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Flexible polymer solar battery with wrinkling structure and preparation method thereof

A technology of solar cells and flexible polymers, applied in circuits, electrical components, photovoltaic power generation, etc., can solve the problem that the photoelectric conversion efficiency and mechanical stability of polymer solar cells are difficult to improve at the same time, so as to facilitate large-scale production and reduce production costs. Cost, the effect of improving photoelectric conversion efficiency

Inactive Publication Date: 2013-07-24
PEKING UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Aiming at the problem that it is difficult to simultaneously improve the photoelectric conversion efficiency and mechanical stability of polymer solar cells, the present invention provides a flexible polymer solar cell with a new structure and a preparation method thereof

Method used

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  • Flexible polymer solar battery with wrinkling structure and preparation method thereof

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Effect test

Embodiment 1

[0042] 1. Preparation of functional layer inkjet printing ink

[0043] (1) Preparation of PEDOT:PSS / graphene composite particles

[0044] Under ice bath conditions, 1.5g of graphite was added to 60ml of concentrated sulfuric acid, stirred vigorously for 30min, and further 18gKMnO 4 Add to the above mixture and stir vigorously for 30min. Transfer the above mixture to a 30°C water bath, slowly add 20g NaNO 3 , stirred for 60min; while stirring, continuously added 140ml of deionized water to the above mixture, then transferred it to an oil bath at a temperature of 90°C, stirred for 30min; then added 12ml of H 2 o 2 , continue to react for 60min to make the solution change from dark brown to bright yellow; under stirring conditions, add graphene oxide amount 10wt%PEDOT:PSS dispersing reagent in the above bright yellow graphene oxide solution, and add dropwise 30ml of hydrazine hydrate solution after dissolving , react at 80°C for 1 hour, further add 20ml of acetic acid aqueous...

Embodiment 2

[0062] 1. Preparation of functional layer inkjet printing ink

[0063] (1) Preparation of PEDOT:PSS / graphene composite particles

[0064] Under ice bath conditions, 3.5g of graphite was added to 60ml of concentrated sulfuric acid, vigorously stirred for 30min, and 20g of KMnO 4 Add to the above mixture and stir vigorously for 30min. Transfer the above mixture to a 30°C water bath, slowly add 23g NaNO 3 , stirred for 60min; while stirring, continuously added 140ml of deionized water to the above mixture, then transferred it to an oil bath at a temperature of 90°C, stirred for 30min; then added 14ml of H 2 o 2 , continue to react for 60min to make the solution change from dark brown to bright yellow; under stirring conditions, add graphene oxide amount 15wt%PEDOT:PSS dispersing reagent in the above bright yellow graphene oxide solution, and add dropwise 30ml of hydrazine hydrate solution after dissolving , react at 80°C for 1 hour, further add 30ml of acetic acid aqueous sol...

Embodiment 3

[0082] 1. Preparation of functional layer inkjet printing ink

[0083] (1) Preparation of PEDOT:PSS / graphene composite particles

[0084] Under ice bath conditions, 3.5g of graphite was added to 60ml of concentrated sulfuric acid, vigorously stirred for 30min, and 20g of KMnO 4 Add to the above mixture and stir vigorously for 30min. Transfer the above mixture to a 30°C water bath, slowly add 23g NaNO 3 , stirred for 60min; while stirring, continuously added 140ml of deionized water to the above mixture, then transferred it to an oil bath at a temperature of 90°C, stirred for 30min; then added 14ml of H 2 o 2 , continue to react for 60min to make the solution change from dark brown to bright yellow; under stirring conditions, add graphene oxide amount 15wt%PEDOT:PSS dispersing reagent in the above bright yellow graphene oxide solution, and add dropwise 30ml of hydrazine hydrate solution after dissolving , react at 80°C for 1 hour, further add 30ml of acetic acid aqueous sol...

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Abstract

The invention relates to a flexible polymer solar battery with a wrinkling structure, comprising a transparent electrode, a cavity transporting layer, photo-activation layer materials, an electron transporting layer and a metal electrode, wherein the photo-activation layer materials comprise a donor material and an acceptor material; the transparent electrode is made of graphene / PEDOT(poly(3,4-ethylenedioxythiophene):PSS(polystyrene sulfonate) / PET(polyethylene terephthalate) composite film; the hole transporting layer is made of a PEDOT:PSS film; an electron donor is made of P3HT; an electron acceptor is made of graphene / PEDOT:PSS composite particles; the electron transporting layer is made of a zinc-oxide film; and the metal electrode is made is silver. The flexible polymer solar battery is prepared by the following steps of: adopting an ink-jet printer to print a graphene / PEDOT:PSS transparent conducting layer, the hole transporting layer, active-layer materials, the electron transporting layer and metal slurry on a pre-stretched PET film in sequence, carrying out drying treatment on the materials under the temperature being 50-100 DEG C, then removing pre-stretching force and obtaining the flexible polymer solar battery with the wrinkling structure. The flexible polymer solar battery has the advantages that the sunlight utilization rate is high, the photoelectric conversion efficiency is high, the preparation process is simple and convenient, the mechanical stability is good, large-scale industrial preparation can be realized and the application prospect is wide.

Description

technical field [0001] The invention relates to a polymer solar cell and a preparation method thereof. Background technique [0002] With the aggravation of the global energy crisis and environmental pollution, solar cells that convert solar energy, a clean renewable energy, into electrical energy have received great attention from countries all over the world. Among all kinds of solar cells, inorganic semiconductor solar cells occupy most of the current solar cell market due to their high photoelectric conversion efficiency and mature technology. However, inorganic semiconductor solar cells have many disadvantages, such as high cost, high energy consumption, complicated manufacturing process, non-flexibility, heavy weight, and difficulty in large-scale preparation, which limit their large-scale application in many fields. [0003] Compared with traditional inorganic solar cells, flexible polymer solar cells are low in cost, simple to manufacture, easy to manufacture in lar...

Claims

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Application Information

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IPC IPC(8): H01L51/42H01L51/46H01L51/48
CPCY02E10/549
Inventor 方岱宁孙友谊张用吉池慧娟马竞
Owner PEKING UNIV
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