Emulsion type amphiphilic polymer resin and preparation and application thereof in preparation of coating
An amphiphilic polymer, emulsion-type technology, applied in the polymer field, can solve the problems of low responsiveness, slow speed, large thixotropy, etc., achieve good application prospects and overcome the effect of high energy consumption
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Embodiment 1
[0052] (1) Preparation of emulsion type amphiphilic polymer resin
[0053] Formula: by weight
[0054] 10 parts of methacrylic acid, 80 parts of methyl methacrylate, 50 parts of butyl acrylate, 10 parts of hydroxypropyl methacrylate, 10 parts of diacetone acrylamide, 1 part of sodium lauryl sulfate, Tween-202 parts , 2 parts of potassium persulfate, 2 parts of sodium bicarbonate.
[0055] Process: methacrylic acid, methyl methacrylate, butyl acrylate, hydroxypropyl methacrylate, diacetone acrylamide and 0.5 part of sodium lauryl sulfate in parts by weight, Tween-201 part, over Mix 1 part of potassium sulfate evenly for pre-emulsification to make a pre-emulsion; dissolve 5 parts of sodium bicarbonate and the remaining sodium lauryl sulfate, 1 part of Tween-201 and 1 part of potassium persulfate in 160 parts of distilled water to form Transparent aqueous solution of initiator and emulsifier, and heat up to 90°C; then add the above-mentioned pre-emulsion into the transparent aq...
Embodiment 2
[0057] Embodiment 2: the preparation of emulsion type amphiphilic polymer resin
[0058] Formula: by weight
[0059] 10 parts of acrylic acid, 60 parts of styrene, 30 parts of butyl acrylate, 30 parts of hydroxyethyl methacrylate, 20 parts of acrylamide, 10 parts of diacetone acrylamide, 1 part of sodium lauryl sulfate, emulsifier OP-102 parts, 3 parts of ammonium persulfate, 1 part of sodium bicarbonate, and 160 parts of distilled water.
[0060] Process: Acrylic acid, styrene, butyl acrylate, hydroxyethyl methacrylate, diacetone acrylamide and sodium lauryl sulfate 1.5 parts, emulsifier OP-10 0.5 parts, ammonium persulfate 1.5 parts according to the above formula Mix evenly for pre-emulsification to make a pre-emulsion; dissolve sodium bicarbonate and the remaining sodium lauryl sulfate, emulsifier OP-10, and ammonium persulfate in distilled water and stir evenly to form a transparent initiator and emulsifier The aqueous solution; the temperature is raised to 80°C, and the...
Embodiment 3
[0062] Embodiment 3: the preparation of emulsion type amphiphilic polymer resin
[0063] Formula: by weight
[0064] 5 parts of methacrylic acid, 5 parts of acrylic acid, 40 parts of methyl methacrylate, 20 parts of styrene, 40 parts of butyl acrylate, 20 parts of hydroxypropyl methacrylate, 5 parts of acrylamide, 25 parts of diacetone acrylamide, 160 parts of distilled water, 2 parts of dodecyltrimethylammonium chloride, 2 parts of emulsifier OP-10, 2 parts of ammonium persulfate, 3 parts of sodium bicarbonate.
[0065] Process: Chlorinated acrylic acid, methacrylic acid, styrene, methyl methacrylate, butyl acrylate, hydroxypropyl methacrylate, acrylamide, diacetone acrylamide and dodecyl trimethyl according to the above formula 0.5 parts of ammonium, 1 part of emulsifier OP-10, 1.5 parts of ammonium persulfate, mixed evenly for pre-emulsification to make a pre-emulsion; Agent OP-10 and ammonium persulfate are dissolved in distilled water to form a transparent aqueous solut...
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