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Method for producing low-sulfur molten iron in one step by smelting and reducing copper slag

A low-sulfur molten iron and copper slag technology, applied in the field of resources and environment, can solve the problems of high sulfur content in molten iron, complex treatment process, low iron recovery rate, etc., and achieve the effect of reducing sulfur content, short process flow and reducing investment cost

Inactive Publication Date: 2012-01-11
KUNMING UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] 2. Iron is enriched in magnetite through oxidation roasting-crushing magnetic separation process. This process has the disadvantages of low iron recovery rate and complicated follow-up treatment process
However, this process has the disadvantage of high sulfur content in molten iron after copper slag smelting reduction (average content higher than 0.6%)

Method used

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  • Method for producing low-sulfur molten iron in one step by smelting and reducing copper slag
  • Method for producing low-sulfur molten iron in one step by smelting and reducing copper slag

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] When the iron reduction reaction in the molten copper slag in the reduction furnace is basically completed [the composition of the slag at this time is: CaO=33.708, SiO 2 =28.09, S=0.58, FeO=2.85 (mass percentage), molten pool temperature is 1630 ℃], the additive CaO-CaF 2 -C (oil coke) is ground to a particle size of about 0.6mm [CaO-CaF 2 -C (oil coke) is added in an amount to make the ternary alkalinity of the slag be 4.9, wherein CaF in the additive 2 The mass percent content of C (oil coke) is 9%, and the addition amount of C (oil coke) is 12% of the total mass of additive], joins in molten pool, and when it melts completely, injects carbon monoxide gas with spray gun deep molten pool to slag-iron interface place The reaction system is stirred to accelerate the desulfurization reaction, and the injection pressure of carbon monoxide gas is maintained at 1.2MPa. Under this condition, the carbon monoxide gas injection time is 30 minutes, and the spray gun is lifted ...

Embodiment 2

[0036] When the reduction reaction of iron in the molten copper slag in the reduction furnace is basically completed [at this time, the composition of the slag is: CaO=32.02, SiO 2 =29.39, S=0.62, FeO=2.74 (mass percentage), molten pool temperature is 1650 ℃], the additive CaO-CaF 2 Grind to a particle size of about 1mm (CaO-CaF 2 The amount added is to make the ternary alkalinity of the slag 5.2, and the CaF in the additive 2 The mass percentage content is 10%), put it into the molten pool, and when it is in a molten state, the spray gun is deep into the molten pool to spray carbon monoxide gas at the slag-iron interface to stir the reaction system, reduce the oxygen potential in the molten iron, and accelerate During the desulfurization reaction, the injection pressure of carbon monoxide gas was maintained at 1.32MPa. Under this condition, the carbon monoxide gas injection time is 35 minutes, and the spray gun is lifted out of the molten pool after the injection is stopped...

Embodiment 3

[0038] When the reduction reaction of iron in the molten copper slag in the reduction furnace is basically completed [at this time, the composition of the slag is: CaO=35.31, SiO 2 =26.34, S=0.54, FeO=2.73 (mass percentage), molten pool temperature is 1670 ℃], the additive CaO-BaO-CaF 2 Broken to a particle size of about 1.2mm (CaO-BaO-CaF 2 The amount of addition is enough to make the alkalinity of the slag 4.9, and the CaF in the additive 2 The mass percentage content of CaO and BaO is 10%, and the addition amount of CaO and BaO m CaO 、m BaO Satisfy the quality ratio ), into the molten pool, when it is in a molten state, the spray gun is deep into the molten pool to spray carbon monoxide gas at the slag-iron interface to stir the reaction system to accelerate the desulfurization reaction, and the injection pressure of carbon monoxide gas is maintained at 1.18MPa. Under this condition, the carbon monoxide gas injection time is 32 minutes, and the spray gun is lifted out ...

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Abstract

The invention discloses a method for producing low-sulfur molten iron in one step by melting and reducing copper slag. The method is characterized in that the method includes the following processing steps that: the high-temperature molten copper slag is first reduced by reducing agent in a high-temperature reduction furnace, wherein, when the reduction reaction of iron is nearly finished, a certain amount of additive, which is theoretically calculated, is added in a melting bath based on the existing slag system in the reduction furnace, a jet gun is inserted into a slag-iron interface to blow carbon monoxide into the melting bath when the additive is completely molten, the blowing time is 30min to 40min, and desulphurization reaction is almost finished. The melting bath is kept still, and when slag and iron are completely separated, the high-temperature low-sulfur molten iron and the slag are respectively discharged out of a tap hole and a slag hole. In addition, after high-temperature flue gas passes through a secondary combustion chamber, a residual heat boiler recovers residual heat from the flue gas, dust is collected from the flue gas by cyclone, and the flue gas is washed.By sufficiently utilizing the high desulphurization of the refined slag and blowing the carbon monoxide, the invention solves the defect that the content of sulfur in the molten iron produced by melting and reducing the copper slag for ironmaking is high; the processing flow is short, the emission of pollutant is less, and moreover, the applicability is high.

Description

technical field [0001] The invention relates to a method for preparing low-sulfur molten iron in one step through copper slag smelting reduction, which belongs to the field of resources and environment. Background technique [0002] In recent years, China's iron and steel industry has developed rapidly. my country's iron and steel industry occupies a pivotal position in the world's iron and steel industry. For more than ten years, its total iron and steel production has always occupied the first place in the iron and steel industries of all countries in the world. However, my country's iron ore resources are far from meeting the needs of the iron and steel industry, and the distribution of resources has the following characteristics: first, there are many lean ores, and the reserves of lean ores account for 80% of the total reserves; The third is that my country's iron ore resources are scarce, the grade is low, and the production capacity of steel enterprises across the coun...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C21B13/00
Inventor 王华李磊胡建杭
Owner KUNMING UNIV OF SCI & TECH
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