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Method for manufacturing conductive polyester fibers

A technology of polyester fiber and manufacturing method, which is applied in the manufacture of conductive polyester fiber and the field of functional polyester fiber manufacturing, can solve the problems of lack of elasticity, conductivity, fiber strength not as good as metal conductive fiber, and metal conductive fiber hard, etc., to achieve Durable self-generated conductivity, good self-generated conductivity, and the effect of improving fracture strength

Active Publication Date: 2013-03-20
ZHEJIANG SCI-TECH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The volume resistivity of polymer polyester fiber at room temperature is as high as 10 13 Ω.cm, usually considered as an insulator fiber, for many years scientific and technological workers have used ordinary fiber-forming polymers as a matrix to develop conductive fibers of polymer materials by adding conductive substances, so that the fibers have conductive properties and at the same time Combined with the excellent processing performance of ordinary synthetic fibers, it becomes a functional fiber with spinnability; but the conductivity and fiber strength of polymer matrix conductive fibers are not as good as metal conductive fibers, and metal conductive fibers are too hard and lack elasticity. very limited in use

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] The manufacture method of conductive polyester fiber of the present invention is characterized in that in the described steps:

[0034] A) According to the number of parts by mass, take 15 copies of tetraacicular zinc oxide whiskers with a diameter of 0.2-1um and a length of 5-15um; 5 copies of electrical conductivity with a diameter of 0.2-0.6um and a length of 5-12um Potassium titanate whiskers; after mixing the above materials evenly, roast in a vacuum furnace at 350°C for 5 hours; after cooling, stir and disperse with sodium hexametaphosphate in absolute ethanol, and treat with plasma at normal pressure for 15 minutes; then use 65°C containing stearin Ultrasonic dispersion and cleaning in deionized water of calcium acid dispersion for 30 minutes, take the suspended whiskers in the upper layer of the solution and filter through 120 meshes, take the modified whiskers mixed solution, and repeat the operation 4 times until filtering; after filtering, dry in a vacuum oven...

Embodiment 2

[0039] The manufacture method of conductive polyester fiber of the present invention, in described step:

[0040] A) According to the number of parts by mass, take 15 copies of tetraacicular zinc oxide whiskers with a diameter of 0.2-1um and a length of 5-15um; 5 copies of electrical conductivity with a diameter of 0.2-0.6um and a length of 5-12um Potassium titanate whiskers; after mixing the above materials evenly, roast in a vacuum furnace at 350°C for 5 hours; after cooling, stir and disperse with sodium hexametaphosphate in absolute ethanol, and treat with plasma at normal pressure for 15 minutes; then use 65°C containing stearin Ultrasonic dispersion and cleaning in deionized water of calcium acid dispersion for 30 minutes, take the suspended whiskers in the upper layer of the solution and pass through 120 meshes, take the modified whiskers mixed solution, and repeat the operation 4 times until filtering; after filtering, dry in a vacuum oven, A modified whisker mixture i...

Embodiment 3

[0044] The manufacture method of conductive polyester fiber of the present invention, it adopts following steps:

[0045] A) According to the number of parts by mass, take 12 copies of tetraacicular zinc oxide whiskers with a diameter of 0.2-1um and a length of 5-15um; 3 copies of electrical conductivity with a diameter of 0.2-0.6um and a length of 5-12um Potassium titanate whiskers; after mixing the above materials evenly, bake in a vacuum furnace at 300°C for 4 hours; after cooling, stir and disperse with sodium hexametaphosphate in absolute ethanol, and treat with plasma at normal pressure for 10 minutes; then use 60°C containing stearin Ultrasonic dispersion and cleaning in deionized water of calcium acid dispersion for 25-35min, take the suspended whiskers in the upper layer of the solution and filter through 100 mesh, take the modified whisker mixed solution, and repeat the operation 3 times until filtering; drying to obtain the modified whisker mixture;

[0046] B) Tak...

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PUM

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Abstract

The invention discloses a method for manufacturing conductive polyester fibers. The method comprises the following steps of: adding conductive materials including ATO conductive powder, superconducting carbon black, zinc oxide whiskers, potassium titanate whiskers and the like into polyester to prepare conductive polyester; and taking the conductive polyester as a skin layer to prepare polyester conductive fibers with other polyesters through a composite spinning technology. Through the method, the skin layer part of the fibers contains conductive substances, so that the fibers have excellent physical and processing performance of synthetic fibers while having conductivity, the resistivity of the polyester fibers can be greatly reduced, and the breaking strength of the fibers can also be improved.

Description

technical field [0001] The invention relates to a method for manufacturing conductive polyester fiber, including ATO conductive powder, superconducting carbon black, zinc oxide whisker (ZnO), conductive potassium titanate whisker (PTW) and other fiber manufacturing methods, belonging to functional polyester Fiber Manufacturing Technology. Background technique [0002] Polyester fiber is made of polyethylene terephthalate, and the trade name in China is polyester, which is currently the largest variety of synthetic fiber. Polyester fiber is an ideal textile raw material. Because of the high rigidity of the fiber macromolecular chain and high elastic modulus, the fiber is not easily deformed. It is easy to wash and dry; it also has good heat resistance, sun resistance and abrasion resistance, and can be used at -70-170 °C; in industry, high-strength polyester can be used as tire cords, conveyor belts, fire hoses, cables, Fishing nets, etc., can also be used as electrical ins...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F8/14D01F1/09D01D5/34
Inventor 凌荣根韩晨凌晓龙姜萌齐庆莹
Owner ZHEJIANG SCI-TECH UNIV
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