Rare-earth permanent magnet with high magnetic performance and high electric resistance and preparation method thereof

A rare earth permanent magnet, high resistivity technology, applied in hybrid methods, chemical instruments and methods, inductance/transformer/magnet manufacturing, etc. energy, high resistivity, and the effect of improving surface insulation

Active Publication Date: 2010-06-16
725TH RES INST OF CHINA SHIPBUILDING INDAL CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

When the bonded magnet is applied in a high-frequency alternating field, due to its low resistivity, strong eddy currents are likely to be generated on the surface of the magnet, resulting in a rapid increase in the temperature of the magnet, and the magnetic properties of the magnet will be seriously affected. Therefore, ordinary bonded rare earth It is difficult for permanent magnets to be applied in high-frequency fields
[0003] In the prior art, one method is a multi-pole electrical insulation R-Fe-B permanent magnet introduced in Japanese Patent Publication No. 8-279407, which is a sintered magnet, which is formed after the magnet is sintered. The method of vacuum evaporation is used to coat a layer of 2-10 μm polyimide resin film on the surface of the magnet to improve its insulation performance, but the magnet obtained by this method still can

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] (1) Surface coupling of magnetic powder: The magnetic powder used is NdFeB, and its composition is Nd with an average particle size of 20 μm 2 Fe 14 B, 0.1 part of titanate coupling agent NDZ401 produced by Nanjing Shuguang Chemical Co., Ltd. and 30 parts by weight of xylene organic solvent were added to 100 parts by weight of magnetic powder, and stirred by high-speed shear at a speed of 2000 rpm for 0.5h. The above solution is mixed evenly, and the magnetic powder and the coupling agent can be fully mixed by ultrasonic vibration for 0.5h, and then the mixture is heated while stirring until the solvent is volatilized, and the modified magnetic powder is dried and ground for use; (2) 1 weight part of 725-2-A bisphenol A epoxy resin produced by the No. 725 Research Institute of China Shipbuilding Industry Corporation, 725-2-F bisphenol F epoxy resin produced by the No. 725 Research Institute of China Shipbuilding Industry Corporation Add the mixed solution of 0.2 parts ...

Embodiment 2

[0024] (1) Surface coupling of magnetic powder: the magnetic powder used is samarium cobalt magnetic powder, and its composition is Sm 2 co 17 , with an average particle size of 40 μm, 2 parts by weight of titanate coupling agent NDZ401 produced by Nanjing Shuguang Chemical Co., Ltd. and 35 parts by weight of alcohol are added to 100 parts by weight of magnetic powder, and stirred by high-speed shear at a speed of 500 rpm Mix the above solution evenly for 1 hour, and vibrate the magnetic powder and the coupling agent through ultrasonic vibration for 1 hour to fully mix, then heat the mixture while stirring until the solvent is evaporated, dry the modified magnetic powder and grind it for use; (2 ) 6.5 parts by weight of 725-2-A bisphenol A epoxy resin produced by the No. 725 Research Institute of China Shipbuilding Industry Corporation, 725-2-F bisphenol F ring produced by the No. 725 Research Institute of China Shipbuilding Industry Corporation Add the mixture of 1.3 parts b...

Embodiment 3

[0027](1) Surface coupling of magnetic powder: the magnetic powder used is samarium cobalt magnetic powder, and its composition is SmCo 5 , 5 parts by weight of titanate coupling agent NDZ401 produced by Nanjing Shuguang Chemical Co., Ltd. and 30 parts by weight of xylene were added to 100 parts by weight of magnetic powder, and the above-mentioned The solution is mixed evenly, and the magnetic powder and the coupling agent can be fully mixed by ultrasonic vibration for 1.5 hours, and then the mixture is heated while stirring until the solvent is volatilized, and the modified magnetic powder is dried and ground for use; (2) 725-2-A bisphenol A epoxy resin produced by the No. 725 Research Institute of China Shipbuilding Industry Corporation, 2 parts by weight of 725-2-F bisphenol F epoxy resin produced by the No. 725 Research Institute of China Shipbuilding Industry Corporation Add the mixed solution with organic solvent acetone to 105 parts by weight of magnetic powder after s...

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Abstract

The invention relates to the technology of rare-earth permanent magnet materials, and particularly discloses a rare-earth permanent magnet with high magnetic performance and high electric resistance and a preparation method thereof. The permanent magnet comprises the following components in part by mass: 100 parts of neodymium iron boron and samarium cobalt type magnetic powder with granularity of 20 to 300 microns, 0.1 to 5 parts of titanate coupling agent, 1 to 10 parts of bisphenol A epoxy resin and 0.2 to 2 parts of bisphenol F epoxy resin; the components are evenly mixed, and then are molded to form a cured substance at the temperature field of between 20 and 200 DEG C under the orientation field of which the magnetic field intensity is 0.5 to 3T; and the preparation method for the rare-earth permanent magnet comprises the following steps: coupling the surface of the magnetic powder and the coupling agent, then mixing the magnetic powder, the coupling agent and the resin, drying and grinding the mixture, and molding the mixture at the temperature field under the orientation field. The magnetic performance of the permanent magnet of the invention can keep higher level and has no obvious decline compared with the magnetic performance of the high-end adhesive NdFeB magnet, and the electric resistance of the magnet is improved by over 10 times; and the permanent magnet has no obvious temperature rise under the high-frequency alternating field for 1 hour.

Description

technical field [0001] The invention relates to a technology in the field of rare earth permanent magnet materials, in particular to a rare earth permanent magnet with high magnetic performance and high resistivity and a preparation method thereof. Background technique [0002] Compared with sintered permanent magnets, bonded magnets have many advantages such as high cost performance, convenient forming of special-shaped magnets, high processing precision, good toughness, small magnetic deviation, and easy miniaturization. Therefore, bonded magnets have been widely used in the fields of computers, mobile communications, high-end audio, micro-special motors, sensors, and magnetoelectric instruments. When the bonded magnet is applied in a high-frequency alternating field, due to its low resistivity, strong eddy currents are likely to be generated on the surface of the magnet, resulting in a rapid increase in the temperature of the magnet, and the magnetic properties of the mag...

Claims

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Application Information

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IPC IPC(8): H01F7/02H01F41/02B01F3/12B22F3/00
Inventor 谢述锋王岳王德义
Owner 725TH RES INST OF CHINA SHIPBUILDING INDAL CORP
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