A kind of high-strength direct-plating aluminum water-based primer and its preparation method and application
A high-strength, water-based technology, applied in coatings, paper coatings, metal coatings, etc., to achieve high flexibility, improve flexibility, and increase cross-linking density
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Embodiment 1
[0043] (1) Preparation of water-based primer for direct aluminum plating:
[0044] (1) Mix 2g propylene glycol methyl ether and 6g ethanol evenly, then add 0.5g leveling agent BYK333 (polyether modified organosiloxane), 0.2g slip agent silok-8580 (silicon-containing organic compound) and 0.05g Defoamer tego902W (polyether modified organosiloxane), stir (200-1000r / min) until each component is dissolved, add 36.15g of deionized water and stir (200-1000r / min) evenly to obtain a mixed solution;
[0045] (2) Add 50g of DSM water-based acrylic modified polyurethane E-129 (solid content 60%) to the mixed solution obtained in step (1) under low-speed stirring (200-1000r / min), and then add 2g of water-based aldehyde ketone EPDS- 1300, dispersed evenly; then about 0.1g cyclohexylamine was added dropwise to adjust the pH to 6-9 to obtain a solution;
[0046] (3) Add 1g of thickener Dow hydroxyethyl cellulose ER-4400 (1% (mass) aqueous solution) to the solution obtained in step (2), adju...
Embodiment 2
[0050] (1) Preparation of water-based primer for direct aluminum plating:
[0051] (1) Mix 4g propylene glycol methyl ether acetate, 6g ethanol, and 6g n-propanol evenly, add 0.1g leveling agent EFKA-3777 (fluorocarbon leveling agent), 0.3g slip agent DC-30 (containing silicon organic compound) and 0.05g mineral oil defoamer AD-76, stir (200-1000r / min) until each component is dissolved, then add 19.35g deionized water and stir (200-1000r / min) evenly to obtain a mixed solution;
[0052] (2) Add 40g of DSM waterborne polyurethane NeoRezR-986 (solid content 34% (mass)) and 16g of waterborne polyester EW-312 ( 50% (mass)), then add 5g organic hardening resin water-based acrylic acid AC-830 (35% (mass)), and disperse evenly; then add about 0.2g N,N-dimethyldiethanolamine dropwise to adjust the pH to 6-9 , to obtain a solution;
[0053] (3) Add 1g of acrylic thickener LH-122 to the solution obtained in step (2) to adjust the viscosity to 25±2ss; then add 2g of silane coupling agen...
Embodiment 3
[0057] (1) Preparation of water-based primer for direct aluminum plating:
[0058] (1) Mix 3g propylene glycol methyl ether, 1g n-butanol and 6g ethanol evenly, add 1g leveling agent Deqian levelol839 (acrylate leveling agent), 0.05g slipping agent CHEMIPEARLW900 (Mitsui Chemicals, water-based polyolefin wax emulsion) and 0.1g of antifoaming agent tego835 (polydimethylsiloxane defoaming agent), stirring (200-1000r / min) until each component is dissolved, then adding 15.8g of deionized water and stirring (200-1000r / min) Uniformly, a mixed solution is obtained;
[0059] (2) Add 40g of Bayer water-based polyurethane 2593 (solid content 35% (mass)) and 30g of ADEKA water-based polyurethane HUX1032 (solid content 30% % (mass)), then add 2g of nano-silica aqueous solution (10% (mass)), and disperse evenly; then add about 0.25g of 1-aminoisopropanol dropwise to adjust the pH to 6-9 to obtain a solution;
[0060] (3) Add 0.8g thickener ADEKAUH-450 (polyurethane associative thickener)...
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