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Self-assembly preparation method for nano-pillar array compound semiconductor device

A nano-pillar array and semiconductor technology, applied in semiconductor devices, semiconductor lasers, laser parts, etc., can solve the problems of high dislocation density and small light-emitting area, reduce energy band bending, increase light-emitting area, and reduce dislocations. Effect

Active Publication Date: 2012-12-26
EPITOP PHOTOELECTRIC TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0007] The purpose of the present invention is to overcome the defects of the above-mentioned traditional existing methods, and solve the problem of excessive dislocation density generated in the process of growing semiconductor devices by traditional methods
In addition, the device design of the nanopillar array can solve the defect that the light-emitting area of ​​the semiconductor device is too small, and improve the utilization rate of light.

Method used

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  • Self-assembly preparation method for nano-pillar array compound semiconductor device
  • Self-assembly preparation method for nano-pillar array compound semiconductor device
  • Self-assembly preparation method for nano-pillar array compound semiconductor device

Examples

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Embodiment 1

[0039] Embodiment 1, nanocolumn array gallium nitride light-emitting diode self-assembly preparation technology, including the following steps:

[0040] 1. The temperature of the MOCVD reaction chamber was raised to 500°C, and trimethylgallium was introduced for 3 minutes, and a decomposition reaction occurred on the Si (0001) substrate to form a 10nm metal thin layer.

[0041] 2. After raising the temperature to 900°C for 3 minutes, the metal condenses into small balls with a density of 2.3×10 6 cm -2 , the diameter of the pellet is 400-600nm, and the duty cycle is 65%.

[0042] 3. Keep the temperature at 900° C., inject hydrogen, trimethylgallium and ammonia gas for 2 minutes, and gallium nitride nuclei are formed at the bottom of the gold particles, with a diameter of 400-600 nm.

[0043] 4. The temperature is raised to 1000°C, and hydrogen, trimethylgallium (50 liters / minute) and ammonia gas are introduced for 20 minutes, wherein the V / III ratio is 200, and the gallium n...

Embodiment 2

[0049] Embodiment 2, nanocolumn array gallium nitride laser self-assembly preparation technology, including the following steps:

[0050] 1. The temperature of the MOCVD reaction chamber was raised to 550°C, and trimethylgallium was introduced for 4 minutes, and a decomposition reaction occurred on the Si (0001) substrate to form a thin metal layer of 8nm.

[0051] 2. After 3 minutes, the temperature is raised to 850°C, and the metal condenses into small balls with a density of 2.0×10 6 cm -2 , the diameter of the pellet is 400-600nm, and the duty cycle is 65%.

[0052] 3. Keep the temperature at 900° C., inject hydrogen, trimethylgallium and ammonia gas for 2 minutes, and gallium nitride nuclei are formed at the bottom of the gold particles, with a diameter of 400-600 nm.

[0053] 4. The temperature is raised to 1000°C, and hydrogen, trimethylgallium (50 liters / minute) and ammonia gas are introduced for 20 minutes, wherein the V / III ratio is 200, and the gallium nitride cry...

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Abstract

A self-assembly preparation method for a nano-pillar array compound semiconductor device comprises the following steps: (1) pumping a layer of metal source reactant into the surface of a conductive substrate in advance; (2) annealing to form metal island particles; (3) pumping in III and V reactants for epitaxial growth of a semiconductor nano-pillar array; (4) accelerating lateral growth of semiconductor nano-pillars and doping an N-type impurity into a source substance to form a semiconductor nano-pillar array of which the surface is N-type; (5) depositing an insulating layer on the surfaces of the nano-pillars and the exposed surface of the conductive substrate among the nano-pillars and etching the insulating layer on the side walls of the nano-pillars through an etching liquid; (6) forming nano-pillar array devices on the surfaces of the nano-pillars; (7) filling a conductive substance among the nano-pillar arrays to form an electrode layer; and (8) manufacturing P-type electrodes in the electrode layer and manufacturing N-type electrodes on the conductive substrate.

Description

technical field [0001] The invention relates to the preparation of a nano-column array compound semiconductor device, in particular to a method for growing high-quality gallium nitride light-emitting diodes and gallium nitride lasers by vapor phase epitaxy. Background technique [0002] The wide bandgap material represented by gallium nitride (GaN) is the third-generation semiconductor material after Si and GaAs, and is used to make electronic devices such as light-emitting diodes, lasers, detectors, and high-frequency high-power transistors. [0003] Since high-quality commercial bulk GaN crystals are not yet available, heterogeneous substrates are generally used to epitaxially obtain GaN thin films. However, there is a large lattice mismatch between GaN and sapphire substrate (or Si substrate), resulting in dislocations in the epitaxial layer, which will spread and pass through the entire epitaxial layer, limiting the performance of GaN devices improvement. In order to r...

Claims

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Application Information

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IPC IPC(8): H01L33/02H01L33/00H01S5/343
Inventor 黄小辉周德保杨东黄炳源康建梁旭东
Owner EPITOP PHOTOELECTRIC TECH