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Fluidized bed technology and fluidized bed system for directly capturing CO2 in mineralized flue gas

A technology of carbon dioxide and fluidized bed, applied in air quality improvement, chemical instruments and methods, separation of dispersed particles, etc., can solve the problems of difficult recovery of chemical reagents, harsh reaction conditions, high raw material prices, etc., and achieve rapid carbonation reaction, equipment Less, the effect of reducing energy consumption

Active Publication Date: 2015-07-08
HUANENG POWER INTERNATIONAL +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, due to the currently developed CO 2 The mineralization process has the disadvantages of long process, low reaction rate, large equipment size, harsh reaction conditions, high energy consumption, difficult recovery of chemical reagents, secondary pollution, etc., and the main researches abroad are suitable for mineralization raw materials such as serpentine, Olivine and other ores are often used as raw materials for handicraft processing in my country, resulting in high raw material prices

Method used

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  • Fluidized bed technology and fluidized bed system for directly capturing CO2 in mineralized flue gas

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Effect test

Embodiment 1

[0039] Fluidized bed process for directly capturing carbon dioxide in mineralized flue gas, using high-calcium fly ash from pulverized coal furnace as raw material, CaO content is about 30%, and the main crystal phase is mullite, quartz and a large amount of glassy amorphous state SiO 2 , D50 is 80 microns, the specific steps are as follows:

[0040] In the first step, after analyzing the gray sample, CaO was found to be CaSiO 3 The form exists, and the reactivity meets the requirements. In order to further improve the reactivity, the fly ash is finely ground to reduce the particle size to D50 of 20 microns. Generally, a dry powder grinder is used for 20 minutes of grinding. Fly ash can be sampled from the ash bin of the power plant with a pneumatic soot blowing system.

[0041] The second step is to open a bypass on the flue after the desulfurization of the power plant to lead a stream of flue gas. First, the pressure is increased to 2bar through the booster, and then adjus...

Embodiment 2

[0045] Fluidized bed process for directly capturing carbon dioxide in mineralized flue gas, using fluidized bed desulfurization fly ash as raw material, CaO content is about 18%, the main crystal phase is a large amount of mullite, amorphous SiO 2 and free CaO, D50 is 40 microns, the specific steps are as follows:

[0046] In the first step, after analyzing the gray sample, it is found that CaO exists in the form of fCaO, and the reactivity meets the requirements without pretreatment. Samples can be delivered from the power plant ash silo using a pneumatic soot blowing system.

[0047] The second step is to open a bypass on the flue after the desulfurization of the power plant to lead a stream of flue gas. First, the pressure is increased to 2bar through the booster, and then adjusted by the temperature and humidity regulator. The temperature is adjusted to 90 degrees Celsius, and the humidity adjustment range 30%.

[0048] In the third step, the flue gas with adjusted tempe...

Embodiment 3

[0051] Fluidized bed process for directly capturing carbon dioxide in mineralized flue gas, using low-calcium fly ash from pulverized coal furnace as raw material, with a CaO content of about 5%, and the main crystal phases are mullite, quartz and a large amount of glass amorphous SiO 2 , D50 is 80 microns, the specific steps are as follows:

[0052] In the first step, after analyzing the gray sample, CaO was found to be CaSiO 3 Alkaline desiliconization is required to meet the requirements of activity and ash-gas ratio. Use 15% NaOH solution to dissolve the fly ash under the condition of 90 degrees and 800 rpm stirring speed, the liquid-solid ratio is 5:1, filter and dry after dissolving for 2 hours to obtain the treated fly ash. In order to further increase the reactivity, the treated fly ash can be heated at 600 degrees for 2 hours.

[0053] The second step is to open a bypass on the desulfurized flue of the power plant to lead a stream of flue gas, first through the boo...

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Abstract

The invention discloses a fluidized bed technology for directly capturing CO2 in mineralized flue gas. In the technology, a high-calcium waste, such as fly ash, carbide slag, steel slag, waste cement and the like, as a raw material. A by-pass is formed on a flue gas discharge pipeline to feed a flue gas flow of which the humidity and the temperature are regulated by a temperature and humidity regulator. In a fluidized bed reactor, the flue gas flow, of which the humidity and the temperature are regulated, is contacted with the high-calcium waste in a co-current flow manner to generate calcium carbonate. After the reaction, a dust-containing gas flow discharged out from the fluidized bed reactor is fed into a cyclone separator for gas-solid separation to obtain a gas flow, wherein the gas flow is fed into the original flue gas discharge pipeline and then is fed into the chimney for being discharged. The invention also provides a fluidized bed system for directly capturing CO2 in the mineralized flue gas. The technology can not only effectively increase the utilization rate of fly ash but also reduce CO2 emission of a power plant, is simple in processes, is convenient to continuously operate, is high in device processing capacity, is small in size and less in occupied area and can be combined with the existing system conveniently. Meanwhile, the decarbonized fly ash does not influence the original use approach of the fly ash from the power plant, thereby achieving a lower decarbonization cost.

Description

technical field [0001] The invention relates to the technical field of flue gas carbon dioxide capture and utilization, in particular to a fluidized bed process and system for directly capturing carbon dioxide in mineralized flue gas. Background technique [0002] The global greenhouse effect caused by the increase in the concentration of greenhouse gases in the atmosphere has caused icebergs to melt, sea levels to rise, species to decrease, and various climate disasters to occur frequently around the world, causing serious economic losses and threatening human survival. carbon dioxide (CO 2 ) as the most important greenhouse gas, its future total control and emission rights allocation have become the focus of international climate negotiations. Governments and energy companies in various countries have paid more and more attention to CO 2 Research on emission control technologies, some countries have taken the lead in starting substantive decarbonization work. With my co...

Claims

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Application Information

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IPC IPC(8): B01D53/83B01D53/62
CPCY02A50/20Y02C20/40
Inventor 王晓龙王金意刘练波牛红伟郜时旺
Owner HUANENG POWER INTERNATIONAL
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