Metamorphic epitaxial growth method based on nano patterned substrate
An epitaxial growth and nano-patterning technology, applied in nanotechnology, electrical components, semiconductor/solid-state device manufacturing, etc., to improve crystal quality, reduce threading dislocation density, and eliminate material contamination
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Embodiment 1
[0046] Embodiment 1 of the present invention provides a heterogeneous epitaxial growth method based on a nano-patterned substrate, and the steps are as follows: figure 1 As shown, it specifically includes the following steps:
[0047] Step S1: forming a single-layer arrangement of nanospheres on the substrate, or on a virtual substrate on which a specific epitaxial layer has been deposited, and controlling the size of the gap between the nanospheres.
[0048] Nanospheres can be silicon dioxide (SiO 2 ), silicon nitride (SiN x ), titanium dioxide (TiO 2 ), polystyrene (PS) and other mono-dispersed (mono-dispersed) beads.
[0049] Among them, to carry out the single-layer coating of silica nanospheres, what is used in this embodiment is the monodisperse SiO that is dissolved in absolute ethanol in advance. 2 Small spheres, containing SiO per milliliter of solution 2 Pellets 0.21 g. Monodisperse nanospheres with uniform size are used. The diameter of monodisperse nanosphere...
Embodiment 2
[0069] Embodiment 2 of the present invention also provides a heterogeneous epitaxial growth method based on a nano-patterned substrate. The difference from Embodiment 1 is that GaAs / Si heterogeneous epitaxy growth is performed in Embodiment 2, including:
[0070] 1. Firstly, a GaAs / Si dummy substrate 81 is grown using traditional two-step method and assisted thermal cycle annealing (TCA), inserting strained layer superlattice (SLS) and other technologies. The GaAs / Si dummy substrate is composed of a Si substrate 811 with a (100) crystal orientation and an epitaxial layer 812 of GaAs.
[0071] 2. SiO is formed on the surface of the dummy substrate 81 2 Monolayer ordered films of small spheres, SiO 2 The diameter of the pellet is 500nm.
[0072] 3. Using reactive ion etching (RIE) on SiO 2 The small balls are subjected to gap expansion treatment, and the SiO 2 The bead gap increases to about 100nm. Gap expansion process as attached Figure 7 As shown, the shape of the smal...
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