Aqueous rusted anti-corrosive coating and preparation method thereof

A rust and anti-corrosion, coating technology, used in anti-corrosion coatings, epoxy resin coatings, coatings and other directions, can solve the problems of solvent pollution of the construction environment, volatile organic compounds easy to pollute the environment, poor rust conversion ability, etc. Firm, dense and uniform, beneficial to environmental protection, and the effect of increasing adhesion

Active Publication Date: 2011-08-17
泰州市杰诚新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the anticorrosion of domestic steel structures still uses the old process of painting after sandblasting. Although the anticorrosion effect is good, there are also complex structural parts with dead angles, high power consumption, dust pollution, noise pollution, and cost in sandblasting and shot blasting processes. High and many shortcomings, so it is very necessary to prepare a rusty coating that can be directly applied on the rusty surface
[0003] At present, there are mainly two types of rusty coatings: solvent-based and water-soluble. Oily rusty coatings that use organic matter as a solvent or dispersion medium, because volatile organic matter is easy to pollute the environment, consumes a lot of energy, and is highly toxic. It is unsafe and the rust conversion is not complete.
For example, the invention patent CN101760109A discloses a kind of two-component solvent-based rusty primer with epoxy resin and phenolic resin as the film-forming material. Although it solves the direct coating of the thin rust surface, there are still problems such as solvent pollution of the construction environment.
Water-based rust coatings are mainly prepared with phosphoric acid, tannic acid and other systems, which have the d

Method used

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  • Aqueous rusted anti-corrosive coating and preparation method thereof
  • Aqueous rusted anti-corrosive coating and preparation method thereof
  • Aqueous rusted anti-corrosive coating and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] (1) Preparation of rust converting agent

[0027] Add 10 grams of ethanol and 10 grams of deionized water in the flask and mix well, add 8 grams of pyrogallol and 2 grams of hydroquinone to dissolve it completely, then add 2 grams of glycerol, 2 grams of citric acid and 60 gram of deionized water, stirred evenly, is the rust conversion agent;

[0028] (2) Preparation of composite polymer emulsion

[0029] Add 70 grams of styrene-acrylic emulsion and 10 grams of epoxy emulsion to the flask and stir evenly, then slowly add 20 grams of urea-formaldehyde resin glue, and stir rapidly for 10-20 minutes to form a composite polymer emulsion;

[0030] (3) Preparation of target product energy-saving and environment-friendly water-based anti-corrosion coating with rust

[0031] Add 60 grams of composite polymer emulsion and 25 grams of rust conversion agent in the flask, stir evenly, then add 0.1 gram of glycerol and 0.3 gram of ethylene glycol ethyl ether in batches, continue t...

Embodiment 2

[0039] (1) Preparation of rust converting agent

[0040] Add 8 grams of ethanol and 8 grams of deionized water into the flask, mix well, add 10 grams of pyrogallol and 2 grams of hydroquinone to dissolve completely, then add 1 gram of polyol, 1 gram of citric acid and 65 grams of Deionized water, stirred evenly, is the rust conversion agent;

[0041] (2) Preparation of target product energy-saving and environment-friendly water-based anti-corrosion coating with rust

[0042] Add 60 grams of composite polymer emulsion and 25 grams of rust conversion agent in the flask, stir evenly, then add 0.1 gram of glycerol and 0.3 gram of ethylene glycol ethyl ether in batches, continue to stir, and finally slowly add 0.1 gram of carboxymethyl cellulose and 14.5 grams of deionized water mixed solution was heated up to 40°C-50°C, stirred for 20-30 minutes to obtain the target product water-based anti-corrosion coating with rust.

[0043] The energy-saving and environment-friendly water-ba...

Embodiment 3

[0049] (1) Preparation of rust converting agent

[0050] Add 12 grams of ethanol and 12 grams of deionized water to the flask and mix well, add 7 grams of pyrogallol and 2 grams of hydroquinone to dissolve completely, then add 1 gram of sorbitol, 1 gram of tartaric acid and 65 grams of Deionized water, stirred evenly, is the rust conversion agent;

[0051] (2) Preparation of target product water-based anti-corrosion coating with rust

[0052] Add 60 grams of composite polymer emulsion and 25 grams of rust conversion agent into the flask, stir evenly, then add 0.1 grams of glycerol and 0.3 grams of ethylene glycol butyl ether in batches, continue stirring, and finally slowly add 0.1 grams of carboxymethyl cellulose After mixing with 14.5 grams of deionized water, the temperature was raised to 40°C-50°C, and stirred for 20-30 minutes to obtain the target product water-based anti-corrosion coating with rust.

[0053] The energy-saving and environment-friendly water-based rust-res...

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Abstract

The invention provides an aqueous rusted anti-corrosive coating and a preparation method thereof, belonging to the technical field of anti-corrosive coatings of steel and iron surfaces. The coating consists of the following raw materials in percentage by mass: 20-30 percent of iron rust transforming agent, 50-60 percent of composite high molecular emulsion, 0.01-0.2 percent of penetrating agent, 0.1-0.5 percent of film forming aid, 0.01-0.2 percent of thickening dispersant and 10-20 percent of deionized water. The aqueous rusted anti-corrosive coating prepared with the preparation method can be directly applied to coating of rusty steel and has high performance. The provided preparation method has the advantages of simple preparation process and low cost.

Description

Technical field: [0001] The invention belongs to the technical field of anti-corrosion coating on steel surfaces, and in particular relates to a water-based anti-corrosion coating with rust directly used on corroded steel and a preparation method thereof. Background technique: [0002] According to statistics, metals rusted due to corrosion account for more than 20% of the annual output in the world every year, and the resulting economic losses are about 100 billion U.S. dollars. The annual domestic economic loss due to corrosion accounts for about 4% of the gross national product. In order to protect steel from corrosion and prolong its service life, anti-corrosion coating on steel has become the most economical and effective method. In order to obtain excellent corrosion resistance, the rust on the steel must be removed before painting, otherwise the paint film and anti-corrosion effect will be poor due to the continuous expansion of the rust. Therefore, the rust removal t...

Claims

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Application Information

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IPC IPC(8): C09D125/14C09D163/00C09D161/24C09D5/08
Inventor 古绪鹏杨建国乔红斌潘正桂章昌华陈翔朱静
Owner 泰州市杰诚新材料有限公司
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