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Modified hydrogenated butadiene-acrylonitrile rubber cable sheath material

A hydrogenated nitrile rubber and cable sheathing technology, which is applied in the field of cable sheathing, can solve the problems of soft and sticky rubber sheath material, deterioration of physical and mechanical properties, long service life of rubber, etc., and achieve enhanced aging performance and excellent Good gas barrier performance and aging resistance

Inactive Publication Date: 2014-12-17
安徽华峰电缆集团有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The rubber sheath material of traditional cables is affected by heat energy, mechanical energy, light energy and radiation energy during long-term storage and use, plus the chemical reactions involving oxygen, ozone, moisture, variable-valence metals and metal ions, the rubber sheath material gradually The aging phenomenon of becoming soft and sticky, hard and brittle or cracked will cause its physical and mechanical properties to deteriorate or even lose its original performance, resulting in failure of the cable during use and corrosion of other components inside the cable sheath The function cable cannot run normally, and during use, due to friction with other objects, the rubber surface is damaged or even loses its original performance, and the rubber is used for too long, and the aging speed becomes faster. How to prepare a Cable sheath materials with good flame retardancy, heat resistance, wear resistance and aging resistance have become a technical problem to be solved at present

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0011] A modified hydrogenated nitrile butadiene rubber cable sheath material, the raw materials of which include by weight: 20 parts of EPDM rubber, 60 parts of modified hydrogenated nitrile butadiene rubber, 20 parts of natural rubber, 2.5 parts of sulfur, and 3 parts of zinc oxide , 3 parts of stearic acid, 2 parts of antioxidant 4010NA, 1.5 parts of accelerator DM, 20 parts of carbon black, 40 parts of kaolin, 5 parts of microencapsulated red phosphorus, 25 parts of ammonium polyphosphate, 6 parts of nylon PA-666, microcrystalline 7 parts of paraffin, 13 parts of diatomaceous earth, 10 parts of reinforcing carbon black, 11 parts of calcined clay, 7 parts of light calcium carbonate, 1.5 parts of anti-aging agent RD;

[0012] Wherein the modified hydrogenated nitrile rubber is prepared by the following process: the expanded graphite is placed in acetone and stirred and mixed for 3 days, then crushed with ultrasonic waves, the ultrasonic frequency is 1500 Hz, and the ultrasoni...

Embodiment 2

[0014] A modified hydrogenated nitrile butadiene rubber cable sheath material, the raw materials of which include by weight: 30 parts of EPDM rubber, 40 parts of modified hydrogenated nitrile butadiene rubber, 30 parts of natural rubber, 2 parts of sulfur, and 5 parts of zinc oxide , 1 part of stearic acid, 2.5 parts of antioxidant 4010NA, 1 part of accelerator DM, 30 parts of carbon black, 30 parts of kaolin, 13 parts of microencapsulated red phosphorus, 20 parts of ammonium polyphosphate, 10 parts of nylon PA-66, microcrystalline 6 parts of paraffin, 10 parts of diatomaceous earth, 18 parts of reinforcing carbon black, 6 parts of calcined clay, 10 parts of light calcium carbonate, 0.8 part of anti-aging agent RD;

[0015] Wherein the modified hydrogenated nitrile rubber is prepared by the following process: the expanded graphite is placed in acetone and stirred and mixed for 4 days, then crushed with ultrasonic waves, the ultrasonic frequency is 1200Hz, and the ultrasonic tim...

Embodiment 3

[0017] A modified hydrogenated nitrile butadiene rubber cable sheath material, the raw materials of which include by weight: 26 parts of EPDM rubber, 56 parts of modified hydrogenated nitrile butadiene rubber, 24 parts of natural rubber, 2.35 parts of sulfur, and 4.1 parts of zinc oxide , 1.8 parts of stearic acid, 2.3 parts of antioxidant 4010NA, 1.32 parts of accelerator DM, 27 parts of carbon black, 37 parts of kaolin, 12 parts of microencapsulated red phosphorus, 23 parts of ammonium polyphosphate, 9 parts of nylon PA-669, microcrystalline 6.2 parts of paraffin, 11.5 parts of diatomite, 17 parts of reinforcing carbon black, 8.5 parts of calcined clay, 9.5 parts of light calcium carbonate, 1.25 parts of anti-aging agent RD;

[0018] Wherein the modified hydrogenated nitrile rubber is prepared by the following process: the expanded graphite is placed in acetone and stirred and mixed for 4 days, then crushed with ultrasonic waves, the ultrasonic frequency is 1400Hz, and the ul...

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PUM

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Abstract

The invention discloses a modified hydrogenated butadiene-acrylonitrile rubber cable sheath material. The modified hydrogenated butadiene-acrylonitrile rubber cable sheath material is characterized by comprising the following raw materials in parts by weight: 20-30 parts of ethylene propylene terpolymer, 40-60 parts of modified hydrogenated butadiene-acrylonitrile rubber, 20-30 parts of natural rubber, 2-2.5 parts of sulphur, 3-5 parts of zinc oxide, 1-3 parts of stearic acid, 2-2.5 parts of anti-ageing agent 4010NA, 1-1.5 parts of accelerant DM, 20-30 parts of carbon black, 30-40 parts of kaolin, 5-13 parts of microencapsulated red phosphorus, 20-25 parts of ammonium polyphosphate, 6-10 parts of nylon PA-66, 6-7 parts of microcrystalline wax, 10-13 parts of kieselguhr, 10-18 parts of reinforcing carbon black, 6-11 parts of calcined clay, 7-10 parts of light calcium carbonate and 0.8-1.5 parts of anti-ageing agent RD. The modified hydrogenated butadiene-acrylonitrile rubber cable sheath material disclosed by the invention has good flame retardant property, heat resistance and wear-resisting property, and excellent ageing-resistant performance.

Description

technical field [0001] The invention relates to the technical field of cable sheaths, in particular to a modified hydrogenated nitrile rubber cable sheath material. Background technique [0002] The rubber sheath material of traditional cables is affected by heat energy, mechanical energy, light energy and radiation energy during long-term storage and use, plus the chemical reactions involving oxygen, ozone, moisture, variable-valence metals and metal ions, the rubber sheath material gradually The aging phenomenon of becoming soft and sticky, hard and brittle or cracked will cause its physical and mechanical properties to deteriorate or even lose its original performance, resulting in failure of the cable during use and corrosion of other components inside the cable sheath The function cable cannot run normally, and during use, due to friction with other objects, the rubber surface is damaged or even loses its original performance, and the rubber is used for too long, and th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08K3/04C08K13/06C08K3/32C08L77/06C08L15/00C08K3/34C08L7/00C08K5/09C08L23/16C08K3/02C08K3/22C08K3/06
Inventor 郭绍华袁加夕王良云姚欢范宇赵加北
Owner 安徽华峰电缆集团有限公司
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