Reflection holography thin film and preparation method thereof

A holographic and film material technology, applied in the field of reflection holographic film and its preparation, can solve the problems of easy image erasing, short storage life, low reflection efficiency, etc., and achieve high refractive index modulation value, long storage life and high reflection efficiency. Effect

Inactive Publication Date: 2008-12-10
SHANGHAI TECHSUN ANTI COUNTERFEITING TECH HLDG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But it also has many deficiencies, such as low sensitivity, short storage life, photosensitive plate needs to be produced at any time, and the material needs wet processing after imaging, and the hologram is greatly affected by the environment. It is easy to disappear in an environment with high humidity;
[0005] And photopolymer material, as the photopolymer in the disclosed material of

Method used

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  • Reflection holography thin film and preparation method thereof
  • Reflection holography thin film and preparation method thereof
  • Reflection holography thin film and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0067] Put 0.012g of azobisisobutyronitrile, 30g of methyl methacrylate and 0.2g of ZnS (with a particle size of 20nm) into a 100mL three-necked flask equipped with an electric stirrer, a condenser tube and a nitrogen pipe, and open the Cooling water, logical nitrogen, start stirrer, stirring speed is 800 rev / min). Heat to 75°C, take a sample after 20 minutes to make a methyl methacrylate prepolymer containing ZnS nanoparticles, then stop heating and cool to room temperature. Flush with nitrogen and store in refrigerator for later use. The weight content of the nanoparticles is 0.66%, and the measured weight average molecular weight is 5600.

Embodiment 2

[0069] Put 0.02g of dibenzoyl, 36g of 4-mercaptomethylstyrene and 0.35g of ZnS (with a particle size of 30nm) into a 100mL three-neck flask equipped with an electric stirrer, a condenser tube and a nitrogen pipe, and turn on the cooling water, nitrogen, and start the stirrer to mix evenly (stirring speed is 1200 rpm). Heat to 75°C and take a sample after 20 minutes. To make 4-mercaptomethylstyrene prepolymer containing ZnS nanoparticles, stop heating and cool to room temperature. Flush with nitrogen and store in refrigerator for later use. The weight content of the nanoparticles is 0.96%, and the weight-average molecular weight is 12000 according to the test.

Embodiment 3

[0071] Under the red safety light of wavelength greater than 600nm, with 9.2 grams (77wt%) film-forming agent polyvinyl acetate-butyl acrylate-acrylic acid terpolymer, monomer N-vinyl carbazole 1.0 grams (8.3wt%) , monomer tricyclodecane dimethanol diacrylate 0.6 gram (5wt%), the methyl methacrylate prepolymer 0.53 gram (4.4% embodiment 1) that contains ZnS nanoparticle, photoinitiator 2,4,6 - 0.078 grams (0.65wt%) of triphenylimidazole base doublet, 0.067 grams (0.056wt%) of photosensitizer diethylamino-benzylidene cyclopentanone, 0.04 grams (0.33wt%) of chain transfer agent 2-mercaptobenzothiazole wt%), UV absorber 2-hydroxyl-4-methoxybenzophenone 0.02 gram (0.17wt%), nonionic surfactant FC-44300.11 grams (0.92wt%), plasticizer diethyl sebacate 0.34 grams (2.8wt%) was added to the mixed solution (butanone: dichloromethane: methanol = 5:1:1, weight ratio) , with a weight solid content of 8%, stirred at room temperature until dissolved, the measured viscosity is 11cp (25°C),...

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Abstract

The invention provides a reflection holographic thin membrane and a preparation method thereof. The reflection holography membrane comprises a basement membrane, a buffer layer which is coated at one side of the basement membrane, a photopolymer coating which is coated at the other side of the buffer layer and formed by the holographic polymer paints, and a protective membrane which is covered on the surface of the photopolymer; wherein, hologram images or the interference fringes of double discoloration pictures are recorded on the photopolymer coating; the photopolymer coating comprises film-forming agents, a nano-composite pre-polymer, a monomer, photo initiators, chain transfer agents and photo sensitizers; the nano-composite pre-polymer is a product which is prepared by alkenyl unsaturated monomer with an unsaturated group at the terminal position and nano-particles. The invention has high sensitivity, high reflection efficiency, high refractivity modulation value, long storage life and little influence of the environment on the hologram images; the recorded images are treated by photo-curing and heat-enhancement and can reach reflected images and double discoloration images with the reflection efficiency of more than 99.9 precent, so mass production is available.

Description

technical field [0001] The invention relates to a reflective holographic film and a preparation method thereof. Background technique [0002] The production of reflection holograms is limited to the fact that the recorded interference fringes are different from rainbow holograms, most of which are parallel to the surface of the recording medium, and cannot be copied mechanically, but can only be copied optically. The appearance of holograms is usually achieved through the contrast of interference fringes. There are many types of materials used to record reflection holograms, but there are fewer ideal recording materials, and fewer materials that can be used for large-scale production. More often, silver salts and gelatin dichromate and a photopolymer material as disclosed in US3,658526 patent are used. [0003] The silver salt recording material has high sensitivity, and its interference fringes are realized by the black and white contrast of the photosensitive material, b...

Claims

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Application Information

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IPC IPC(8): G03F7/00G03H1/18
Inventor 徐良衡高芸游仁顺李兰芳徐雪雯
Owner SHANGHAI TECHSUN ANTI COUNTERFEITING TECH HLDG
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