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Metamorphic epitaxial growth method based on nano patterned substrate

An epitaxial growth and nano-patterning technology, applied in nanotechnology, electrical components, semiconductor/solid-state device manufacturing, etc., to improve crystal quality, reduce threading dislocation density, and eliminate material contamination

Inactive Publication Date: 2014-08-27
BEIJING UNIV OF POSTS & TELECOMM
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0011] In view of the defects of the above-mentioned metamorphic epitaxy method, the technical problem to be solved in the present invention is how to prepare a nano-patterned substrate with a relatively simple process and low cost, and then realize a high degree of crystal lattice mismatch between two materials. High-quality heterogeneous epitaxial growth, greatly reducing the threading dislocation density in heterogeneous epitaxy materials, meeting the requirements for the preparation of high-performance optoelectronic integrated devices

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  • Metamorphic epitaxial growth method based on nano patterned substrate
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Embodiment 1

[0046] Embodiment 1 of the present invention provides a heterogeneous epitaxial growth method based on a nano-patterned substrate, and the steps are as follows: figure 1 As shown, it specifically includes the following steps:

[0047] Step S1: forming a single-layer arrangement of nanospheres on the substrate, or on a virtual substrate on which a specific epitaxial layer has been deposited, and controlling the size of the gap between the nanospheres.

[0048] Nanospheres can be silicon dioxide (SiO 2 ), silicon nitride (SiN x ), titanium dioxide (TiO 2 ), polystyrene (PS) and other mono-dispersed (mono-dispersed) beads.

[0049] Among them, to carry out the single-layer coating of silica nanospheres, what is used in this embodiment is the monodisperse SiO that is dissolved in absolute ethanol in advance. 2 Small spheres, containing SiO per milliliter of solution 2 Pellets 0.21 g. Monodisperse nanospheres with uniform size are used. The diameter of monodisperse nanosphere...

Embodiment 2

[0069] Embodiment 2 of the present invention also provides a heterogeneous epitaxial growth method based on a nano-patterned substrate. The difference from Embodiment 1 is that GaAs / Si heterogeneous epitaxy growth is performed in Embodiment 2, including:

[0070] 1. Firstly, a GaAs / Si dummy substrate 81 is grown using traditional two-step method and assisted thermal cycle annealing (TCA), inserting strained layer superlattice (SLS) and other technologies. The GaAs / Si dummy substrate is composed of a Si substrate 811 with a (100) crystal orientation and an epitaxial layer 812 of GaAs.

[0071] 2. SiO is formed on the surface of the dummy substrate 81 2 Monolayer ordered films of small spheres, SiO 2 The diameter of the pellet is 500nm.

[0072] 3. Using reactive ion etching (RIE) on SiO 2 The small balls are subjected to gap expansion treatment, and the SiO 2 The bead gap increases to about 100nm. Gap expansion process as attached Figure 7 As shown, the shape of the smal...

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Abstract

The invention discloses a metamorphic epitaxial growth method based on a nano patterned substrate. The method includes the following steps: on a substrate or on a virtual substrate on which a specific metamorphic epitaxial layer is deposited, single-layer array of nano-spheres is formed and the sizes of gaps of the nano-spheres are controlled; the gaps of the nano-spheres are connected together so that a nano scale pattern is formed; the nano-spheres are used as a mask to deposit an epitaxial layer material in the gaps of the nano-spheres and the epitaxial layer material is closely combined with the substrate or the virtual substrate so that the deposited thickness of the epitaxial layer material is increased and the epitaxial layer material is enabled to be higher than the nano-spheres. The epitaxial layer material grows laterally and then is combined so as to cover completely the nano-spheres and thus the surface roughness of the epitaxial layer material is reduced. Growth windows of the gaps of the nano-spheres have the characteristics of being narrow in width and high in aspect ratio and the nano-spheres are capable of effectively blocking continued upward penetration of threading dislocation in the epitaxial layer, caused by lattice mismatch between the substrate and the epitaxial layer so that the quality of the metamorphic epitaxial material is improved significantly and a metamorphic epitaxial growth problem among lattice mismatch materials is solved.

Description

technical field [0001] The invention relates to the field of semiconductor optoelectronic integration, in particular to a method for heterogeneous epitaxial growth based on a nano-pattern substrate. Background technique [0002] With the rapid increase in the demand for network bandwidth and switching speed, huge technical challenges are posed to optical transmission systems and networks that carry information. At present, network terminals and node equipment still mainly rely on discrete optoelectronic devices, which makes the problems of volume, function, power consumption, reliability, cost and other aspects increasingly prominent, and can no longer meet the development requirements of the new generation of optical communication systems and networks. Realizing optoelectronic integration is the only effective way to solve these problems. [0003] After more than 30 years of hard work, optoelectronic integration technology has made considerable progress, but compared with ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L21/20B82Y40/00
CPCB82Y40/00H01L33/0062
Inventor 王琦边志强任晓敏贾志刚闫映策蔡世伟黄永清
Owner BEIJING UNIV OF POSTS & TELECOMM
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