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Low smoke zero halogen flame retardant polyphenyl ether elastomer cable material and preparation method therefor

A polyphenylene ether elastomer and cable material technology, which is applied in the direction of plastic/resin/wax insulators, organic insulators, etc., can solve the problems of low technical indicators of cable materials, unsatisfactory insulation, and low volume resistivity, etc., and achieve improvement Comprehensive mechanical properties, excellent flame retardancy, good water resistance and electrical insulation

Active Publication Date: 2013-10-16
ANHUI CABLE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Wire and cable materials are mainly made of resin components, fillers, plasticizers, anti-aging agents, flame retardants, antioxidants, etc. The formula raw materials are mainly concentrated in some common ingredients, which leads to low technical indicators of cable materials Or high cost issues, such as low volume resistivity, high temperature resistance, low temperature resistance, flame retardancy, insulation, etc. cannot meet the requirements of cable manufacturers for higher electrical properties of insulating grade sheath materials

Method used

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Examples

Experimental program
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Effect test

Embodiment Construction

[0011] A low-smoke, halogen-free, flame-retardant polyphenylene ether elastomer cable material, made of the following raw materials in parts by weight (kg):

[0012] Polyphenylene ether 25, ethylene-methyl acrylate copolymer (EMA 1126AC) 34, tantalum boride 7, hafnium diboride 2, boric acid 2, monoglyceride stearate 6, zinc stearate 3, zinc oxide 1, Rapeseed oil 5, aluminum hydroxide powder 15, bauxite 26, glycerol triglyceride 4, methyltrimethoxysilane 3, accelerator DM 2, modified diatomite 8.

[0013] Described modified diatomite is made by following method:

[0014] Put diatomite at 450-500°C for 3-4 hours, take it out, cool it, soak it in 10-12% hydrochloric acid solution for 1-2 hours, take it out, wash it with pure water, dry it and grind it into powder; Add aluminum nitride equivalent to 40% of the weight of diatomite, 3% calcium stearate, 3% zirconium fluoride, and 4% alum powder, mix and grind for 30-40 minutes, and then spray an equivalent amount of diatomite Tria...

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PUM

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Abstract

Provided is a low smoke zero halogen flame retardant polyphenyl ether elastomer cable material and a preparation method therefor. The cable material is characterized by comprising, by weight, 25-28 parts of polyphenyl ether, 30-34 parts of ethylene-methyl acrylate copolymers (EMA1126AC), 5-7 parts of tantalum boride, 2-3 parts of hafnium diboride, 1-2 parts of boric acid, 4-6 parts of glycerol monostearate, 2-3 parts of zine stearate, 1-2 parts of zinc oxide, 4-5 parts of colza oil, 12-15 parts of aluminium hydroxide powder, 26-29 parts of bauxite, 3-4 parts of glycerol triglyceride, 2-3 parts of methyltrimethoxysilane, 1-2 parts of accelerant DM and 6-8 parts of modified diatomite. The cable material can pass the VW-1 vertical burning test, and is advantaged by excellent flame retardance, good mechanical property, good hydrolytic resistance, good electrical insulating property and high and low temperature resistance.

Description

technical field [0001] The invention belongs to the technical field of cable materials, and more specifically relates to a low-smoke, halogen-free, flame-retardant polyphenylene ether elastomer cable material and a preparation method thereof. Background technique [0002] Wire and cable materials are mainly made of resin components, fillers, plasticizers, anti-aging agents, flame retardants, antioxidants, etc. The formula raw materials are mainly concentrated in some common ingredients, which leads to low technical indicators of cable materials Or high cost issues, such as low volume resistivity, high temperature resistance, low temperature resistance, flame retardancy, insulation, etc., cannot meet the requirements of cable manufacturers for higher electrical properties of insulating grade sheath materials. [0003] Contents of the invention [0004] The purpose of the present invention is to provide a low-smoke halogen-free flame-retardant polyphenylene ether elastomer ...

Claims

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Application Information

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IPC IPC(8): C08L23/08C08L71/12C08K13/06C08K9/04C08K9/02C08K3/34C08K5/5419H01B3/44
Inventor 张万有周俊韩俊宝高从明徐晓丽朱元忠夏侯东
Owner ANHUI CABLE
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