The process of preparing 1, 1, 1, 2, 3, 3-hexafluoro propane with 1, 1, 1, 2, 3, 3-hexafluoro propylene and hydrogen belongs to the field of hydrogenating organic halide to prepare alkane. Compound 1, 1, 1, 2, 3, 3-hexafluoro propylene and hydrogen are made to react in the presence of catalyst comprising one or several of Ni, Cu, Fe, Cr, Zn and Al and one or several of RE metal oxide, transition metal oxide and alkali metal oxide. The preparation process with non-noble metal as the main active components in the catalyst has greatly lowered cost, simple reaction process, high material utilizing rate and no pollution.