Bismuth ferrate-carbon nano tube, preparation method thereof and method for treating organic dye wastewater by utilizing bismuth ferrate-carbon nano tube
A carbon nanotube and organic dye technology, applied in the field of wastewater treatment, can solve problems such as no water treatment technology, unsuitable for household use, secondary pollution, etc., and achieve easy large-scale production and use, reduce equipment investment, and total cost. low effect
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Embodiment 1
[0036] A method for preparing bismuth ferrite-carbon nanotubes, the steps are:
[0037] (1) Dissolve iron nitrate and bismuth nitrate with the same number of moles in pure 2-methoxyethanol so that the concentrations of both iron nitrate and bismuth nitrate are 0.3 mol / L.
[0038] (2) Add 0.1mol / L nitric acid solution to the solution formed in step (1) while stirring, the volume of the added nitric acid solution is 0.05% of 2-methoxyethanol, and adjust the pH to 5.
[0039] (3) While stirring, add carbon nanotubes, citric acid with the same molar number as ferric nitrate, and ethylene glycol that is 1 / 3 of the volume of 2-methoxyethanol as a dispersant in the solution in step (2), and continue stirring for 2 Hours.
[0040] (4) Heat up to 55°C and keep at this temperature, stir for 1 hour to form a sol.
[0041] (5) Raise the temperature to 85°C and keep it at this temperature, evaporate the solvent to form a gel, take out the gel and grind it into powder and mix well;
[00...
Embodiment 2
[0050] A method for preparing bismuth ferrite-carbon nanotubes, the steps are:
[0051] (1) Dissolve iron nitrate and bismuth nitrate with the same number of moles in pure 2-methoxyethanol so that the concentrations of both iron nitrate and bismuth nitrate are 0.5 mol / L.
[0052] (2) Add 0.2 mol / L nitric acid solution to the solution formed in step (1) while stirring, the volume of the added nitric acid solution is 0.2% of 2-methoxyethanol, and adjust the pH to 7.
[0053] (3) While stirring, add carbon nanotubes, citric acid with the same molar number as ferric nitrate, and ethylene glycol that is 2 / 3 of the volume of 2-methoxyethanol as a dispersant in step (2), and continue stirring for 2.5 Hours.
[0054] (4) Raise the temperature to 65°C and keep it at this temperature, stir for 1.5 hours to form a sol.
[0055] (5) Raise the temperature to 105°C and keep it at this temperature, evaporate the solvent to form a gel, take out the gel, grind it into powder and mix well.
...
Embodiment 3
[0065] A method for preparing bismuth ferrite-carbon nanotubes, the steps are:
[0066] (1) Dissolve the same number of moles of iron nitrate and bismuth nitrate in pure 2-methoxyethanol so that the concentrations of both iron nitrate and bismuth nitrate are 0.4 mol / L.
[0067] (2) Add 0.15 mol / L nitric acid solution to the solution formed in step (1) while stirring, the volume of the added nitric acid solution is 0.15% of 2-methoxyethanol, and adjust the pH to 6.
[0068] (3) While stirring, add carbon nanotubes, citric acid with the same molar number as ferric nitrate, and ethylene glycol that is 1 / 2 the volume of 2-methoxyethanol as a dispersant to the solution in step (2), and continue stirring for 3 Hours.
[0069] (4) Raise the temperature to 60°C and keep it at this temperature, and stir for more than one hour to form a sol.
[0070] (5) Raise the temperature to 90°C and keep it at this temperature, evaporate the solvent to form a gel, take out the gel, grind it into ...
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