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Manufacturing method for high-performance NdFeB rare earth permanent magnet devices

一种稀土永磁、制造方法的技术,应用在电感/变压器/磁铁制造、磁性材料、电气元件等方向,能够解决稀土短缺、工艺研究不够深入、纳米氧化物易吸潮等问题

Active Publication Date: 2014-08-20
SHENYANG GENERAL MAGNETIC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] With the wide application of NdFeB rare earth permanent magnets, rare earths are becoming more and more scarce, especially heavy rare earth elements are obviously becoming scarce, and the price of rare earths has risen again and again; for this reason, people have carried out many explorations, and double alloys have appeared. technology, metal infiltration technology, improvement or recombination of grain boundary phase technology, etc.; patent CN101521069B is a technology disclosed by Yue Ming, Beijing University of Technology, etc., who doped heavy rare earth hydride nanoparticles to prepare NdFeB. , followed by hydrogen crushing and jet milling, and then mixing the heavy rare earth hydride nanoparticles produced by physical vapor deposition technology with the aforementioned powder, and then manufacturing NdFeB magnets through conventional processes such as magnetic field molding and sintering, although the patent A method to improve the coercive force of magnets has been found, but the process research is not deep enough, and there are problems in mass production. Patents CN101,383,210B; CN101,364,465B; CN101,325,109B; CN101,325,109B disclose similar technologies, performance The improvement is limited, nano oxides are easy to absorb moisture, the absorbed moisture seriously affects product performance, and the product consistency is poor

Method used

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  • Manufacturing method for high-performance NdFeB rare earth permanent magnet devices

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0051] According to the composition in Table 1, 600Kg of R-Fe-B-M alloy is selected for melting, and the alloy is cast on a rotating copper roll with water cooling in the molten state to cool to form an alloy sheet; Manufactured in a quenching furnace, the rotational speed of the molybdenum wheel is selected to be 15m / s; the microcrystalline Dy-Fe alloy fiber and the R-Fe-B-M alloy sheet are selected according to the ratio listed in Table 1 for hydrogen crushing, and the microcrystalline Dy-Fe alloy after hydrogen crushing The fiber and the R-Fe-B-M alloy sheet are put into the mixer together, and then T is added according to the ratio in Table 1. m G n Chemical powder, mixed under the protection of nitrogen, the mixing time is 60 minutes, jet milling after mixing, the powder collected by the cyclone collector and the ultrafine powder collected by the filter are put into the post-mixer for further processing Post-mixing, the post-mixing is also carried out under the protectio...

Embodiment 2

[0053] Select 600Kg of R-Fe-B-M alloy according to the composition in Table 1 for smelting, inductively heat and melt the R-Fe-Co-B-M raw material under vacuum or argon protection to form an alloy, refine it at 1400-1470°C, and melt the molten alloy liquid after refining Casting through the tundish on the rotating roller with water cooling, the rotating roller speed is 1m / s, the molten alloy is cooled by the rotating roller to form alloy flakes, and the alloy flakes leave the rotating copper roller and then fall on the turntable for secondary cooling; HR-Fe alloy fiber (80%HR) is manufactured by vacuum quenching furnace, and the rotation speed of molybdenum wheel is 18m / s respectively; microcrystalline Dy-Fe alloy fiber and R-Fe-B-M alloy sheet are selected according to the ratio listed in Table 1. Hydrogen crushing, the microcrystalline Dy-Fe alloy fibers and R-Fe-B-M alloy sheets after hydrogen crushing are put into the mixer together, and then add T m G n Chemical powder, ...

Embodiment 3

[0055] Select 600Kg of R-Fe-B-M alloy according to the composition in Table 1 for smelting, inductively heat and melt the R-Fe-Co-B-M raw material under vacuum or argon protection to form an alloy, refine it at 1400-1470°C, and melt the molten alloy liquid after refining Casting through the tundish on the rotating roller with water cooling, the rotating roller speed is 2m / s, the molten alloy is cooled by the rotating roller to form alloy flakes, and the alloy flakes fall immediately after leaving the rotating copper roller, and the alloy flakes are broken after falling. Enter the receiving box, and then cool the alloy sheet with an inert gas; the microcrystalline HR-Fe alloy fiber (80%HR) is manufactured by a vacuum quenching furnace, and the rotation speed of the molybdenum wheel is respectively selected at 22m / s; the ratio listed in Table 1 is selected The microcrystalline Dy-Fe alloy fibers and R-Fe-B-M alloy sheets are subjected to hydrogen crushing, and the microcrystallin...

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Abstract

The invention discloses a manufacturing method for high-performance NdFeB rare earth permanent magnet devices. The high-performance NdFeB rare earth permanent magnet devices are made of R-Fe-Co-B-M rapid-hardening alloy, microcrystal HR-Fe alloy fibers and TmGn compound micro-powder. The manufacturing method comprises the steps of manufacturing the R-Fe-Co-B-M rapid-hardening alloy, manufacturing the microcrystal HR-Fe alloy fibers, performing hydrogen decrepitation on the alloy, performing mixing before pulverization, performing pulverization in a grinding mode through air flow, performing mixing after pulverization, forming a magnetic field, performing sintering and performing aging. In this way, a sintered NdFeB permanent magnet is manufactured, and machining and surface treatment are performed on the sintered NdFeB permanent magnet to manufacture various rare earth permanent magnet devices.

Description

technical field [0001] The invention belongs to the field of rare earth permanent magnets, in particular to a method for manufacturing high-performance NdFeB rare earth permanent magnet devices. Background technique [0002] NdFeB rare earth permanent magnet materials, with their excellent magnetic properties, have been used more and more, and are widely used in medical nuclear magnetic resonance imaging, computer hard drives, audio, mobile phones, etc.; with the requirements of energy saving and low-carbon economy , NdFeB rare earth permanent magnet materials have begun to be used in auto parts, household appliances, energy saving and control motors, hybrid vehicles, wind power generation and other fields. [0003] In 1983, Japanese patents 1,622,492 and 2,137,496 first disclosed the NdFeB rare earth permanent magnet material invented by Sumitomo Metal, announced the characteristics, composition and manufacturing method of the NdFeB rare earth permanent magnet material, and...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01F41/02H01F1/057B22F1/062
CPCC22C38/32H01F1/0577H01F41/0273B22F9/023B22F2998/10B22F2999/00C22C38/16C22C38/14C22C38/10C22C38/06C22C38/005C22C38/002B22F1/062C22C1/12C22C1/11B22F9/08B22F9/04B22F2009/044B22F3/02B22F3/1021B22F3/1028B22F2003/247B22F1/09B22F1/10
Inventor 孙宝玉
Owner SHENYANG GENERAL MAGNETIC
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