High-thermal-conductivity polymer conductive ink and production process thereof
A technology of conductive ink and conductive polymer, applied in ink, household appliances, applications, etc., can solve the problems of low conductivity and large interface resistance, and achieve the effect of low solid content, good dispersion stability and good thermal conductivity
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specific Embodiment 1
[0034] 1) Preparation of conductive polymer dispersion: Weigh 60.0% polyethylenedioxythiophene conductive polymer aqueous dispersion (1.5% solid content), add 5.0% dimethyl sulfoxide, and mix well;
[0035] 2) Preparation of resin solution: weigh 20.0% of water-based acrylic resin, add 5.0% of water-based thickener to mix with it, stir for 0.5h, grind for 0.5h and mix well;
[0036] 3) Preparation of functional unit particle dispersion: Weigh 3% of graphene prepared by chemical method, add ethanol 2 to 3 times the mass of graphene and polyethylene glycol with 0.5% mass of graphene, stir for 0.5h, and ultrasonically disperse for 0.5 h, mixing and dispersing evenly;
[0037] 4) Add 0.7-0.9% N,N-dimethylethanolamine to the conductive polymer dispersion prepared in step 1) to adjust the pH to 8-9;
[0038] 5) Mix the water-based acrylic resin solution obtained in the above steps, the graphene dispersion, and the pH-adjusted polyvinyldioxythiophene solution by mass percentage, the...
specific Embodiment 2
[0040] 1) Preparation of conductive polymer dispersion: Weigh 62.0% aqueous dispersion of polyethylenedioxythiophene doped with polystyrene sulfonate (PEDT:PSS) according to the formula, wherein the molar ratio of PEDT to PSS is 1 :0.5, add 5.0% dimethyl sulfoxide, mix well;
[0041] 2) Preparation of resin solution: weigh 15.0% of water-based polyurethane resin, add 4.0% of polyurethane resin mass of cellulose-based water-based thickener to mix with it, and stir for 2 hours to mix evenly;
[0042] 3) Preparation of functional unit particle dispersion: Weigh 8% graphene prepared by physical method, add ethanol 2~3 times the mass of graphene and polyethylene glycol with 0.5% mass of graphene, stir for 1h, ultrasonically disperse for 1h, mix Evenly dispersed;
[0043] 4) Add 1.0% N,N-dimethylethanolamine to the conductive polymer dispersion to adjust the pH to 9.
[0044] 5) Mix water-based polyurethane resin solution, graphene dispersion, and pH-adjusted PEDT:PSS dispersion, ...
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