particular to an anti-channeling agent for carbon dioxide flooding in ultra-low permeability reservoirs and its application. technical background [0002] As we all know, ultra-low permeability reservoirs contain relatively abundant crude oil reserves, but the development of ultra-low permeability reservoirs is difficult by water flooding, so they are generally more suitable for carbon dioxide displacement. Due to the heterogeneity of reservoirs, there is obvious gas channeling in almost all CO2 flooding processes, which limits the extent to which CO2 expands and sweeps volume. The water phase after additives generally increases in consistency, which is more difficult than water injection displacement, and it is difficult to achieve deep channel sealing, resulting in poor final carbon dioxide flooding effect. [0003] T...

Claims

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Application Information

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IPC IPC(8): C09K8/58
Inventor 侯吉瑞刘中春赵凤兰
Owner CHINA UNIV OF PETROLEUM (BEIJING)
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