Catalyst for catalytic combustion and preparation method thereof
A catalytic combustion and catalyst technology, which is applied in the direction of catalyst activation/preparation, combustion methods, physical/chemical process catalysts, etc., can solve the problems of easy cracking of the coating, unfavorable industrialization, peeling, etc., and achieve simple preparation methods, promotion of penetration, Good penetration and wetting properties
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Embodiment 1
[0036] Cordierite pretreatment: completely immerse cordierite honeycomb ceramics in 5wt% nitric acid solution for 1 hour, rinse with deionized water for 3 times after taking it out, put it in an oven at 120°C, and dry it for 10 hours to obtain Surface activated cordierite honeycomb ceramic support.
[0037] Aluminum sol preparation: 20 grams of pseudoboehmite was added to 150 mL of deionized water, and 7 grams of concentrated nitric acid was added dropwise while stirring. After stirring for a certain period of time, heat to 80°C, add nitric acid dropwise until completely peptized, control the pH value of the solution at 2-5, and age for 24 hours to obtain a transparent aluminum sol with a content of 8wt% based on alumina.
[0038] Preparation of silicon-aluminum coating slurry: first mix 90 grams of aluminum sol with 6 grams of fumed silica, add 4 grams of fatty alcohol polyoxyethylene ether (molecular formula is RO(CH 2 CH 2 O) 5 H, where R is C 7 ~C 9 ) after stirring a...
Embodiment 2
[0044] Mix equal volumes of 5 g / L platinum nitrate solution and 5 g / L palladium nitrate solution to prepare the active component solution. Others are the same as embodiment 1. The carrier coated with silicon-aluminum coating and composite coating obtained in this example is ZT2, the final product is CT2, and the loading of platinum and palladium is 0.05wt% of the total weight of the catalyst.
Embodiment 3
[0046] Cordierite pretreatment: with embodiment 1.
[0047] Aluminum sol is commercially available (solid content is 15%, pH is 3-4).
[0048] Preparation of silicon-aluminum coating slurry: First, mix 87 grams of aluminum sol and 10 grams of fumed silica evenly, add 3 grams of alkylphenol polyoxyethylene ether (molecular formula is RC 6 h 4 O(CH 2 CH 2 O) n H, where R is C 9 ~C 12 , n is 9~12) After stirring and mixing for 30 minutes, the coating liquid can be obtained.
[0049] Composite coating slurry preparation: Add 54 grams of nano-titanium dioxide (50-100nm), 32 grams of fumed silica (10-80nm), and 17.2 grams of nano-cerium oxide into 280ml of carbonic acid solution (0.2mol / L), and stir evenly Finally, add 43 grams of aluminum sol to it, stir and mix for 90 minutes until uniform, add 4.3 grams of alkylphenol polyoxyethylene ether (molecular formula is RC 6 h 4 O(CH 2 CH 2 O) n H, where R is C 9 ~C 12 , n is 9~12), and then stir and mix for 30 minutes to ob...
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