Amino stoving varnish capable of being cured quickly at low temperature

An amino baking varnish and rapid curing technology, which is applied in the field of amino baking varnish, can solve the problems that alkyd resin or acrylic resin cannot be used, promotion restrictions, etc., and achieve the effects of improving hardness and nitric acid resistance, strong applicability, and simple preparation method

Active Publication Date: 2013-05-08
浙江德尚化工科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Patent CN200810021672.5 proposes a method for preparing quick-drying amino baking varnish by using alkyd or amino resin, amino resin, polybasic dibasic acid ester, auxiliary agent and diluent. Although the baking time of the obtained amino baking varnish is shortened, the The required baking temperature is still very high (170°C); patent CN201010590719.7 discloses an

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] 100 parts of epoxy resin YD128, 30 parts of benzoic acid, 2 parts of antioxidant 168, 0.5 parts of TNPP, 5 parts of ethylene glycol butyl ether, 0.1 parts of triphenylphosphine and 0.1 parts of tetrabutyl Put ammonium bromide into the reaction kettle, heat to 100°C; keep warm until the acid value is less than 5mgKOH / g; evenly add a mixture of 10 parts of phosphoric acid and 50 parts of n-butanol dropwise within 1.0h, keep warm until the acid value is less than 20 mgKOH / g g; cooling and adding 50 parts of n-butanol for dilution, and filtering to obtain a functional auxiliary product.

[0032] Mix 50 parts of hydroxyacrylic resin 1570 (self-made), 15 parts of amino resin 582, 2 parts of functional additives, 0.2 parts of leveling agent, 0.2 parts of defoamer, 5 parts of xylene and 5 parts of Propylene glycol methyl ether acetate is mixed evenly to obtain an amino baking varnish product.

Embodiment 2

[0034] 100 parts of epoxy resin YD127, 30 parts of benzoic acid, 2 parts of antioxidant 168, 0.5 parts of TNPP, 5 parts of ethylene glycol butyl ether, 0.1 parts of triphenylphosphine and 0.1 parts of tetrabutyl Put ammonium bromide into the reaction kettle, heat to 100°C; keep warm until the acid value is less than 5mgKOH / g; evenly add a mixture of 10 parts of phosphoric acid and 50 parts of n-butanol dropwise within 1.0h, keep warm until the acid value is less than 20 mgKOH / g g; cooling and adding 50 parts of n-butanol for dilution, and filtering to obtain a functional auxiliary product.

[0035] Mix 50 parts of hydroxyacrylic resin 1570 (self-made), 15 parts of amino resin 582, 2 parts of functional additives, 0.2 parts of leveling agent, 0.2 parts of defoamer, 5 parts of xylene and 5 parts of Propylene glycol methyl ether acetate is mixed evenly to obtain an amino baking varnish product.

Embodiment 3

[0037] 100 parts of epoxy resin YD128, 30 parts of benzoic acid, 2 parts of antioxidant 168, 0.5 parts of TNPP, 5 parts of ethylene glycol butyl ether, 0.1 parts of triphenylphosphine and 0.1 parts of tetrabutyl Put ammonium bromide into the reaction kettle, heat to 100°C; keep warm until the acid value is less than 5mgKOH / g; evenly add a mixture of 10 parts of phosphoric acid and 50 parts of n-butanol dropwise within 1.0h, keep warm until the acid value is less than 20 mgKOH / g g; cooling and adding 50 parts of n-butanol for dilution, and filtering to obtain a functional auxiliary product.

[0038] Mix 50 parts of hydroxyacrylic resin 1570 (self-made), 15 parts of amino resin 582, 1 part of functional additive, 0.2 part of leveling agent, 0.2 part of defoamer, 5 parts of xylene and 5 parts of Propylene glycol methyl ether acetate is mixed evenly to obtain an amino baking varnish product.

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PUM

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Abstract

The invention relates to amino stoving varnish, and in particular to amino stoving varnish capable of capable of being cured quickly at a low temperature. The amino stoving varnish comprises the following components in parts by weight: 50-60 parts of hydroxy acrylic resin or alkyd resin, 10-20 parts of amino resin, 1-5 parts of functional auxiliary, 0.1-0.5 part of flatting agent, 0.1-0.5 part of antifoaming agent and 10-20 parts of diluent. A preparation method of the amino stoving varnish provided by the invention is simple, and the prepared product has strong applicability and good quality.

Description

technical field [0001] The invention relates to an amino baking varnish, in particular to an amino baking varnish capable of fast curing at low temperature. Background technique [0002] Amino baking varnish uses acrylic resin or alkyd resin and amino resin with hydroxyl groups as the main film-forming substances. It is packaged in a single component at room temperature. It has a three-dimensional network structure, high hardness, excellent adhesion, high gloss, good gloss and color retention, and is widely used in the coating of automobiles, ships, and aircraft. [0003] After the amino baking varnish is painted, it generally needs to be baked at 140~180°C for more than 30 minutes to be completely cured, which brings many problems to the use of amino baking varnish. On the one hand, high-temperature baking causes a large amount of energy consumption in the coating process, and is more likely to bring hidden dangers to production safety; on the other hand, longer baking tim...

Claims

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Application Information

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IPC IPC(8): C09D133/00C09D167/08C09D161/32C09D163/02C09D7/12
Inventor 辜朝辉
Owner 浙江德尚化工科技有限公司
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