Tackifier for drilling fluid and preparation method thereof

A technology for tackifier and drilling fluid, which is applied in the field of synthesizing treatment agent for oilfield drilling fluid, can solve the problems of insignificant increase in shear force, adverse environmental impact, decreased viscosity increasing effect, etc. ability, the effect of reducing the filtration effect

Active Publication Date: 2015-01-28
CHINA PETROCHEMICAL CORP +1
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Problems solved by technology

[0003] In the prior art, viscosifiers are mainly used to improve the rheology and suspension stability of drilling fluids, which can significantly increase the viscosity of drilling fluids, but the shear force is not significantly improved, especially in brine drilling fluids; the temperature resistance is average The temperature is 120°C, and the viscosity-increasing effect drops rapidly after exceeding, or even completely fails, such as biopolymer xanthan gum, 80A51, etc.
[0004] Patent 201010593450.8 discloses a drilling fluid anti-high temperature thickener and its preparation method. The mass ratio of each component is: starch: guar gum: alkaline hydroxide: epoxide: alcohol solvent = 1:0.05~ 5: 0.01~2: 0.02~6: 0~9, a large amount of organic solvent needs to be added in the preparation process, which will bring adverse effects on the environment; patent 201110184384.3 discloses a preparation method of a viscosity enhancer for drilling fluid, and the raw materials used are Acrylamide, water, initiator, sodium hydroxid

Method used

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  • Tackifier for drilling fluid and preparation method thereof
  • Tackifier for drilling fluid and preparation method thereof
  • Tackifier for drilling fluid and preparation method thereof

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[0026] Example 1:

[0027] (1) Dissolve 100g of acrylamide, 30g of A12-acrylamido-2-methylpropanesulfonic acid and 10g of B1N-vinylpyrrolidone in 120g of clean water, and adjust the pH to 7 with sodium hydroxide;

[0028] (2) Dissolve 0.14g C1N and N-methylenebisacrylamide in 5g clean water;

[0029] (3) Dissolve 0.14 g of D1 isopropanol in 5 g of clean water, add the solution obtained in step (1) and step (2) into the reaction vessel, and raise the temperature to 30°C;

[0030] (4) Dissolve 0.93g of ammonium persulfate and 0.47g of sodium bisulfite in 5g of water;

[0031] (5) Add the initiator solution obtained in step (4) to the reaction vessel of step (3) in sequence, and polymerize for 30 minutes to obtain a thickener product with a solid content of 50%. The product is dried and crushed to obtain Tackifier APN-1 for drilling fluid, its structural formula is:

[0032]

[0033] Purify the tackifier product obtained from the reaction in Example 1, and use an infrared spectrometer to d...

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Abstract

The invention relates to a tackifier for drilling fluid and a preparation method thereof, and belongs to the technical field of synthesis of processing agents for oil-field drilling fluids. The tackifier is a net-like polymer obtained by mixing acrylamide, a sulfo-group-containing monomer A and a pyrrolidone monomer B according to the mass ratio of 10:(3-5):(0.7-1.5), adjusting the pH value of the solution, adding a cross-linking agent C, a molecular-weight adjusting agent D and an initiator and performing copolymerization crosslinking. The preparation method is simple and practicable, and short in reaction time. The obtained tackifier has good salt resistance, has the temperature resistance up to 135 DEG C, has good effects of increasing shear viscosity and reducing filter loss when being applied to drilling fluids, is capable of substantially improving the cutting carrying capability of the drilling fluids under the condition of high temperature, has the effect obviously better than a tackifier normally used on site, is widely applicable to fresh-water drilling fluids and saturated brine drilling fluids, and has relatively good application prospect.

Description

technical field [0001] The invention relates to a viscosifier for drilling fluid and a preparation method thereof, and belongs to the technical field of synthesis of treatment agents for oilfield drilling fluid. technical background [0002] In recent years, with the continuous deepening of oil and gas exploration and development, the formations encountered by drilling have become increasingly complex, such as high temperature, high salt content, salt-gypsum formations, and water-sensitive formations. Salt resistance and temperature resistance, rock carrying and stable borehole wall and other properties, which require some drilling fluid treatment agents with high temperature resistance and salt resistance to meet the requirements of preparing high-performance drilling fluids. Among them, drilling fluid viscosity enhancers It is an important class of treatment agents for drilling fluids. Under the condition of high temperature and high salinity, the viscosifier in the drill...

Claims

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Application Information

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IPC IPC(8): C08F220/56C08F220/58C08F226/10C08F226/06C08F222/38C08F222/14C09K8/035C09K8/04
Inventor 马文英李晓岚舒尚文李保慧钟灵
Owner CHINA PETROCHEMICAL CORP
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