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Easily-degradable alkali-free viscosity reducer for thick oil and preparation method thereof

A heavy oil viscosity reducer, easy to degrade technology, applied in the field of heavy oil viscosity reducer, easy to degrade alkali-free heavy oil viscosity reducer, can solve the problems of corrosion, difficult to degrade, unfavorable demulsification and dehydration, etc. Good capacity, fast biodegradation rate, and good compatibility

Active Publication Date: 2012-10-17
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Currently the most widely used viscosity reducer, its main component is basically non-ionic alkylphenol ether surfactant (OP or NP type) or anionic surfactant alkylbenzene sulfonate or petroleum sulfonate (AS or PS), and this type of surfactant has a very stable benzene ring structure in its molecular structure, and its disadvantages are difficult to degrade, high toxicity, and easy to pollute the environment; Containing inorganic alkali components, the pH value of most viscosity reducers is slightly alkaline. Although thick oil viscosity reducers containing alkaline substances have good emulsification and viscosity reduction effects, the biggest disadvantage is that the formed oil-water emulsion is too stable. It is not conducive to the demulsification and dehydration of the combined station in the later stage, that is, this kind of viscosity reducer is not compatible with the demulsifier, and it is easy to cause fouling and corrosion of oil well strings and oil pipelines.

Method used

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  • Easily-degradable alkali-free viscosity reducer for thick oil and preparation method thereof
  • Easily-degradable alkali-free viscosity reducer for thick oil and preparation method thereof
  • Easily-degradable alkali-free viscosity reducer for thick oil and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0032] This embodiment provides an easily degradable alkali-free heavy oil viscosity reducer, which is prepared according to the following steps:

[0033] Under normal pressure, first add 55g of water into a four-necked flask equipped with an electric heating mantle, start the stirrer, adjust the rotation speed to 60-120 rpm, and raise the temperature at the same time, and the temperature is controlled at about 65°C;

[0034] Then slowly add L6415g, fatty alcohol ammonium sulfate 15g, lauryl alcohol 5g, fatty alcohol polyoxyethylene ether 10g in order, and mix and stir through 60-90 minutes, promptly obtain 100g active ingredient content and be 45wt% (mass percentage) Viscosity reducer.

[0035]Weigh 60g, 70g, 80g of dehydrated extra heavy oil with a viscosity of 12730mPa·s at 50°C, add 40g, 30g, 20g of the aqueous solution containing 0.3% (mass percentage) of the viscosity reducing agent of this embodiment respectively, and stir at 50°C After 1 minute, three parts of emulsif...

Embodiment 2

[0037] This embodiment provides an easily degradable alkali-free heavy oil viscosity reducer, which is prepared according to the following steps:

[0038] Under normal pressure, first add 40g of water into a four-necked flask equipped with an electric heating mantle, start the stirrer, adjust the speed to 60-120 rpm, and raise the temperature at the same time, and control the temperature at about 65°C;

[0039] Then slowly add L6425g, fatty alcohol ammonium sulfate 25g, lauryl alcohol 4g, fatty alcohol polyoxyethylene ether 6g in order, and through mixing and stirring for 60-90 minutes, 100g of active ingredient content is 60wt% (mass percentage) Viscosity reducer, denoted as J-2.

[0040] Weigh 60g, 70g, 80g of dehydrated super heavy oil with a viscosity of 57320mPa·s at 50°C, add 40g, 30g, 20g of the aqueous solution containing 0.3% (mass percentage) of the viscosity reducing agent of this embodiment respectively, and After stirring for 1 minute, three parts of emulsified h...

Embodiment 3

[0045] In this embodiment, the demulsification and dehydration performance test is carried out on the viscosity reducer prepared in Example 2, which specifically includes the following steps:

[0046] Measure four parts of ordinary heavy oil (water content 28wt%) with a viscosity of 2180mPa·s at 50°C and contain bound water, each part is 70mL, numbered I, II, III, IV respectively;

[0047] In I, II, add the viscosity reducer J-2 concentration that embodiment 2 prepares to be the aqueous solution 30mL of 0.3% (mass percentage), in III, IV, add PS viscosity reducer (produced by Huayou Industrial Company of Liaohe Oilfield) 0.3 % (mass percentage) aqueous solution of 30mL, stirred at 50°C for 1 minute, after all the emulsions are formed, then add 2-3 drops of demulsifier P-1 (TR-DEM / LY-IV type) to II and IV respectively Water-soluble crude oil demulsifier, produced by Liaohe Oilfield Huayou Hongshan Chemical Factory), mix and stir evenly, then quickly transfer I, II, III, and IV ...

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PUM

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Abstract

The invention relates to an easily-degradable alkali-free viscosity reducer for thick oil and a preparation method thereof. The viscosity reducer consists of propylene glycol block polyether, fatty alcohol ammonium sulfate, fatty alcohol, a penetrating agent and water; and in terms of the total mass of the viscosity reducer, the sum of mass percent of propylene glycol block polyether, fatty alcohol ammonium sulfate, fatty alcohol and the penetrating agent is 45 to 60 wt%. The invention also provides the preparation method for the viscosity reducer, and the method comprises the following steps: successively adding propylene glycol block polyether, fatty alcohol ammonium sulfate, fatty alcohol and the penetrating agent into water at a temperature of 50 to 80 DEG C under normal pressure, wherein a mass ratio of the four above-mentioned raw materials to water is 15: 15: 5: 10: 55 to 25: 25: 4: 6: 40; and carrying out continuous stirring for 60 to 90 min at a rotating speed of 60 to 120 r / min while adding the four raw materials so as to obtain the easily-degradable alkali-free viscosity reducer for thick oil. Surfactant used in the viscosity reducer is nonionic and anionic surfactant, the structure of benzene rings is not included in a molecule, and therefore, the characteristics of easy degradability, no toxicity, greenness and environment friendliness are obtained.

Description

technical field [0001] The invention relates to a heavy oil viscosity reducer, in particular to an easily degradable alkali-free heavy oil viscosity reducer, which belongs to the technical field of petroleum exploitation. Background technique [0002] At present, two methods of mixing thin oil and electric heating have been used in the wellbore lifting process of heavy oil and ultra-heavy oil, and the surface pipeline adopts high-temperature heat-tracing transportation technology. The lifting process of heavy oil mixed with thin oil has the problems of loss of price difference between thin oil and heavy oil and the reduction of thin oil that can be mixed. The problem of high consumption has greatly increased the production cost per ton of oil. [0003] The use of heavy oil viscosity reducer in heavy oil production, lifting, gathering and transportation is an effective chemical viscosity reduction method with low cost and low energy consumption. Its main mechanism is to make...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/584F17D1/17E21B43/22
Inventor 尉小明岳志强熊梅龙华李德胜王俊良赵建飞孙睿单振邦曲冬雪
Owner PETROCHINA CO LTD
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