Smokeless smellless inorganic nano high-temperature-resistant corrosion-resistant wear-resistant paint and preparation method thereof

An inorganic nano, anti-corrosion and wear-resistant technology, applied in the field of materials, can solve problems such as pungent odor, inconvenient use for customers, easy yellowing, etc., achieve good high-temperature heat insulation, save material consumption, and enhance the effect of cross-linking density

Inactive Publication Date: 2013-02-13
CHANGSHA HUANGMEI PAINT
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] CN100587017C discloses a solvent-based organosilicon ultra-high-temperature resistant coating and its production method, which can withstand high temperatures of 450-500 degrees, but the pyrolysis of organic resins will still produce some pungent and toxic odors, and will change color
Can only do very few colors of black and silver black, can not do light and bright colors
[0005] CN102030906A discloses the preparation of an organic-inorganic hybrid resin for high-temperature-resistant heavy-duty anti-corrosion coatings, which can withstand a certain high temperature, but does not specify how much high temperature it can withstand, and cannot be used at 600-800 degrees for a long time
At the same time, due to the use of a large amount of epoxy silane monomer in the formula, it is easy to yellow when it exceeds 280 degrees
[0006] CN102351497A discloses a high-temperature-resistant environment-friendly nano-modified inorganic coating and its preparation method and application, which can withstand high temperatures of 700-1000 degrees, but the film thickness must be as high as 45-80um to have good high-temperature resistance and anti-corrosion performance, and only for alloy parts It has excellent high-temperature anti-corrosion effect, but it has poor protection effect on ordinary steel parts. At the same time, aluminum tripolyphosphate and zinc powder are added to the coating as the curing agent of potassium silicate coating, which will cause the coating to have a very short shelf life. When used, it must be used up as soon as possible, otherwise it will be gelled and scrapped, resulting in loss
[0007] CN102190940A discloses a high-temperature-resistant anti-corrosion coating for engineering machinery exhaust pipes, which can only withstand a temperature of 500 degrees, and can only be made in black, and will produce a large amount of pungent odor at high temperatures
[0008] CN102167570A discloses a composite nano high-temperature coating and its preparation method and application method. The process is cumbersome and takes a long time. It must be aged for 7-10 days before entering the next process.
However, due to the use of siloxane-modified acrylic resin as the base material, it is prone to yellowing at high temperatures and can only be made into silver black. At the same time, the coating is anti-corrosion by adding up to 35% aluminum powder to achieve high-temperature melting and secondary film formation. Because a large amount of aluminum powder will soften and melt at high temperature, the coating has no thermal hardness, and the wear resistance is extremely poor at high temperature. At the same time, special ultrasonic vibration is used for coating. Compared with the conventional process, it is extremely inconvenient for customers to use.
And the paint also uses some toxic trimethylbenzene as solvent, which is not environmentally friendly
[0010] The above organic or inorganic high-temperature-resistant coatings have poor high-temperature and anti-corrosion effects and poor wear-resisting effects when thinly applied.

Method used

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  • Smokeless smellless inorganic nano high-temperature-resistant corrosion-resistant wear-resistant paint and preparation method thereof
  • Smokeless smellless inorganic nano high-temperature-resistant corrosion-resistant wear-resistant paint and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Add 50kg of 10 nanometer to 20 nanometer silica dispersion, 20kg of 30 nanometer to 50 nanometer silica dispersion, and 30kg of 60 nanometer to 90 nanometer silica dispersion into a jacketed water-cooled pull cylinder, start stirring, and then put in 8kg Acetic acid, adjust the PH value to 4, then increase the temperature to 50 degrees, start dripping a mixture of 45kg methyltrimethoxysilane, 4.5kg dimethyldimethoxysilane, 0.5kg glycidyl ether trimethoxysilane, Finish the drop within 30 minutes, keep the reaction temperature at 60 degrees, react at a constant temperature for 3 hours, then add 1.5 kg of accelerator HMT, keep the reaction for 30 minutes, stop heating, cool down, and obtain an inorganic nanometer with the appearance of a semi-opaque transparent viscous liquid Resin. The solid content of inorganic nano-resin is 35.6%, the pencil hardness is 9H, the gloss is 58°, and the temperature resistance is 1000°.

