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Carbon nanotube/short-fiber composited nano-carbon paper and continuous preparation method thereof

A technology of carbon nanotubes and short fibers, which is applied in the direction of fiber dispersant addition, paper, papermaking, etc., can solve the problems that it is difficult to prepare large-sized products, the preparation efficiency cannot be improved, and the brittleness of nano-carbon paper is large. The effect of broad commercialization prospects and low equipment requirements

Inactive Publication Date: 2013-01-16
SUZHOU INST OF NANO TECH & NANO BIONICS CHINESE ACEDEMY OF SCI
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  • Application Information

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Problems solved by technology

[0007] Among them, the first two methods are limited by equipment, and the preparation efficiency has not been improved, which seriously limits their large-scale production. As for the third method, although it can achieve relatively low cost to prepare nano-carbon paper, but due to the dispersion of carbon nanotubes The process is severely cut off, resulting in the brittleness of the nano-carbon paper obtained by filtration, which makes it difficult to prepare large-sized products. At the same time, the nano-scale carbon nanotubes make the efficiency of the filtration process very low. Continuous and high-efficiency preparation must be solved, so also very difficult to achieve

Method used

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  • Carbon nanotube/short-fiber composited nano-carbon paper and continuous preparation method thereof
  • Carbon nanotube/short-fiber composited nano-carbon paper and continuous preparation method thereof
  • Carbon nanotube/short-fiber composited nano-carbon paper and continuous preparation method thereof

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preparation example Construction

[0040] As another aspect of the technical solution of the present invention, the continuous preparation method of the carbon nanotube / short fiber composite nanocarbon paper comprises the following steps:

[0041] First, the carbon nanotubes are dispersed in a solvent with the aid of a dispersant to form a dispersion;

[0042] Subsequently, the short fibers are slowly mixed into the dispersion liquid under low-speed stirring, and the short fibers are well dispersed by high-speed shearing to obtain a slurry;

[0043] Then, the above-mentioned slurry is formed into a film by vacuum-assisted casting to form an initial composite nano-carbon paper, and the dispersant is removed through post-treatment to obtain a composite nano-carbon paper.

[0044] Further, the dispersion process of the aforementioned carbon nanotubes may adopt any one of high-speed shear dispersion, ultrasonic dispersion, grinding dispersion and ball mill dispersion, but is not limited thereto.

[0045] The foreg...

Embodiment 1

[0052] Example 1 Weigh 30 grams of multi-walled carbon nanotubes, dissolve them in 1 liter of Triton-100 aqueous solution with a concentration of 1%, then use a grinder to grind and disperse, stir and disperse at a speed of 3000 rpm for 1 hour, and sieve through a 200-mesh filter to obtain Uniform carbon nanotube dispersion ("dispersion" for short); add 5 grams of chopped carbon fibers with a length of 3 mm in slow stirring, and the weight ratio of carbon nanotubes to carbon fibers is 6:1. Disperse in a cutting disperser with a rotation speed of 3000 rpm, disperse for 20 minutes to form a stable slurry, and stand for 20 minutes to defoam before proceeding to film-forming processing. Afterwards, an initial composite nano-carbon paper with a thickness of 70 microns was prepared by means of a vacuum-assisted casting film-forming device, and the polymer was washed off after subsequent leaching, and the carbon paper could be directly peeled off from the filter membrane to obtain a...

Embodiment 2

[0054] Example 2 This embodiment is basically the same as Embodiment 1, the difference is that the weight ratio of carbon nanotubes to carbon fibers is 8:1, Figure 3a-Figure 3c Shown is the scanning electron micrograph of the carbon nano paper prepared in this embodiment.

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Abstract

The invention provides a kind of carbon nanotube / short-fiber composited nano-carbon paper and a continuous preparation method thereof. The nano-carbon paper mainly comprises disordered carbon nanotubes and short fibers, and is in a non-woven form. The preparation method of the nano-carbon paper comprises the following steps that: the disordered carbon nanotubes are dispersed in a solvent so as to form a dispersion liquid; then, mixing and dispersing the short fibers so as to form a size; preparing an initial film through vacuum assisted flow-casting film-forming; and then, removing polymers in the initial film through subsequent processing so as to obtain a target product. The composited nano-carbon paper disclosed by the invention integrates the huge specific surface areas, superior conductivity and functional characteristics of the carbon nanotubes and the enhancement effect of the short fibers on the strength and flexibility of the carbon paper, therefore, the composited nano-carbon paper is good in self-supporting property and flexibility; meanwhile, through the direct film-forming implemented by using a flow-casting method, the continuous film-forming of the nano-carbon paper is realized, therefore, the nano-carbon paper has the advantages of high efficiency, rapidness and easy large-scale preparation. The composited nano-carbon paper disclosed by the invention has a wide application prospect in the fields of energy electrodes, catalytic carriers, environmental management, static resistance, electromagnetic shielding, wave-absorbing camouflage, and the like.

Description

Technical field [0001] The present invention specially involves a carbon nanotuba / short -fiber composite nano -carbon paper and its continuous preparation method, which belongs to the field of nano -carbon material preparation technology. Background technique [0002] Nano -carbon paper is a non -woven form composed of disorderly carbon nanotubes. It is the simplest macro material form of carbon nanotubes. It has the characteristics of light quality, flexible, conductive, thermal conductivity and huge surface area.Its excellent functional characteristics have important application prospects in the fields of electrode materials, environmental materials, filter materials, catalytic carriers, electronic materials, etc., and are new carbon paper products after traditional carbon fiber paper and graphite paper.Due to the size of the carbon nanopotranskin in nano -scale, traditional carbon paper processing and preparation technology cannot be used to prepare nano -carbon paper. It is u...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D21H27/00D21H15/02D21H21/08
Inventor 李清文陈名海蔡锋陈宏源
Owner SUZHOU INST OF NANO TECH & NANO BIONICS CHINESE ACEDEMY OF SCI
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