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Method for conditioning and dehydrating residual sludge

A technology for excess sludge and sludge, applied in the direction of dewatering/drying/concentrating sludge treatment, etc., can solve problems such as difficulty in filtering and sticking to filter cloth, smaller sludge floc particles, affecting practical applicability, etc. The effect of dewatering cost, improving dewatering performance and reducing sludge moisture content

Active Publication Date: 2013-04-10
北京方兴科创环境科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The patent application number 200810198538.2 uses the surfactant dodecyldimethylbenzyl ammonium chloride to treat the sludge, which can reduce the specific resistance of the sludge, but the inventor found that the single use of dodecyldimethylbenzyl Although ammonium chloride can peel off part of the EPS and reduce the bound water content, the sludge floc particles become smaller, which is easy to block the filter holes of the filter cloth, making it difficult to filter and stick to the filter cloth.
The patent with the application number 200810198539.7 discloses an additive and dehydration method for sludge dewatering, including cationic surfactant with a weight ratio of 1.42%-2.07% of sludge solid content, 4.92%-10.18% polyaluminum chloride And polyacrylamide, 5%-10% of the medium after picking edible mushrooms, but the use of polyacrylamide can lead to the re-agglomeration of EPS dispersed in water, without using the reduction of the water content of sludge, while the edible mushroom picking medium There are many types, and the materials and properties used are quite different, which greatly affects its practical applicability.

Method used

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  • Method for conditioning and dehydrating residual sludge
  • Method for conditioning and dehydrating residual sludge
  • Method for conditioning and dehydrating residual sludge

Examples

Experimental program
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Effect test

Embodiment 1

[0033] Add 200kg of excess sludge with a moisture content of 90.5% in a sewage treatment plant to 1.0 mol / L sulfuric acid (H 2 SO 4 ) solution is adjusted to a pH value of 4.6; adding quality quaternary ammonium salt cationic organic matter (tetradecyl dimethyl benzyl ammonium chloride and cetyl trimethyl ammonium chloride with a molar ratio of 6.6% of sludge dry weight 2.5:1), with a stirring intensity of 100r / min, stirring for 15 min; after that, adding silica (SiO 2 ), with a stirring intensity of 300r / min, stirring for 5 min; then, adding a coagulant polyaluminum chloride (PAC) with a mass of 2.0% of the dry weight of the sludge to the sludge, and stirring at a stirring intensity of 120r / min, Stirring for 6.5 min; the treated sludge was dewatered by pressure filtration, and the water content of the sludge dropped to 43.6% after dehydration.

Embodiment 2

[0035] 55kg of excess sludge with a water content of 92.7% in a certain sewage treatment plant was added to a hydrochloric acid (HCl) solution with a concentration of 1.3 mol / L to adjust to a pH value of 5.3; Alkyl dimethyl benzyl ammonium chloride and cetyl trimethyl ammonium chloride at a molar ratio of 4:1), with a stirring intensity of 60 r / min, stirring for 10 min; after that, adding mass of Calcium silicate (CaSiO 3 ), with a stirring intensity of 500 r / min, stirring for 3 min; then, adding a coagulant polyaluminum ferric chloride (PAFC) with a mass of 4.4% of the dry weight of the sludge to the sludge, and stirring at a stirring intensity of 150 r / min Stirring intensity, stirring for 5 minutes; the treated sludge is dehydrated by pressure filtration, and the moisture content of the sludge is reduced to 44.9% after dehydration.

Embodiment 3

[0037] Add 1.5 mol / L acetic acid (CH 3 COOH) solution was adjusted to a pH value of 6.0; adding quaternary ammonium salt cationic organic matter (octadecyl dimethyl benzyl ammonium chloride and cetyl trimethyl ammonium chloride in moles) was 8.0% of sludge dry weight ratio 3:1), with a stirring intensity of 50 r / min, stirring for 20 min; after that, adding calcium silicate (CaSiO 3 ), with a stirring intensity of 450r / min, stirring for 4.5 min; then, adding a coagulant polyaluminum ferric chloride (PAFC) with a mass of 3.5% of the dry weight of the sludge to the sludge, and stirring at a stirring intensity of 100r / min , stirred for 5.5 minutes; the treated sludge was dewatered by pressure filtration, and the water content of the sludge dropped to 40.2% after dehydration.

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Abstract

The invention relates to the technical field of residual sludge treatment, in particular to a process method for conditioning and dehydrating residual sludge. The method particularly comprises the following steps: (1) adding acid into the residual sludge to be treated and with the water content of 90 to 95 percent and adjusting until the pH value is between 4.0 and 6.0; (2) adding quaternary ammonium salt cationic organic matters into the conditioned sludge in the step (1) and performing hybrid reaction; (3) adding a dehydration aid into the conditioned sludge in the step (2) and stirring uniformly; and (4) adding coagulant into the conditioned sludge in the step (3) and mechanically dehydrating after mixing and stirring. The extracellular polymers on sludge flocs are stripped and partially hydrolyzed by a chemical conditioning mode, microbial cells are dissolved, a large amount of bound water is released, and the water permeability of the sludge is improved by utilizing the aid, so that the dehydration performance of the sludge is integrally improved, the water content of the sludge is reduced, the dehydration time is shortened and the dehydration cost is reduced.

Description

technical field [0001] The invention relates to the technical field of excess sludge treatment, in particular to a process method for conditioning and dehydrating excess sludge. technical background [0002] With the development of our country's society and urbanization, the amount of urban sewage is increasing, the number of corresponding sewage treatment facilities is also increasing, and the by-product of sewage treatment - sludge is also increasing. How to properly handle and dispose of these increasingly large amounts of sludge has become an urgent problem to be solved in my country's environmental protection. [0003] At present, the sludge dewatering process and dehydration equipment of most domestic sewage treatment plants can only reduce the moisture content of sludge from more than 98% to 80%, which cannot meet the requirements of most sludge disposal processes for low sludge moisture content. [0004] After the sludge is treated by biological method, the water in...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F11/14
Inventor 邢奕洪晨姜长禄余广炜张坤
Owner 北京方兴科创环境科技有限公司
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