Polyvinyl-alcohol imbibition sponge material and preparation method thereof

A polyvinyl alcohol absorbent sponge and polyvinyl alcohol technology, applied in the coating and other directions, can solve the problems of unsolved starch cleaning, low density and compressive elasticity, low sponge cross-linking density, etc., and reduce product utilization. rate, weak penetration, and the effect of improving poor low temperature stability

Active Publication Date: 2013-12-11
SOUTH CHINA UNIV OF TECH
View PDF4 Cites 33 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For example, U.S. Patent No. 4,098,728 discloses a medical polyvinyl alcohol sponge that is prepared by entraining air by mechanical stirring alone. The pore size is controlled by the amount of surfactant and the stirring speed. Although the purity of the sponge is very high, the pore connectivity is not high. Low density and compressive elasticity, severe molding shrinkage, difficult to control pore size
[0006] In the patent documents published above, one is to obtain sponge body by foaming with starch filling method, and the other is to obtain sponge body by filling and foaming by mixing gas or adding gas that can react and release gas; the former consumes a lot of water due to starch cleaning problems, On the other hand, it is diff...

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Polyvinyl-alcohol imbibition sponge material and preparation method thereof
  • Polyvinyl-alcohol imbibition sponge material and preparation method thereof
  • Polyvinyl-alcohol imbibition sponge material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] A preparation method of a polyvinyl alcohol liquid-absorbing sponge material, comprising the steps of:

[0032](1) Add 5g of polyvinyl alcohol (type 1799) provided by Shanghai Sinopharm Group Chemical Reagent Co., Ltd. and 25g of distilled water into the reactor, and dissolve it in a water bath at 95°C with a stirrer at a speed of 400r / min After 20 minutes, an aqueous solution of polyvinyl alcohol was obtained.

[0033] (2) Take the above polyvinyl alcohol aqueous solution, add dropwise 5g of crosslinking agent (formaldehyde and glutaraldehyde are mixed uniformly in a mass ratio of 4:1), then add dropwise 0.8g of sulfuric acid, and add 1g of pentane and 0.8g of starch at the same time , 0.5g sodium lauryl sulfate, 0.5g cellulose and 0.5g polyoxyethylene stearate were mixed evenly in a water bath at 30°C, and reacted for 5 minutes under stirring by a mixer at a speed of 400r / min.

[0034] (3) Pour the emulsion obtained in step (2) into the mold, and solidify at 30°C for...

Embodiment 2

[0037] A preparation method of a novel polyvinyl alcohol liquid-absorbing sponge material, comprising the steps of:

[0038] (1) The 2g model provided by Shanghai Sinopharm Chemical Reagent Co., Ltd. is 1788, the 2g model provided by Shanghai Sinopharm Chemical Reagent Co., Ltd. is 1799, the 2g model provided by Shanghai Sinopharm Chemical Reagent Co., Ltd. is 2099, and 2g The model provided by Shanghai Sinopharm Chemical Reagent Co., Ltd. is 2488, 2g polyvinyl alcohol of the model 2699 provided by Shanghai Sinopharm Chemical Reagent Co., Ltd., and 45g distilled water is added in the reactor, under 50 ℃ of water baths, use Stirrer, under the condition of rotating speed 600r / min, dissolve 30min, obtain the aqueous solution of polyvinyl alcohol.

[0039] (2) Take the above polyvinyl alcohol aqueous solution and add 3g of crosslinking agent dropwise Nonylacetaldehyde, Trimethylhexanal, Benzaldehyde, Phenylacetaldehyde, Phenylpropionaldehyde and Cinnamaldehyde by mass ratio 1:2:1...

Embodiment 3

[0043] A preparation method of a novel polyvinyl alcohol liquid-absorbing sponge material, comprising the steps of:

[0044] (1) The 1g model provided by Shanghai Sinopharm Chemical Reagent Co., Ltd. is 224, the 2g model provided by Shanghai Sinopharm Chemical Reagent Co., Ltd. is 117, and the 2g model provided by Shanghai Sinopharm Chemical Reagent Co., Ltd. is BF-17 The polyvinyl alcohol and 5 g of distilled water were added into the reactor, and dissolved in a water bath at 70° C. using a stirrer for 25 min at a rotation speed of 450 r / min to obtain an aqueous solution of polyvinyl alcohol.

[0045] (2) Take the above polyvinyl alcohol aqueous solution, add dropwise 15g of cross-linking agent (mixed uniformly by mass ratio of tridecanal and myristic aldehyde at 3:1), then add dropwise 3g of acetic acid, 3g of oxalic acid, and add 10g of Tetrahydrofuran, 8g of diatomaceous earth, 8g of kaolin, 5g of polysorbate, 2g of sodium dioctyl succinate, 2g of polyethylene glycol and 2...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses a polyvinyl-alcohol imbibition sponge material and a preparation method thereof. The method comprises the steps of firstly, mixing polyvinyl alcohol and distilled water, and dissolving in water bath with the temperature of 50-95 DEG C, so as to obtain a polyvinyl-alcohol aqueous solution; adding a cross-linking agent, a catalyst, a foamer, a pore filling agent and an auxiliary foamer into the polyvinyl-alcohol aqueous solution, and uniformly stirring and mixing in water bath with the temperature of 30-80 DEG C; pouring a uniformly-mixed emulsion into a mold, and carrying out crosslinking reaction at the temperature of 30-90 DEG C; reacting for 30-60 minutes, after pores are formed, maintaining the temperature, and further heating to solidify for 2-8 hours, thereby obtaining the polyvinyl-alcohol imbibition sponge material. The sponge is uniform in pore, strong in water absorbing power, good in flexibility and viscoelasticity and good in biocompatibility, has the advantages of low cost, environment friendliness, simple process and the like, and has broad prospects for development in the fields of aquatic product processing, food, clinical medicine, water treatment and the like.

Description

technical field [0001] The invention relates to a liquid-absorbing sponge material, in particular to a novel polyvinyl alcohol liquid-absorbing sponge material and a preparation method thereof. Good, good flexibility and viscoelasticity and good biocompatibility. technical background [0002] The polyvinyl alcohol liquid-absorbing sponge material has the following excellent properties: 1) Strong water absorption capacity due to the hydrophilic group in the molecular structure; 2) The sponge has good flexibility and resilience; 3) Hydrophilicity and alkali resistance Good durability, wear resistance, creep resistance, and freeze-thaw resistance; 4) Stable to oxygen and ultraviolet rays, and not easy to age. Therefore, it is widely used in the fields of electronics industry, daily cleaning, medical and sanitation, kitchen and bathroom, building materials and so on. With the rapid economic development in recent years and people's continuous pursuit of a comfortable and health...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C08J9/14C08J9/36C08J3/24C08L29/04
Inventor 蔡智奇罗志波陆园文秀芳程江
Owner SOUTH CHINA UNIV OF TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products