Water-based ultraviolet curing coating

A technology of curing coatings and ultraviolet light, applied in anti-corrosion coatings, polyester coatings, epoxy resin coatings, etc., can solve the problems of no anti-corrosion effect, human skin irritation, inconvenience in use, etc., to reduce environmental and human health. Harm, improve adhesion, with reasonable effect

Active Publication Date: 2010-02-24
CNOOC CHANGZHOU PAINT & COATINGS IND RES INST +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, although the diluent contained in this paint will not volatilize into the atmosphere and cause pollution, it is irritating to human skin and brings some inconvenience to use, and it can only play an initial protective effect on metals; ZL02138207. 7 Using maleic anhydride modified epoxy acrylate as active oligomer, adding adhesion promoting resin with epoxy groups, effectively improves the adhes

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] ①Recipe see Table 1

[0016] Table 1

[0017] components

raw material name

Dosage, mass fraction (%)

Water-based photocurable resin

HUV water-based UV resin

35

acrylic emulsion

AM 185 RS

20

Photoinitiator

2-Hydroxy-2-methyl-1-phenylacetone

2.5

corrosion inhibitor

Benzotriazole

2.0

Auxiliary

Defoamer BYK022

Leveling agent BYK310

0.2

0.3

water

Deionized water

Top up to 100

[0018] Note: HUV water-based UV resin is the product brand of water-based epoxy UV resin produced by Zhongshan Zhongqiao Paint Viscose Co., Ltd.; AM 185 RS is the product brand of pure acrylic emulsion produced by French Baoshi Company; BYK022 and BYK310 are German Product grades of defoamers and leveling agents produced by BYK;

[0019] ② Preparation of paint

[0020] Add 2-hydroxy-2-methyl-1-phenylacetone to the HUV water-based UV resin to dissolve according to...

Embodiment 2

[0024] ①See Table 2 for the formula

[0025] Table 2

[0026] components

raw material name

Dosage, % by mass

Water-based photocurable resin

Desmolux XP 2587

45

acrylic emulsion

AM 185 RS

20

Photoinitiator

1-Hydroxy-cyclohexylphenylketone-1

3.5

corrosion inhibitor

Benzotriazole

2.0

Auxiliary

Defoamer BYK022

Leveling agent BYK310

0.2

0.3

water

Deionized water

Top up to 100

[0027] Note: Desmolux XP 2587 is the product brand of waterborne polyurethane acrylate produced by Bayer;

[0028] ② Preparation of paint

[0029] Add 1-hydroxy-cyclohexyl phenyl ketone-1 to Desmolux XP 2587 according to the formula amount in Table 2 to dissolve (it can be slightly heated to facilitate dissolution), and then add deionized water, AM 185 RS, and benzene three in sequence under stirring Azole, BYK022, BYK310 and stir evenly to obtain the water-based UV-curable coating...

Embodiment 3

[0033] ①Recipe see Table 3

[0034] table 3

[0035] components

raw material name

Dosage, mass fraction (%)

Water-based photocurable resin

UV VP LS 2282

60

acrylic emulsion

AM 185 RS

18

Photoinitiator

2-Hydroxy-2-methyl-1-phenylacetone

3.5

corrosion inhibitor

Benzotriazole

2-Hydroxyphosphonoacetic acid

1.5

1.5

Auxiliary

Defoamer BYK022

Leveling agent BYK310

0.2

0.3

water

Deionized water

Top up to 100

[0036] Note: UV VP LS 2282 is the product brand of waterborne polyurethane acrylate produced by Bayer;

[0037] ② Preparation of paint

[0038] While stirring, add AM 185 RS, benzotriazole, 2-hydroxyphosphonoacetic acid, BYK022, BYK310, 2-hydroxy-2-methyl-1 -Phenylacetone, deionized water and stir to obtain the water-based UV-curable coating C of the present invention;

[0039] ③ Preparation of test samples

[0040] Take the above-mentioned...

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PUM

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Abstract

The invention relates to water-based ultraviolet curing coating, containing water-based ultraviolet curing resin, a photo initiator, accessory ingredients and water; the water-based ultraviolet curingcoating is characterized in that: the water-based ultraviolet curing coating also comprises acrylic emulsion and corrosion inhibitors, all constituents are as follows by mass fraction: 15-45 percentof the water-based ultraviolet curing resin, 15-45 percent of the acrylic emulsion, 2-10 percent of photo initiators, 2-5 percent of the corrosion inhibitors, 0.2-1 percent of the accessory ingredients, and the balance of water; wherein the acrylic emulsion has the function of enhancing adhesive force, so as to greatly improve the adhesive force of the coating on a metal surface, be beneficial toimproving the anti-corrosion performance of coatings without needing reactive diluent to adjust the adhesive force of the coating and reduce the harm of the reactive diluent to environment and human body; wherein the defined amount of the corrosion inhibitors increases the anti-corrosion performance of the coating. The water-based ultraviolet curing coating is particularly suitable for protectivedecoration of the surfaces of metal bases,such as iron, aluminum, copper, nickel and the like, for a medium to long period.

Description

technical field [0001] The invention relates to a water-based ultraviolet light curing paint, which is especially suitable for medium and long-term protective decoration of metal surfaces. Background technique [0002] Metal anti-corrosion has always been a hot and difficult point in the field of metal anti-corrosion research. Although there were some measures to control corrosion in the past, metal corrosion still seriously troubled people. About 30% of the world's annual total steel is turned into useless scrap iron due to corrosion. The losses caused by corrosion all over the world are greater than the sum of losses caused by natural disasters such as volcanoes and earthquakes. At present, most of the anti-corrosion coatings developed and produced at home and abroad are solvent-based. Due to the volatility of solvents, they seriously damage the living environment to varying degrees. Therefore, reducing the solvent in anti-corrosion coatings has become an important resea...

Claims

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Application Information

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IPC IPC(8): C09D4/06C09D163/10C09D167/06C09D175/14C09D5/08
Inventor 王坚沈雪锋苟小青
Owner CNOOC CHANGZHOU PAINT & COATINGS IND RES INST
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