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Bio-based methanol gasoline product stabilizer and preparation method thereof

A technology of methanol gasoline and stabilizer, which is applied in the field of alcohol substitute fuels, can solve problems such as unsatisfactory stabilization effect, and achieve the effects of low cost, complete combustion and remarkable effect.

Active Publication Date: 2013-11-20
NORTHWEST UNIVERSITY FOR NATIONALITIES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The patent number is CN100451092C. In the disclosed "methanol gasoline emulsification stabilizer", the stabilizer with naphthenic acid, cyclohexylamine, glucose, toluene and anhydrous sodium sulfate as main components, wherein cyclohexylamine cyclohexylamine has strong Organic alkaline properties, glucose insoluble in alcohol, toluene pollute the environment, and sodium sulfate contains dielectrics that affect the use of methanol gasoline; CN101323800A "Methanol gasoline stability and synergistic additive for vehicles" contains alcohols, emulsifiers, di-tert-butyl In CN102295962A, it contains toluene and xylene controlled by environmental protection; in CN101423777A, the stabilizer contains sodium bicarbonate that strengthens the electrocorrosion effect; in other patents, CN102191091A, CN101024788A, etc. are environmentally friendly Pollution controlled toluene and xylene are used as oleyl alcohol stabilizers

Method used

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  • Bio-based methanol gasoline product stabilizer and preparation method thereof
  • Bio-based methanol gasoline product stabilizer and preparation method thereof
  • Bio-based methanol gasoline product stabilizer and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] A bio-based methanol gasoline oil stabilizer is composed of the following volume percentage functional components:

[0030] Inhibit aldehyde acid component: C 16 ~C 18 Fatty acid soap 7.0%; C 4 Isomerized fatty alcohol 10.0%;

[0031] Balance acid-base component: C 4 ~C 6 Fatty Alcohol 6.0%; C 4 Fatty acid 7.5%;

[0032] Viscosity improving component: C 4 Fatty acid ester 30.0%;

[0033] Distillation range improving component: C 4 ~C 5 Fatty aldehyde 20.0%;

[0034] Stable liquid phase component: C 3 ~C 4 Fatty alcohol 19.5%;

[0035] Among them: inhibiting the C of the aldehyde acid component16 ~C 18 Fatty acid soap is yeast fatty acid soap, which is a fatty acid soap formed by saponification of petroleum yeast fatty acid (RCOOH) and organic amine (triethanolamine) at a volume ratio of 2:1 at room temperature (RCONHR 1 );C 4 The isomeric fatty alcohol is isobutanol; the C of the balanced acid-base component 4 ~C 6 Fatty alcohol, which is composed of n...

Embodiment 2

[0037] A bio-based methanol gasoline oil stabilizer is composed of the following volume percentage functional components:

[0038] Inhibit aldehyde acid component: C 16 ~C 18 Fatty acid soap 8.0%;

[0039] C 4 Isomerized fatty alcohol 9.0%;

[0040] Balance acid-base component: C 4 ~C 6 Fatty Alcohol 7.0%;

[0041] C 4 Fatty acids 7.5%;

[0042] Viscosity improving component: C 4 Fatty acid ester 30.0%;

[0043] Distillation range improving component: C 4 ~C 5 Fatty aldehyde 20.0%;

[0044] Stable liquid phase component: C 3 ~C 4 Fatty Alcohol 18.5%;

[0045] Among them: inhibiting the C of the aldehyde acid component 16 ~C 18 Fatty acid soap is yeast fatty acid soap, which is a fatty acid soap formed by saponification of petroleum yeast fatty acid (RCOOH) and organic amine (triethanolamine) at a volume ratio of 2:1 at room temperature (RCONHR 1 );C 4 The isomeric fatty alcohol is isobutanol; the C of the balanced acid-base component 4 ~C 6 Fatty alcohol, ...

Embodiment 3

[0047] A bio-based methanol gasoline oil stabilizer is composed of the following volume percentage functional components:

[0048] Inhibit aldehyde acid component: C 16 ~C 18 Fatty acid soap 8.5%;

[0049] C 4 Isomerized fatty alcohol 8.0%;

[0050] Balance acid-base component: C 4 ~C 6 Fatty Alcohol 8.0%;

[0051] C 4 Fatty acids 7.5%;

[0052] Viscosity improving component: C 4 Fatty acid ester 30.0%;

[0053] Distillation range improving component: C 4 ~C 5 Fatty aldehyde 20.0%;

[0054] Stable liquid phase component: C 3 ~C 4 Fatty Alcohol 18.0%;

[0055] Among them: inhibiting the C of the aldehyde acid component 16 ~C 18 Fatty acid soap is yeast fatty acid soap, which is a fatty acid soap formed by saponification of petroleum yeast fatty acid (RCOOH) and organic amine (triethanolamine) at a volume ratio of 2:1 at room temperature (RCONHR 1 );C 4 The isomeric fatty alcohol is isobutanol; the C of the balanced acid-base component 4 ~C 6 Fatty alcohol, ...

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Abstract

The invention discloses a bio-based methanol gasoline product stabilizer and a preparation method thereof. The bio-based methanol gasoline product stabilizer consists of an inhibition aldehyde acid component, an acid-alkali balancing component, a viscosity improving component, a distillation range improving component and a stable liquid-phase component, wherein the five functional components are uniformly stirred under the normal temperature to form the bio-based methanol gasoline product stabilizer finished product. Compared with the prior art, the bio-based methanol gasoline product stabilizer is obvious in stabilizing effect and incapable of bringing secondary pollution to the environment. When the moisture content of the bio-based methanol gasoline product stabilizer exceeds 10%, the oleyl alcohol phase stable period is still as long as 180 days, so that a problem that a fuel oil system and an engine must be regulated and optimized when the methanol content exceeds 85% is broken through. The prepared methanol gasoline has excellent water resistance, low temperature resistance, acid-alkali balancing resistance, stability of long-term stored oleyl alcohol as well as no emulsion phenomenon and no phase separation phenomenon while being mixed with the goods gasoline at any proportion, so that the combustion is more complete, and the emission of formaldehyde, the formic acid and the tail gas pollutants is reduced.

Description

technical field [0001] The invention relates to the field of alternative fuels for alcohols, in particular to an oil stabilizer which mainly uses biomass energy and can be blended with bioalcohols in a high proportion and a preparation method thereof. Background technique [0002] For a long time, gasoline and diesel have been the main fuels for various types of motor vehicles. This usage pattern is increasingly restricted by serious environmental pollution and increasingly scarce resources. In order to improve this dilemma, a variety of energy alternatives have been adopted at home and abroad. However, if these alternatives are to be popularized on a large scale, there are serious defects. In recent years, as the international oil price continues to hover at a high level, the promotion, application and research process of alternative alcohol-ether fuels at home and abroad have been accelerated. Alcohol gasoline, as a clean, cheap and efficient gasoline substitute, has been...

Claims

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Application Information

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IPC IPC(8): C10L1/10C10L1/22C10L1/182C10L1/188C10L1/19C10L1/185
Inventor 牛锋黄晓磊吴慧昊
Owner NORTHWEST UNIVERSITY FOR NATIONALITIES
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