Amino stoving varnish capable of being cured quickly at low temperature
An amino baking varnish and rapid curing technology, which is applied in the field of amino baking varnish, can solve the problems that alkyd resin or acrylic resin cannot be used, promotion restrictions, etc., and achieve the effects of improving hardness and nitric acid resistance, strong applicability, and simple preparation method
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Embodiment 1
[0031] 100 parts of epoxy resin YD128, 30 parts of benzoic acid, 2 parts of antioxidant 168, 0.5 parts of TNPP, 5 parts of ethylene glycol butyl ether, 0.1 parts of triphenylphosphine and 0.1 parts of tetrabutyl Put ammonium bromide into the reaction kettle, heat to 100°C; keep warm until the acid value is less than 5mgKOH / g; evenly add a mixture of 10 parts of phosphoric acid and 50 parts of n-butanol dropwise within 1.0h, keep warm until the acid value is less than 20 mgKOH / g g; cooling and adding 50 parts of n-butanol for dilution, and filtering to obtain a functional auxiliary product.
[0032] Mix 50 parts of hydroxyacrylic resin 1570 (self-made), 15 parts of amino resin 582, 2 parts of functional additives, 0.2 parts of leveling agent, 0.2 parts of defoamer, 5 parts of xylene and 5 parts of Propylene glycol methyl ether acetate is mixed evenly to obtain an amino baking varnish product.
Embodiment 2
[0034] 100 parts of epoxy resin YD127, 30 parts of benzoic acid, 2 parts of antioxidant 168, 0.5 parts of TNPP, 5 parts of ethylene glycol butyl ether, 0.1 parts of triphenylphosphine and 0.1 parts of tetrabutyl Put ammonium bromide into the reaction kettle, heat to 100°C; keep warm until the acid value is less than 5mgKOH / g; evenly add a mixture of 10 parts of phosphoric acid and 50 parts of n-butanol dropwise within 1.0h, keep warm until the acid value is less than 20 mgKOH / g g; cooling and adding 50 parts of n-butanol for dilution, and filtering to obtain a functional auxiliary product.
[0035] Mix 50 parts of hydroxyacrylic resin 1570 (self-made), 15 parts of amino resin 582, 2 parts of functional additives, 0.2 parts of leveling agent, 0.2 parts of defoamer, 5 parts of xylene and 5 parts of Propylene glycol methyl ether acetate is mixed evenly to obtain an amino baking varnish product.
Embodiment 3
[0037] 100 parts of epoxy resin YD128, 30 parts of benzoic acid, 2 parts of antioxidant 168, 0.5 parts of TNPP, 5 parts of ethylene glycol butyl ether, 0.1 parts of triphenylphosphine and 0.1 parts of tetrabutyl Put ammonium bromide into the reaction kettle, heat to 100°C; keep warm until the acid value is less than 5mgKOH / g; evenly add a mixture of 10 parts of phosphoric acid and 50 parts of n-butanol dropwise within 1.0h, keep warm until the acid value is less than 20 mgKOH / g g; cooling and adding 50 parts of n-butanol for dilution, and filtering to obtain a functional auxiliary product.
[0038] Mix 50 parts of hydroxyacrylic resin 1570 (self-made), 15 parts of amino resin 582, 1 part of functional additive, 0.2 part of leveling agent, 0.2 part of defoamer, 5 parts of xylene and 5 parts of Propylene glycol methyl ether acetate is mixed evenly to obtain an amino baking varnish product.
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