The invention relates to an ultralow-hydrogen high-toughness submerged arc welding flux core and a submerged arc flux-cored wire. The welding flux core comprises the following components of: CaF2, Na2SiF6, ReF, BaCO3, CaCO3, MgO, TiO2, SiO2, ZrO2, boride, Na2O, K2O, Mn, Al-Mg, Ni, Ti, Si, Re and the balance of Fe. When the welding flux core is matched with a high-alkalinity sintering welding flux, the weld metal has the impact absorbed power of more than 80J at the temperature of 60 DEG C below zero; when the welding flux core is matched with a low-hygroscopicity smelting welding flux, the weld metal has the impact absorbed power of more than 90J at the temperature of 40 DEG C below zero; and when the welding flux core is matched with any one welding flux, weld diffusion hydrogen content is less than 5ml/100g. The standard specific ultralow-hydrogen range is achieved; and the submerged arc flux-cored wire is high in cold crack resistance, has high in fracture toughness value, is suitable for low-alloy high-strength steel and can be used for welding important structures.