Method for manufacturing NbTi-CuNi-Cu superconductive composite wire rod

A technology of nbti-cuni-cu and composite wire, which is applied in the field of superconducting wire preparation technology, can solve the problems of reducing the processing amount of passes, environmental pollution, increasing production cycle, etc., and is beneficial to hot extrusion and cold drawing processing , reduce costs, reduce the effect of production costs

Active Publication Date: 2014-07-30
西部超导材料科技股份有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Although CuNi alloy has a relatively high resistivity, its cold workability is poor, and its work hardening is relatively serious. It is not suitable for cold drawing processing with large deformation. It needs to reduce the amount of processing in passes, and the production efficiency is low. In order to eliminate work hardening, the production cycle is increased; while the cost of Ni plating is high, and a good coating generally only reaches a few microns, the subsequent conductor preparation and magnet winding process are easy to damage the coating, and the superconducting wire needs to be Ni The coating is removed by chemical method, but the Cu matrix material cannot be damaged, the process operation is cumbersome, and the electroplating production process also has environmental pollution problems

Method used

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  • Method for manufacturing NbTi-CuNi-Cu superconductive composite wire rod

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preparation example Construction

[0028] A kind of preparation method of NbTi-CuNi-Cu superconducting composite wire of the present invention specifically comprises the following steps:

[0029] step 1:

[0030] Take cleaned NbTi alloy rods and Cu tubes with a diameter of Φ20-250mm, the mass percentage content of Ti in the NbTi alloy rods is 45%-50%, and the wall thickness of the Cu tubes is 1 / 20-20% of the diameter of the NbTi alloy rods. 1 / 5, and then put the NbTi alloy rod into the Cu tube, you can add a cleaned Nb tube between the NbTi alloy rod and the Cu tube according to the performance requirements of the finished wire, and the thickness of the Nb tube is 1 of the diameter of the NbTi alloy rod. / 350-1 / 70, the NbTi / Cu single-core composite billet is obtained by hot extrusion or casing stretching. When hot extrusion is used, the two ends of the Cu tube need to be vacuum sealed with copper caps before processing;

[0031] Step 2:

[0032] The NbTi / Cu single-core composite rod obtained in step 1 is stre...

Embodiment 1

[0041]Adopt the Nb tube that the wall thickness is 2mm, the outer diameter is Φ151mm, and the Cu tube of the outer diameter Φ185mm, the inner diameter Φ156mm and the NbTi alloy rod (the mass percentage content of Ti 45wt%) of diameter Φ146mm, after cleaning, the NbTi alloy rod is packed into the Nb tube, and then put them into the Cu tube together. After sealing and welding at both ends, they are hot-extruded into a NbTi / Cu single-core composite billet; then the NbTi / Cu single-core composite billet is processed into a pair of Hexagonal rods with a side specification of 6.5mm, the pass processing rate is 10%; 528 hexagonal rods are cleaned and put into a Cu tube with an outer diameter of Φ182mm and an inner diameter of Φ170mm, and the Cu tube is then fitted with a wall thickness of 3mm and an outer diameter of Φ189mm CuNi alloy tube (the mass percentage content of Ni is 5wt%), and the gap part is filled with a small copper rod, and a Cu sheath with an outer diameter of Φ216mm an...

Embodiment 2

[0044] Three Nb coils with a thickness of 0.5mm are used to make Nb tubes with diameters of Φ171mm, Φ172mm, and Φ173mm, and they are packaged together from small to large, as well as Cu tubes with an outer diameter of Φ182mm and an inner diameter of Φ173mm and NbTi alloy rods of Φ169mm (Ti mass percentage Content 47wt%), after cleaning respectively, put the NbTi alloy rod into the coiled Nb tube, then put it into the Cu tube together, and heat-extrude it into a NbTi / Cu single-core composite billet after sealing and welding at both ends; then NbTi / Cu The Cu single-core composite bar blank is processed into a hexagonal bar with an opposite side specification of 15.2mm after multiple cold drawing and stretching, with a pass processing rate of 15%; 102 hexagonal bars are cleaned and loaded into Cu with an outer diameter of Φ183mm and an inner diameter of Φ175mm In the tube, the gap part is filled with a small copper rod, and the CuNi alloy tube with an outer diameter of Φ179.6mm an...

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Abstract

The invention discloses a method for manufacturing an NbTi-CuNi-Cu superconductive composite wire rod. The method comprises the following steps of putting an NbTi alloy rod into a Cu tube, and obtaining an NbTi-Cu single-core composite rod blank through a hot extrusion or sleeve extension method; extending the NbTi-Cu single-core composite rod blank to a hexagonal rod to obtain an NbTi-Cu single-core composite rod, putting the NbTi-Cu single-core composite rod into a copper tube to manufacture an NbTi-Cu multi-core composite rod; putting the NbTi-Cu single-core composite rod or the NbTi-Cu multi-core composite rod into a copper tube, sleeving a CuNi tube with the copper tube, sleeving another copper tube with the CuNi tube, and sealing two ends of the copper tube; reducing space in the copper tube through a hot isostatic pressure method and performing hot extrusion to obtain an NbTi-CuNi-Cu composite rod; performing multiple cold extension and aging treatment on the NbTi-CuNi-Cu composite rod to obtain the superconductive composite wire rod with the required dimension and shape. By means of the method, alternating current loss of the NbTi superconductive composite wire rod is reduced, production processes are simplified, and production cost is reduced.

Description

technical field [0001] The invention belongs to the technical field of superconducting wire preparation technology, and in particular relates to a preparation method of NbTi-CuNi-Cu superconducting composite wire. Background technique [0002] NbTi superconducting wire is currently the most widely used low-temperature superconducting material, and is widely used in the manufacture of superconducting magnets, nuclear magnetic resonance instruments, large particle accelerators, magnetically confined controllable nuclear fusion devices and other fields. In order to reduce the AC loss of the NbTi superconducting composite wire in the alternating magnetic field and reduce the electromagnetic coupling effect of the wire core wire, it is necessary to increase the contact resistance between the wires. CuNi alloys are often used to directly replace pure Cu as the matrix material or in pure Cu. A layer of pure Ni coating is processed outside the superconducting composite wire of the s...

Claims

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Application Information

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IPC IPC(8): H01B13/00H01B12/04
CPCY02E40/60
Inventor 刘维涛李建峰严凌霄侯婧高慧贤
Owner 西部超导材料科技股份有限公司
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