Preparation method of epoxy asphalt road surface materials

A technology for epoxy asphalt and pavement materials, which is applied in building insulation materials, roads, roads, etc., can solve the problems of high cost, unexplained water stability, poor water stability, etc., and achieves good deformation ability and durability, shortening Traffic closed time, excellent effect of fatigue resistance

Active Publication Date: 2010-01-27
江苏文昌新材料科技有限公司
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  • Application Information

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Problems solved by technology

The applicant searched and found that the Chinese patent application with the application date of April 28, 2006, the application number 200610039988.8, and the name "thermosetting epoxy asphalt material for road and bridge and its preparation method" discloses an epoxy asphalt material and its The preparation method of the material is obtained by reacting the epoxy resin of component A and component B in a mass ratio of 2:1-8:1, wherein the raw material of component A needs to be modified asphalt with carboxyl group or acid anhydride group, There are many raw materials for aliphatic dibasic acid, dimer acid or alkyd resin, fatty acid anhydride, and curing accelerator. When preparing, it is necessary to modify the asphalt in component A first, then raise the temperature to 140-160°C, and then add The remaining components heated to 140-160°C form component A, and then mix with component B to obtain the product. There are many steps in the whole preparation process and the reaction time is long, especially the nitrogen filling, vacuuming, Steps such as mechanical dispersion not only have many types of raw materials, but also high reaction temperature and high energy consumption; because the raw materials contain aliphatic epoxy resin (mostly water-based epoxy resin) after synthesis, the epoxy asphalt prepared after use Water stability is poor, and there is no explanation for the water stability test in the patent application
An application date similar to it is April 22, 2008, the application number is 200810023956.8, and the name is "Epoxy Asphalt Material for Road and Bridge and Its Green Preparation Method", which also requires the above multiple raw materials and tedious preparation process. High cost and high energy consumption
[0004] The modified asphalt of the above prior art is difficult to meet the needs of modern road construction due to the variety of raw materials, complicated preparation process and poor water stability during road construction, which is labor-intensive and time-consuming

Method used

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  • Preparation method of epoxy asphalt road surface materials
  • Preparation method of epoxy asphalt road surface materials
  • Preparation method of epoxy asphalt road surface materials

Examples

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Effect test

Embodiment 1

[0020] The steps of the preparation method of the present embodiment epoxy asphalt pavement material are as follows:

[0021] A) putting 25 parts by weight of petroleum pitch (U.S. Shell) into a reactor and heating it to 120° C. to melt it;

[0022] B) tetrahydrophthalic anhydride (Jintan Weidelong Chemical Co., Ltd.) of 1.2 weight parts, the hexahydrophthalic anhydride (Jintan Weidelong Chemical Co., Ltd.) of 1.3 parts by weight and 16 Phenyl glycidyl ether (Shanghai Bangcheng Chemical Co., Ltd.) in parts by weight was added to the melted petroleum asphalt for high-speed shearing and stirring for 25 minutes to obtain component A, and heated to 150 ° C;

[0023] C) with 15 parts by weight of bisphenol A epoxy resin (Zhenjiang Danbao Resin Co., Ltd., E-44) as component B, heated to 150 ° C,

[0024] D) Mix the above component A with component B, the ratio of parts by weight is 2.9:1, after stirring at 130°C, keep warm for 2 hours and then cool to obtain epoxy asphalt pavement ...

Embodiment 2

[0026] The steps of the preparation method of the present embodiment epoxy asphalt pavement material are as follows:

[0027] A) 50 parts by weight of oxidized bitumen (U.S. Shell) is put into a reactor and heated to 120° C. to melt it;

[0028] B) adding 6 parts by weight of trimellitic anhydride (Jintan Weidelong Chemical Co., Ltd.) and 30 parts by weight of cresol glycidyl ether (Guangzhou Cangliqi Chemical Materials Co., Ltd.) into the melted oxidized asphalt High-speed shearing and stirring for 22 minutes to obtain component A, and heating to 140°C;

[0029] C) using 40 parts by weight of bisphenol A epoxy resin (Shanghai Xinhua Resin Factory, E-51) as component B, heated to 140 ° C;

[0030] D) Mix component A and component B, the ratio of parts by weight is 2.15:1, stir at 110°C, keep warm for 1.5 hours and then cool to get epoxy asphalt pavement material, which can be used as pavement The bonding layer is used, and its properties are shown in Table 1.

Embodiment 3

[0032] The steps of the preparation method of the present embodiment epoxy asphalt pavement material are as follows:

[0033] A) putting 60 parts by weight of coal tar pitch (Jingmen Petrochemical) into a reactor and heating to 120°C to melt it;

[0034] B) adding 9 parts by weight of tetrahydrophthalic anhydride (Jintan Weidelong Chemical Co., Ltd.) and 35 parts by weight of phenol (Nanjing Zhongxu Chemical Co., Ltd.) into the melted coal tar pitch for high-speed shearing Stir for 15 minutes to obtain component A, and heat to 130°C;

[0035] C) the total epoxy resin of 33 parts by weight of the bisphenol F epoxy resin (Shanghai Xinhua Resin Factory, trade mark 6420) and the resorcinol epoxy resin (Shanghai Xinhua Resin Factory) of 17 parts by weight as group Part B, heated to 130°C;

[0036] D) Mix component A and component B, the ratio of parts by weight is 3.15:1, stir at 140°C, keep warm for 2.5 hours and then cool to get epoxy asphalt pavement material, which can be use...

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Abstract

The invention relates to a preparation method of modified asphalt, in particular to modified asphalt which is used on the road surface, belonging to the technical field of chemical materials. The invention has the beneficial effects of easy operation, low cost, low energy consumption and short solidification time, thus shortening traffic closing time and being beneficial for rapid and smooth traffic. The epoxy asphalt road surface materials prepared by the method in the invention feature high elongation; the anti-fatigue life is 10 to 30 times of that of ordinary asphalt under the action of equal fatigue stress; the epoxy asphalt road surface materials have good deformation ability and durability, have dramatic effects in preventing tracking under high temperature, resisting cracks under low temperature and resisting water damage in the rainy season and have good anti-fatigue property.

Description

technical field [0001] The invention relates to a method for preparing modified asphalt, in particular to a method for preparing modified asphalt for road surfaces, and belongs to the technical field of composite asphalt materials. Background technique [0002] Asphalt is neither a complete viscous liquid nor a complete solid elastic body, but a typical viscoelastic body. Asphalt is thermoplastic, that is, viscosity dominates at high temperatures, making it fluid; at low temperatures, elasticity dominates, making it resistant to flow. Therefore, asphalt-paved roads are prone to rutting under heavy loads during the high temperature season in summer, and shrinkage cracks are prone to appear on the pavement during the cold winter season. This reversible property greatly limits the application range of asphalt. As a result, bitumen must be modified to change ordinary thermoplastic bitumen into thermoset bitumen. [0003] The research and development and application of modifie...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): E01C19/02E01C19/08E01C19/10C08L95/00C08L63/00C08L63/02
Inventor 苏文国王世珍黄伟
Owner 江苏文昌新材料科技有限公司
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