Botanical fungicide synergistic agent, extracting technique and application thereof in agricultural fungicide

An extraction process and synergist technology, applied in fungicides, plant growth regulators, applications, etc., can solve problems such as environmental hazards, no reports of bactericidal synergists, and reduced drug efficacy, so as to alleviate environmental pollution, Good promotion and application prospects, enhance the effect of drug efficacy

Inactive Publication Date: 2010-01-13
QINGDAO STAR CROPSCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The extract product of citrus appears on the market at present, but it is various health medicines, similarly, although there are data records for the extraction process of citrus peel, as mentioned the process research of extracting pectin from orange peel by microwave method, and Orange peel is used as raw material. Under microwave conditions, the pH value of the extract is adjusted with mixed acid, and the pectin is extracted by anhydrous ethanol precipitation process. However, the extract of orange peel is used as a bactericidal synergist in agriculture and its extraction process and Applications in pesticides have not been reported
[0004] In the process of prevention and control of agricultural diseases, chemical fungicides are mainly used to deal with them. Although the sterilization speed is fast and the effect is obvious, with the long-term and unreasonable use of various chemicals, the bacteria have developed serious drug resistance, and the drug effect has gradually decreased. The harm to the environment is also becoming more and more serious. Therefore, the search for botanical fungicides with good environmental compatibility has become the current mainstream direction

Method used

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  • Botanical fungicide synergistic agent, extracting technique and application thereof in agricultural fungicide
  • Botanical fungicide synergistic agent, extracting technique and application thereof in agricultural fungicide

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specific Embodiment

[0023] The specific embodiment of extraction process of the present invention is as follows:

[0024] ① Wash the peel of the citrus fruit, dry it, and crush it into 50-mesh particles;

[0025] ②Put 100g of crushed peel particles into the reaction kettle, add 200ml of mixed extract composed of ethanol and water, wherein the weight percentage of ethanol is 80%, stir and reflux at 50-80°C for 3h, apply ultrasonic waves during heating and reflux , sonicate once every 30min, each time ultrasonically oscillate for 10min, reflux ends and filter, and retain the filtrate;

[0026] ③ Add 100ml of mixed extract to the residue of step ②, repeat step ② to extract again, filter, and keep the filtrate;

[0027] ④ Replace the mixed extract in step ② with 50ml of water, extract the residue in step ③ again, filter, and keep the filtrate;

[0028] 5. all filtrates in the merging steps 2., 3., 4. are heated and distilled and concentrated to obtain the bactericidal synergist concentrated solutio...

Embodiment 1

[0032] The application of the extract of the present invention as a synergist in 5% difenoconazole microemulsion, the distribution ratio of each component is by weight:

[0033] Difenoconazole 5%

[0034] Phenylphenol polyoxyethylene polyoxypropylene ether 4%

[0035] Alkylphenol ethoxylates 4%

[0036] Calcium Alkylbenzene Sulfonate 2%

[0037] Cyclohexanone 10%

[0038] Concentrate of the present invention 5%

[0039] Citric acid 0.2%

[0040] water balance

[0041] The preparation process is as follows: dissolve difenoconazole with cyclohexanone, add phenylethylphenol polyoxyethylene polyoxypropylene ether, alkylphenol polyoxyethylene ether, calcium alkylbenzenesulfonate, and the concentrated solution of the present invention and stir Uniformly used as the oil phase, adding citric acid into water and stirring evenly as the water phase, slowly adding the water phase to the oil phase under stirring at 1000-2000r / min, and continuing to stir for 30min.

Embodiment 2

[0043] The application of the extract of the present invention as a synergist in 10% difenoconazole wettable powder, the distribution ratio of each component is by weight:

[0044] Difenoconazole 10%

[0045] Solid particles of the present invention 50%

[0046] Sodium Alkyl Sulfate 2%

[0047] Calcium lignosulfonate 4%

[0048] Pull apart powder 4%

[0049] Silica balance

[0050]The preparation process is as follows: uniformly mix the solid particles of the extract of the present invention with difenoconazole, sodium alkyl sulfate, calcium lignin sulfonate, pull-off powder and white carbon black, and then mix them after airflow crushing.

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Abstract

The invention discloses a botanical fungicide synergistic agent, an extracting technique and the application thereof in agricultural fungicide. The botanical synergistic agent is extract of pericarp of citrus fruit; the three-time extracting technique is adopted, and ultrasound-assisted extraction is applied, so that the maximum extraction capacity of active ingredient can be ensured; the technique is simple and seldom affects the environment, and the botanical fungicide synergistic agent can be taken as synergistic agent to be matched with the traditional chemical bactericide for use, so that the sterilizing effect is remarkably improved; the botanical fungicide synergistic agent can be added into liquid preparation and solid preparation, and more particularly can be applied to preparations such as microemulsion, suspending agent, wetting powder, water dispersible granules, etc.

Description

technical field [0001] The invention relates to the technical field of agricultural fungicide preparations, in particular to a botanical fungicide synergist, its extraction process and the application of the extract as a synergist in agricultural fungicide preparation technology. Background technique [0002] Citrus is the general name of tangerine, tangerine, orange, kumquat, pomelo, and trifoliate. It has been cultivated in my country for more than 4,000 years, and many strains have been formed. The citrus fruit has both excellent color and fragrance, rich juice, and beautiful flavor. In addition to sugar, organic acids, and minerals, it is also rich in vitamin C and a variety of glycosides, with high nutritional value, so it is often used as Chinese medicinal materials and health food. It is reported that citrus is beneficial to Qi, strengthens the body, aids digestion, It has the functions of invigorating the spleen and stomach, lowering blood pressure, etc., and has certa...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A01N65/36A01P3/00
Inventor 李国安孙明明
Owner QINGDAO STAR CROPSCI
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