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Bauxite direct flotation composite collector and application method thereof

A bauxite and positive flotation technology, used in flotation, solid separation and other directions, can solve the problems of increasing the difficulty of wastewater treatment, poor flotation desilication effect, and increasing the cost of concentrate treatment, and achieve excellent performance. and wetting ability, excellent emulsifying and penetrating effect, beneficial to concentrate filtration

Inactive Publication Date: 2014-11-19
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Fatty acid collectors have poor dispersibility, low temperature and hard water resistance, and strong foaming performance are the main reasons for the large use of fatty acid collectors
[0004] With the large-scale mining of bauxite, the bauxite with high aluminum-silicon ratio is almost exhausted, and the development and utilization of low-aluminum-silicon ratio bauxite is the general trend. Ridge stone, illite pyrophyllite and other friable aluminosilicate minerals are high in content, and aluminosilicate minerals are easy to muddy during the grinding process. large amount
In addition, a small amount of hydroxamic acid is added to general bauxite flotation reagents to enhance the flotation effect, while hydroxamic acid collectors have certain physiological toxicity, and are not easy to decompose in the natural state, and rich in water The assembly causes eutrophication of the water body and cannot be discharged directly, which increases the difficulty of wastewater treatment and increases the cost of wastewater establishment
At present, due to some factors such as overcapacity, the alumina industry has entered the era of meager profits. The reduction of ore quality and the problems of existing collectors have increased the cost of beneficiation, and at the same time increased the cost of subsequent concentrate treatment. Cost issues have become restrictions on mining. Important Factors for Utilizing Low Al-Si Ratio Bauxite

Method used

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  • Bauxite direct flotation composite collector and application method thereof
  • Bauxite direct flotation composite collector and application method thereof
  • Bauxite direct flotation composite collector and application method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] The chemical multi-element analysis results of a diaspore-type bauxite with a low aluminum-silicon ratio in Henan are listed in Table 1.

[0043] Table 1 Chemical multi-element analysis results of a diaspore-type bauxite with a low aluminum-silicon ratio in Henan

[0044] project

Al 2 o 3

SiO 2

MgO

CaO

TF

A / S

Content (%)

55.43

17.49

0.31

0.59

4.53

3.17

[0045] The ore samples were ground until the grinding fineness was -0.074㎜, accounting for 93%, and the collector type comparison test was carried out. The collectors used included oleic acid + OP-10, oleic acid + Tween-80, and the composite collector of the present invention Collector (oleic acid + synergist, synergist includes: compound of silicone surfactant, polyoxyethylene ether surfactant and mine foaming agent). The dosage of medicine is: oleic acid 800g / t, sodium carbonate 4000g / t, water glass 1000g / t, the mass ratio of synergist and ...

Embodiment 2

[0055] The degree of polymerization of ethylene oxide is 7-15 (ie n 1=7-15) the applicability of the polyoxyethylene surfactant in the collector of the present invention, choose the polyoxyethylene surfactant that degree of polymerization is 7,10,15 as polyoxyethylene ether described in the present invention Surfactants were subjected to roughing tests. The dosage of medicine is: oleic acid 800g / t, sodium carbonate 4000g / t, water glass 1000g / t, synergist (polyoxyethylene ether: silicone: pine alcohol oil mass ratio = 2:3:5) and fatty acid mass ratio The ratio is 1:4, and the results are shown in Table 3.

[0056] Table 3 Applicability test of polyoxyethylene ether surfactants

[0057]

[0058] From the test results, it can be seen that the selection of polyoxyethylene ether surfactants with different degrees of polymerization has little effect on the recovery rate of crude concentrate and the ratio of aluminum to silicon, which proves that polyoxyethylene ethers with a de...

Embodiment 3

[0060] For proving the applicability of mine foaming agents such as terpineol oil and isooctyl alcohol in the present invention, roughing test is carried out as mine foaming agents described in the present invention with pine alcohol oil and isooctyl alcohol. The dosage is: oleic acid 800g / t, sodium carbonate 4000g / t, water glass 1000g / t, synergist (polyoxyethylene ether: silicone: terpineol oil / isooctanol mass ratio = 2:3:5) The mass ratio with fatty acid is 1; 4, and the test results are shown in Table 2.

[0061] Table 4 Applicability test of mine foaming agent

[0062]

[0063] The test shows that when different types of mine foaming agents are used as the mine foaming agent described in the present invention, the recovery rate of bauxite coarse concentrate alumina and the ratio of aluminum to silicon have little difference, which proves that different types of mine foaming agents Agents are applicable to the mine foaming agent described in the present invention.

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Abstract

The invention discloses a collector for bauxite direct flotation desilicification and an application method of the collector. The collector is characterized by comprising the chemical component of a mixture of monocarboxyl fatty acid, an organosilicon surfactant, a polyoxyethylene ether surfactant and a mining foaming agent, wherein the compounding mass percents of the monocarboxyl fatty acid, the organosilicon surfactant, the polyoxyethylene ether surfactant and the mining foaming agent are 70-80%, 5-10%, 5-10% and 10-20% respectively. The collector has the obvious advantages that by adding the surfactants without collecting ability, the dispersing performance of the fatty acid collector is improved, the collecting performance of the fatty acid collector is improved, recovery of aluminum oxide is improved, and the use quantity of medicaments is reduced; on the condition of not conducting desliming, the flotation effect of diaspore bauxite with a medium and low alumina-silica ratio (2.5-5) is prominent.

Description

technical field [0001] The invention belongs to the field of mineral processing, and relates to a bauxite positive flotation composite collector and an application method thereof. Background technique [0002] More than 90% of my country's alumina resources belong to diaspore bauxite. After the last ten years of predatory mining, my country's bauxite resources have been severely depleted and depleted. The aluminum-silicon ratio of raw ore in alumina plants has been decreasing year by year. By 2012, the ratio of aluminum to silicon in alumina plants in my country will basically remain between 2.5 and 5. Since 2003, Aluminum Corporation of China Zhongzhou Branch adopted the new technology of bauxite beneficiation and desiliconization-Bayer method to produce alumina, and more than 80% of the medium and low-grade bauxite in my country can be processed by this method. Compared with other methods, the Bayer method has lower energy consumption, but requires the aluminum-silicon ra...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B03D1/016B03D101/02
Inventor 曹学锋胡岳华孙伟高建德黄红军朱溢洋
Owner CENT SOUTH UNIV
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