High reinforced fireproof cable sheath material and preparation method thereof

A technology for fire-resistant cables and sheathing materials, which is applied in the direction of insulated cables, cables, circuits, etc., can solve the problems of turning into ashes, secondary hazards, and the lack of mechanical strength of burning residues, so as to reduce smoke density and improve flame retardancy. , The effect of flame retardant effect is obvious

Inactive Publication Date: 2014-07-23
ANHUI DINGXING CABLE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] With the improvement of social safety awareness, many application fields have clearly put forward the flame retardant performance requirements for the rubber materials used. Usually, halogen-containing rubber matrix is ​​used or halogen flame retardant is added to the rubber matrix to achieve excellent flame retardant effect. , although the effect is very good, it emits a large amount of poisonous and corrosive gas when burning, accompanied by a large amount of smoke
With the increasingly stringent environmental protection and recycling regulations and the continuous emergence of new sheath materials, traditional cable materials are facing huge challenges. The current technology mainly uses halogen-free low-smoke flame-retardant rubber, mainly silicone rubber and ethylene-propylene rubber. And ethylene-vinyl acetate rubber, etc. These rubbers have flame retardancy and self-extinguishing properties in fire, and have a certain effect in fire, but after continuous high-temperature combustion, the burnt residue has no mechanical strength and turns into ashes, which will It will cause more dangerous secondary hazards, and the protection of personal and property safety in fire is a major concern of people. How to prepare a cable sheath material with high reinforcement strength, good ablation resistance, and excellent fire resistance and flame retardancy has become a current demand. Technical issues resolved

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] A high-reinforcement fire-resistant cable sheath material, the raw materials of which include by weight:

[0022] 88 parts of phenyl silicone rubber, 24 parts of fumed silica, 16 parts of precipitated silica, 1.7 parts of octamethylcyclotetrasiloxane, 42 parts of calcium carbonate, 12 parts of quartz powder, 1.3 parts of hydroxyl silicone oil, poly 2.1 parts of siloxane, 0.00036 parts of platinum catalyst, 22 parts of aluminum hydroxide, 18 parts of magnesium hydroxide, 1.2 parts of dioctahedral basic aluminum silicate, 0.6 part of trioctahedral basic aluminum silicate, and 4 parts of zinc oxide.

[0023] In this embodiment, the preparation method of the above-mentioned high-reinforced fire-resistant cable sheath material includes the following steps:

[0024] S1. Weigh phenyl silicone rubber, fumed silica, precipitated silica and hydroxy silicone oil according to the proportion, and send them to the kneader for mixing. The mixing temperature is 173°C, and the mixing ti...

Embodiment 2

[0028] A high-reinforcement fire-resistant cable sheath material, the raw materials of which include by weight:

[0029] 92 parts of phenyl silicone rubber, 21 parts of fumed silica, 14 parts of precipitated silica, 1.7 parts of octamethylcyclotetrasiloxane, 45 parts of calcium carbonate, 8 parts of quartz powder, 1.4 parts of hydroxyl silicone oil, poly 2.1 parts of siloxane, 0.00052 parts of platinum catalyst, 19 parts of aluminum hydroxide, 18 parts of magnesium hydroxide, 1.2 parts of dioctahedral basic aluminum silicate, 0.6 part of trioctahedral basic aluminum silicate, and 4 parts of zinc oxide.

[0030] In this embodiment, the preparation method of the above-mentioned high-reinforced fire-resistant cable sheath material includes the following steps:

[0031] S1. Weigh phenyl silicone rubber, fumed silica, precipitated silica and hydroxy silicone oil according to the proportion, and send them into the kneader for mixing. The mixing temperature is 175°C, and the mixing t...

Embodiment 3

[0035] A high-reinforcement fire-resistant cable sheath material, the raw materials of which include by weight:

[0036] 90 parts of phenyl silicone rubber, 23 parts of fumed silica, 16 parts of precipitated silica, 1.9 parts of octamethylcyclotetrasiloxane, 43 parts of calcium carbonate, 11 parts of quartz powder, 1.5 parts of hydroxyl silicone oil, poly 1.8 parts of siloxane, 0.00043 parts of platinum catalyst, 21 parts of aluminum hydroxide, 21 parts of magnesium hydroxide, 1.2 parts of dioctahedral basic aluminum silicate, 0.6 part of trioctahedral basic aluminum silicate, and 6.7 parts of zinc oxide.

[0037] In this embodiment, the preparation method of the above-mentioned high-reinforced fire-resistant cable sheath material includes the following steps:

[0038] S1. Weigh phenyl silicone rubber, fumed silica, precipitated silica and hydroxyl silicone oil according to the proportion, and send them to the kneader for mixing. The mixing temperature is 180°C, and the mixing...

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PUM

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Abstract

The invention discloses a high reinforced fireproof cable sheath material. Raw materials of the high reinforced fireproof cable sheath material comprise, by weight, 85-95 parts of phenyl siloxane rubber, 20-25 parts of fumed silica, 13-17 parts of precipitated silica, 1.5-2 parts of otcamethylcyclotetrasiloxane, 40-50 parts of calcium carbonate, 5-13 parts of quartz powder, 1.2-1.7 parts of hydroxy silicone oil, 1.5-2.3 parts of polysiloxane, 0.00026-0.00058 parts of a platinum catalyst, 17-23 parts of aluminum hydroxide, 15-25 parts of magnesium hydroxide, 1-1.5 parts of dioctahedral alkali aluminum silicate, 0.4-0.7 parts of trioctahedral alkali aluminum silicate and 3-8 parts of zinc oxide. The invention also discloses a preparation method of the high reinforced fireproof cable sheath material. The high reinforced fireproof cable sheath material has the advantages of high reinforcing strength, good ablation resistance, excellent fireproof and fire-retardant properties, low production cost and simple preparation process.

Description

technical field [0001] The invention relates to the technical field of cable sheaths, in particular to a high-strength fire-resistant cable sheath material and a preparation method thereof. Background technique [0002] With the improvement of social safety awareness, many application fields have clearly put forward the flame retardant performance requirements for the rubber materials used. Usually, halogen-containing rubber matrix is ​​used or halogen flame retardant is added to the rubber matrix to achieve excellent flame retardant effect. , although the effect is very good, it emits a large amount of poisonous and corrosive gas when burning, accompanied by a large amount of smoke. With the increasingly stringent environmental protection and recycling regulations and the continuous emergence of new sheath materials, traditional cable materials are facing huge challenges. The current technology mainly uses halogen-free low-smoke flame-retardant rubber, mainly silicone rubbe...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L83/04C08L83/06C08K13/06C08K9/06C08K3/34C08K3/36C08K3/26C08K3/22H01B7/295
Inventor 余金余
Owner ANHUI DINGXING CABLE
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