[0036] The prepared 50kg inorganic nano resin, 15kg env...

Embodiment 2 Embodiment 17

[0038] The preparation methods of Examples 2 to 17 are the same as those of the Examples, and for the formula, please refer to Table 1 and Table 2:

[0039] Table 1: Formulations of Example 2 to Example 9

[0040]

[0041] Table 2: Formulations of Example 10 to Example 17

[0042]

[0043] For its main performance indicators, please refer to Table 3 and Table 4:

[0044] Table 3: Main performance indexes of Example 2 to Example 9

[0045] Serial number

Indicator name

Example 2

Example 3

Example 4

Example 5

Example 6

Example 7

Example 8

Example 9

1

Solid content

35

42

48

35.5

35

35

34

34

2

Pencil hardness

9H

9H

7H

9H

9H

9H

9H

9H

3

Luster

55°

68°

75°

65°

61°

60°

40°

67°

4

Temperature resistance

1000°

800°

600°

1000°

1000°

1000°

1000。

600°

[0046] Table 4: Main performance indexes of Example 10 to Example 17

[0047] Serial number

Indicator name

Example 10

Example 11

Example 12

Example 13

Example 14

Example 15

Example 16

Example 17

1

Soli...

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Abstract

The invention discloses a smokeless smellless inorganic nano high-temperature-resistant corrosion-resistant wear-resistant paint and a preparation method thereof. The wear-resistant paint comprises an inorganic nano resin and a mixed solvent, wherein the inorganic nano resin is prepared from the following components in percentage by weight: 30-90% of silicon dioxide, 10-70% of silane, 0.1-10% of pH value regulator and 0.01-1% of accelerator HMT (hexamethylenetetramine); and the mixed solvent is prepared from high-temperature-resistant environment-friendly pigment, filler, ethanol and water. The preparation method comprises the following steps: mixing the nano silicon dioxide dispersion with different particle sizes, adding the pH regulator and mixed silanes, carrying out thermostatic reaction, adding the metered accelerator HMT, and keeping the temperature to react, thereby obtaining the inorganic nano resin; and mixing the prepared inorganic nano resin and the mixed solvent, dispersing with a high-speed dispersion machine at high speed, and grinding to obtain the smokeless smellless inorganic nano high-temperature-resistant corrosion-resistant wear-resistant paint. The smokeless smellless inorganic nano high-temperature-resistant corrosion-resistant wear-resistant paint is smokeless, smellless and environment-friendly, does not discolor, has high wear resistance, and has favorable functions of corrosion resistance and rust prevention.

Description

Technical field [0001] The invention belongs to the technical field of materials, and particularly relates to a smokeless and odorless inorganic nano high-temperature, anticorrosive and wear-resistant paint and a preparation method thereof. Background technique [0002] Wear-resistant coatings are mainly used for high-temperature anti-corrosion and wear-resistant protection of engineering machinery and automobile exhaust pipes; anti-corrosion and flame-retardant protection of steel structures; wear-resistant, flame-retardant and fire-resistant protection of subway and tunnel decorative panels; gas hot water exchangers , Heat-resistant and anti-corrosion protection of boiler heat exchangers; wear-resistant, anti-corrosion, and flame-retardant protection of burners, fireplaces, and kitchenware in contact with open flames. [0003] CN101503598A discloses a solvent-type organic silicon flame-resistant paint, which can withstand 500-800 degrees. Open flame does not emit smoke, and blac...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D1/00C09D7/12
Inventor 宋海兵
Owner CHANGSHA HUANGMEI PAINT
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