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Alkali-soluble resin polymer for color light filter and light-sensitive resin composition

An alkali-soluble resin and color filter technology, which is applied in the fields of optical filters, optics, and optomechanical equipment, can solve the problem that color filters cannot meet the development performance and stability at the same time, and achieve good matching, good Effects of storage safety and superior developing performance

Inactive Publication Date: 2015-05-27
BEIJING ETERNAL MATERIAL TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] For this reason, the technical problem to be solved by the present invention is that the alkali-soluble resin used in the color filter in the prior art cannot satisfy the problem of developing performance and stability at the same time, and then provide a kind of alkali-soluble resin with better developing performance and stability polymer;

Method used

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  • Alkali-soluble resin polymer for color light filter and light-sensitive resin composition
  • Alkali-soluble resin polymer for color light filter and light-sensitive resin composition
  • Alkali-soluble resin polymer for color light filter and light-sensitive resin composition

Examples

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Effect test

Synthetic example 1

[0042] Into a 200mL flask, add 10g of monomer M-5400 (Toagosei Co., Ltd.), 20g of monomer M-5700 (Toagosei Co., Ltd.), 35g of benzyl methacrylate, 20g of N-phenylmaleimide, and part of propylene glycol Monomethyl ether acetate, molecular weight regulator (dodecyl mercaptan), under the protection of nitrogen, the system is heated to a predetermined temperature, and under stirring, the azobisisobutyronitrile is dissolved in a constant pressure dropping funnel. The remaining propylene glycol methyl ether acetate solution and 15 g of methacrylic acid were added dropwise into a three-necked flask within 30 minutes, then stirred and reacted at a constant temperature for 3 hours, the temperature was lowered to room temperature, and the solvent was removed to obtain alkali-soluble resins B1-B4 respectively. The weight-average molecular weight and molecular weight distribution of the polymer were measured by GPC, and the acid value was determined by acid-base titration.

[0043] The pr...

Embodiment 1-8

[0057] Taking the alkali-soluble resin polymers B1-B8 synthesized above as examples respectively, the photosensitive resin composition is formulated, and the specific implementation includes the following steps: uniformly dissolving and mixing the components (A)-(F) in a stirrer, controlling The solid content of the system is about 17.5%, and the photoresist is prepared according to the ratio in Table 5. The obtained photosensitive resin compositions were respectively marked as S1-S8, and photolithographic development was carried out to verify the relevant properties of the photosensitive resin compositions.

[0058] The lithographic imaging method using the photosensitive resin composition of the present invention is well known to those skilled in the art.

[0059] The formula (g) of photosensitive composition described in table 5 embodiment 1-8

[0060]

[0061] In the above table, the corresponding specific components are:

[0062] A1: red pigment R254, solid content 2...

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Abstract

The invention belongs to the field of liquid crystal displays, and particularly relates to an alkali-soluble resin polymer for a color light filter and a light-sensitive resin composition. The alkali-soluble resin polymer disclosed by the invention is manly obtained by polymerization of 1,2-phthalic acid mono [2-[(1-oxo-2-allyl)oxygen]ethyl] ester, an unsaturated carboxylic acid or anhydride monomer (b1), an unsaturated carboxylic acid or anhydride monomer (b1) containing hydroxyl, an N-maleimide monomer (b3) and an unsaturated polymeric monomer (b4). According to the alkali-soluble resin polymer provided by the invention, the 1,2-phthalic acid mono [2-[(1-oxo-2-allyl)oxygen]ethyl] ester is selected and added; compared with the polymerized alkali-soluble resin polymer free of the monomer in the prior art, the alkali-soluble resin polymer has the advantages of relatively good storage stability, developing property, solvent resistance, and good matching property with a coloring agent, has low acid value, but has good developing property.

Description

technical field [0001] The invention belongs to the field of liquid crystal displays, and in particular relates to an alkali-soluble resin polymer and a photosensitive resin composition for a color filter. Background technique [0002] In the field of liquid crystal display (LCD), generally, the photosensitive resin composition is coated on the substrate and dried (pre-baked), exposed to ultraviolet rays through a photomask, hardened, and then developed by an alkaline developer to form a pattern. , and finally heat-treated (post-baked). Specifically, hardened films such as red, blue, and green pixels in color filters, resin light-shielding layers, protective films, or interlayer insulating films are all completed using this process. [0003] The color filter is a key device for liquid crystal display to achieve colorization, and the performance of the color photoresist used to prepare the color filter directly affects the display effect of the liquid crystal display. With ...

Claims

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Application Information

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IPC IPC(8): C08F220/18C08F222/16C08F222/40C08F220/06C08F212/08G03F7/027G02B5/20
Inventor 孙绪霞刘永祥朱海龙郭金梁
Owner BEIJING ETERNAL MATERIAL TECH
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