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Method for microporous treatment of metal surface

A metal surface and microporous technology, applied in the field of material processing, can solve the problems of low bonding strength, high cost, uneven and irregular rough surface, etc., and achieve the effect of good order and enlarged pore size

Active Publication Date: 2015-05-06
东莞市慧泽凌化工科技有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The traditional way is to use phosphating and passivation to corrode the metal surface by soaking in chemical solution to achieve the purpose of not only protecting the metal surface but also roughening the surface to improve the bonding strength of the metal and the attachment. The rough surface obtained by this method is uneven and irregular, and is only suitable for relatively rough and simple protection. The bonding strength of the surface attachment of the treated metal is low. There are many types of conventional methods for making micropores to roughen the surface, such as Patents CN102537066A, CN102145331A, CN1584119A, CN101578018A, etc. propose methods such as laser micromachining, assembly coating, and design of rounded corners and undercut embedding, all of which talk about methods of improving the bonding strength of metal surfaces and attachments from various angles. However, These methods have various problems such as complex operation, high cost, and narrow application to varying degrees, which limit their application to a certain extent.

Method used

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  • Method for microporous treatment of metal surface
  • Method for microporous treatment of metal surface
  • Method for microporous treatment of metal surface

Examples

Experimental program
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Effect test

Embodiment 1

[0031]A method for microporous treatment of a metal surface, comprising the following steps: 1) Anodizing: anodizing a pretreated metal substrate to obtain a metal substrate with an anodized film layer on the surface, the metal substrate being aluminum Alloy substrate or aluminum substrate; 2) Removal of anodized film: immerse the metal substrate containing the anodized film layer obtained in step 1) into an etching solution to obtain a metal substrate from which the anodized film layer has been removed. H in etching solution + / OH - The concentration is 0.55~5.5mol / L, the etching solution contains fluoride ions and / or phosphate ions, and the etching solution also contains an aluminum corrosion inhibitor; 3) modified anodic oxidation: the metal obtained in step 2) The substrate is put into an anodic oxidation tank containing sulfuric acid and ammonium chloride for modification treatment to obtain a metal substrate with a modified anodic oxidation film layer; 4) surface adjust...

Embodiment 2

[0040] Adopt the same step in embodiment 1 to process ten aluminum alloy sheets, the difference is: c. anodic oxidation film is anodized, adopt 20g / l sodium hydroxide, 2g / l vinyl thiourea and 2g / l xylitol in Soak for 3 minutes at 40°C, e. During surface adjustment, the phosphoric acid soaking time is extended to 15 minutes. The SU-70 thermal field emission scanning electron microscope was used to observe the surface-treated aluminum sheet, and it was observed that alumina micropores with an average pore diameter of 70 nm were evenly distributed on the surface. Others are the same as Experimental Example 1, which will not be repeated here, and a linear relationship conforming to Y=a*X+b is also obtained.

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Abstract

The invention belongs to the technical field of material treatment and particularly relates to a method for microporous treatment of a metal surface. The method comprises the following steps: (1) performing anodic oxidation on a preprocessed metal base material to obtain a metal base material provided with an anodic oxide film layer on the surface; (2) soaking the metal base material obtained in the step (1) in etching liquor for treatment; (3) putting the metal base material obtained in the step (2) into an anodic oxidation groove with sulfur acid and ammonium chloride for modification treatment; (4) soaking the metal base material obtained in the step (3) in a phosphate anion solution, washing with water, soaking in a washing regulating agent at a room temperature, washing with water, and baking for 0.5-1 hour. The purpose of pore size expansion is achieved in a condition-controllable AAO (anodic aluminum oxide) film production mode, a problem that a conventional pore-forming method cannot obtain ordered controllable micropores is solved, and strict requirements on various aspects of product size, structure and the like are avoided from a macroscopic perspective.

Description

technical field [0001] The invention belongs to the technical field of material processing, in particular to a method for microporous metal surface treatment. Background technique [0002] In the fields of mobile communication equipment, electronic and electrical equipment, automotive machinery, etc., it is often necessary to spray, bond, and inject the metal surface. In order to improve the bonding strength of surface attachments, it is usually necessary to treat the surface, such as common phosphating, Passivation and processing methods such as creating holes and undercuts, in short, all improve the bonding strength of the metal and the attachment by increasing the surface corrosion resistance and roughness. The traditional way is to use phosphating and passivation to corrode the metal surface by soaking in chemical solution to achieve the purpose of not only protecting the metal surface but also roughening the surface to improve the bonding strength of the metal and the a...

Claims

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Application Information

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IPC IPC(8): C23F17/00
Inventor 陆业文吴强张兵金磊
Owner 东莞市慧泽凌化工科技有限公司
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