Nickel-iron-phosphorus/nano V8C7 composite electroplating solution

A composite electroplating, V8C7 technology, applied in the direction of electrolytic coatings, coatings, etc., can solve the problems of fracture failure, localized adiabatic shear band single shear crack, etc., to achieve less energy consumption, high raw material utilization, plating solution The effect of simple ingredients

Inactive Publication Date: 2015-03-25
CHANGSHA UNIVERSITY OF SCIENCE AND TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, when amorphous materials are deformed at room temperature, it is easy to indu

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] (1) Nano V 8 C 7 For the pretreatment of powder, first weigh 8 grams of nano V 8 C 7 powder, add 500ml of 15wt% hydrochloric acid solution, heat to 60°C in a water bath, stir for 30min, and V 8 C 7 Wash the powder twice with deionized water after filtration;

[0020] (2) First weigh 0.1 g of tartaric acid and 0.1 g of sodium dodecylbenzenesulfonate, add 1000 ml of deionized water, heat to 90°C in a water bath, and stir until tartaric acid and sodium dodecylbenzenesulfonate dissolved; then weigh 100 grams of nickel sulfate (NiSO 4 ·6H 2 O), 15 grams of nickel chloride (NiCl 2 ·6H 2 O), 50 grams of ferrous sulfate (FeSO 4 ·7H 2 O), 10 grams of ferrous chloride (FeCl 2 4H 2 O), 30 grams of sodium hypophosphite (NaH 2 PO 2 ·H 2 O), 3 grams of ascorbic acid, 20 grams of boric acid (H 3 BO 3 ) was added to the above solution, stirred at room temperature until dissolved; then added the cleaned V 8 C 7 The powder was continuously stirred for 2 hours, then 0.2...

Embodiment 2

[0022] (1) Nano V 8 C 7 For the pretreatment of powder, first weigh 10 grams of nanometer V 8 C 7 powder, add 500ml of 15wt% hydrochloric acid solution, heat to 60°C in a water bath, stir for 30min, and V 8 C 7 Wash the powder twice with deionized water after filtration;

[0023] (2) First weigh 0.1 g of tartaric acid and 0.1 g of sodium dodecylbenzenesulfonate, add 1000 ml of deionized water, heat to 90°C in a water bath, and stir until the sodium dodecylbenzenesulfonate is dissolved; Then weigh 80 grams of nickel sulfate (NiSO 4 ·6H 2 O), 10 grams of nickel chloride (NiCl 2 ·6H 2 O), 40 grams of ferrous sulfate (FeSO 4 ·7H 2 O), 15 grams of ferrous chloride (FeCl 2 4H 2 O), 35 grams of sodium hypophosphite (NaH 2 PO 2 ·H 2 O), 3 grams of ascorbic acid, 10 grams of boric acid (H 3 BO 3 ) was added to the above solution, stirred at room temperature until dissolved; then added the cleaned V 8 C 7 The powder was continuously stirred for 2 hours, then 0.2 g of ...

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Abstract

The invention discloses a nickel-iron-phosphorus/nano V8C7 composite electroplating solution. According to a formula, the composite electroplating solution comprises 70-120g/L of nickel sulfate, 10-20g/L of nickel chloride, 40-80g/L of iron sulfate, 10-20g/L of iron chloride, 20-40g/L of sodium hypophosphite, 10-25g/L of boric acid, 0.1-0.5g/L of a complexing agent, 0.1-0.5g/L of a brightener, 2-5g/L of a stabilizer and 5-20g/L of nano V8C7. Compared with the prior art, the composite electroplating solution disclosed by the invention has the advantages that a composite coating with nickel-iron-phosphorus amorphous alloy as a matrix and nano V8C7 as a second phase can be prepared, and the composite coating is free of microcracks on the surface and high in wear and corrosion resistance. The composite electroplating solution is simple in component; environmental hazards of all reagents are low; the process is stable and simple in operation; and the current efficiency is high.

Description

technical field [0001] The invention relates to a composite electroplating solution in the field of material surface treatment, specifically a nickel-iron-phosphorus / nanometer V 8 C 7 Composite plating solution. Background technique [0002] Composite electroplating uses electrochemical methods to co-deposit metals (or alloys) and solid particles (or fibers). There is almost no diffusion phenomenon between the base metal and the added solid particles in the composite coating, so it has the comprehensive properties of the base metal and solid particles. The particularity of amorphous structure (short-range order) makes amorphous materials have excellent mechanical properties, corrosion resistance, and chemical activity compared with traditional metals. However, when the amorphous material is deformed at room temperature, it is easy to induce the local adiabatic shear band to form a single shear crack and suddenly break and fail. On the other hand, the structural character...

Claims

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Application Information

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IPC IPC(8): C25D15/00C25D3/56
Inventor 罗奕兵戴晓元张健
Owner CHANGSHA UNIVERSITY OF SCIENCE AND TECHNOLOGY
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