Self-assembly preparation method for nano-pillar array compound semiconductor device
A nano-pillar array and semiconductor technology, applied in semiconductor devices, semiconductor lasers, laser parts, etc., can solve the problems of high dislocation density and small light-emitting area, reduce energy band bending, increase light-emitting area, and reduce dislocations. Effect
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Embodiment 1
[0039] Embodiment 1, nanocolumn array gallium nitride light-emitting diode self-assembly preparation technology, including the following steps:
[0040] 1. The temperature of the MOCVD reaction chamber was raised to 500°C, and trimethylgallium was introduced for 3 minutes, and a decomposition reaction occurred on the Si (0001) substrate to form a 10nm metal thin layer.
[0041] 2. After raising the temperature to 900°C for 3 minutes, the metal condenses into small balls with a density of 2.3×10 6 cm -2 , the diameter of the pellet is 400-600nm, and the duty cycle is 65%.
[0042] 3. Keep the temperature at 900° C., inject hydrogen, trimethylgallium and ammonia gas for 2 minutes, and gallium nitride nuclei are formed at the bottom of the gold particles, with a diameter of 400-600 nm.
[0043] 4. The temperature is raised to 1000°C, and hydrogen, trimethylgallium (50 liters / minute) and ammonia gas are introduced for 20 minutes, wherein the V / III ratio is 200, and the gallium n...
Embodiment 2
[0049] Embodiment 2, nanocolumn array gallium nitride laser self-assembly preparation technology, including the following steps:
[0050] 1. The temperature of the MOCVD reaction chamber was raised to 550°C, and trimethylgallium was introduced for 4 minutes, and a decomposition reaction occurred on the Si (0001) substrate to form a thin metal layer of 8nm.
[0051] 2. After 3 minutes, the temperature is raised to 850°C, and the metal condenses into small balls with a density of 2.0×10 6 cm -2 , the diameter of the pellet is 400-600nm, and the duty cycle is 65%.
[0052] 3. Keep the temperature at 900° C., inject hydrogen, trimethylgallium and ammonia gas for 2 minutes, and gallium nitride nuclei are formed at the bottom of the gold particles, with a diameter of 400-600 nm.
[0053] 4. The temperature is raised to 1000°C, and hydrogen, trimethylgallium (50 liters / minute) and ammonia gas are introduced for 20 minutes, wherein the V / III ratio is 200, and the gallium nitride cry...
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