Wear-resistant Buna-N rubber thermoplastic elastomer composition and preparation method thereof

A thermoplastic elastomer, wear-resistant nitrile technology, applied in the field of butadiene and acrylonitrile copolymer composition and its preparation, can solve the problems of low hardness, large filling amount, modification of wear resistance, etc. The cost of raw materials, good scratch resistance, and the effect of reducing production costs

Active Publication Date: 2012-05-16
CHINA PETROLEUM & CHEM CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Rubber itself has good elasticity and is a good elastomer, which can improve the low temperature resistance, resilience and compression permanent deformation of the material. Although it has certain wear resistance, it is used in some places that require high wear resistance The industry still does not meet the requirements
At present, to improve the wear resistance of rubber materials, it is generally to choose high polymer resin with better wear resistance or add resin and filler with better wear resistance to rubber, such as adding calcium carbonate, talcum powder, and mica powder to rubber. etc. can reduce the cost of materials, adding white carbon black can impr...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~ Embodiment 3

[0044] The raw material formula of embodiment 1~embodiment 3 is listed in table 1

[0045] Table 1

[0046] raw material

[0047] Zinc stearate

Embodiment 1 and comparative example 1

[0074] The sample preparation method of embodiment 1 and comparative example 1, comparative example 2:

[0075] According to the ratio of raw materials, first put PVC, lubricant, heat stabilizer and clay into the high-low stirring mixer for low-speed stirring, add the plasticizer in three times during the stirring process, and then carry out high-speed stirring for 3-10 minutes, and then Add high-hardness wear-resistant filler (or white carbon black) and NBR and stir for 1 to 3 minutes, discharge to low-speed cooling and high-stirring to cool, and control the blending temperature not to exceed 40°C when discharging. The mixed material is extruded and granulated on a parallel twin-screw extruder, and the temperature of each zone of the extruder is controlled at 90-120°C, and the screw speed is 50-80 rpm.

Embodiment 2

[0076] The sample preparation method of embodiment 2:

[0077] After weighing each component according to the ratio of raw materials, mix them in a high-speed mixer for 2-5 minutes, and discharge the material after mixing evenly. Extrude and granulate the mixed material on a parallel twin-screw extruder. The temperature is 80-100°C, and the screw speed is 30-50 rpm.

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PUM

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Abstract

The invention discloses a wear-resistant Buna-N rubber thermoplastic elastomer composition and a preparation method thereof. The wear-resistant Buna-N rubber thermoplastic elastomer composition is prepared from Buna-N rubber, modified resin, a high-hardness silicate mineral substance and conventional auxiliary agents by blending. Raw materials of the wear-resistant Buna-N rubber thermoplastic elastomer composition comprise: by mass, 100 parts of Buna-N rubber (NBR), 0 to 60 parts of polyvinyl chloride (PVC) resin, 0 to 50 parts of styrene-butadiene-styrene block copolymer (SBS), 0 to 30 partsof a plasticizer dioctyl phthalate (DOP), 5.0 parts of a calcium-zinc composite stabilizing agent, 0 to 1.0 part of zine stearate, 0 to 0.6 parts of calcium stearate, 0.6 parts of eleaostearic acid, 0 to 0.5 parts of a composite antioxidant, 0 to 10 parts of potter's clay, and 15 to 60 parts of the high-hardness silicate mineral substance. The wear-resistant Buna-N rubber thermoplastic elastomer composition has excellent elasticity of a rubber elastomer, good scratch resistance and wear resistance and low raw material prices and can be recycled. The preparation method of the wear-resistant Buna-N rubber thermoplastic elastomer composition has simple preparation processes and a low production cost, and utilizes waste and old resources.

Description

technical field [0001] The invention is a wear-resistant nitrile rubber thermoplastic elastomer composition and a preparation method thereof. It is a copolymer of conjugated dienes. In particular, it relates to a butadiene-acrylonitrile copolymer composition and a preparation method thereof. Background technique [0002] Thermoplastic elastomers, also known as thermoplastic rubbers, combine the properties of rubber with those of thermoplastics. With the rapid development of the automobile industry, the application of TPE thermoplastic elastomers has grown rapidly, and the demand is also increasing. The performance of existing products can no longer meet the demand. The thermoplastic elastomer product with high wear resistance meets the new development needs of the material market and has a relatively broad application space and market prospect. [0003] Rubber itself has good elasticity and is a good elastomer, which can improve the low temperature resistance, resilience ...

Claims

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Application Information

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IPC IPC(8): C08L9/02C08L27/06C08L53/02C08K13/06C08K9/04C08K3/34C08K5/098
Inventor 李静王晶张新华刘容德贾小波刘浩桂俊杰王秀丽孙丽朋
Owner CHINA PETROLEUM & CHEM CORP
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