Fast adsorbent used for emergency treatment of abrupt environmental pollution, and preparation method and application thereof
An emergency treatment and sudden technology, applied in the field of environmental science, can solve the problems of reducing the adsorption capacity of the adsorbent, and achieve the effect of shortening the adsorption saturation time, wide range of sources, and high practical application value.
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Embodiment 1
[0034] A preparation method of fast adsorbent, comprising the following steps:
[0035] (1) 6g of ferric chloride hexahydrate was dissolved in 15mL of water, and KOH with a mass concentration of 2% was added dropwise to adjust the pH of the solution to 7.5 to obtain a mixed solution;
[0036] (2) 4g of rosin (purchased from Shenzhen Yoshida Chemical Co., Ltd.) was dissolved in 20mL of absolute ethanol and added dropwise to the mixed solution described in step (1) to obtain the mixture;
[0037] (3) At 80°C, volatilize the solvent in the mixture in step (2) to remove 80% of the solvent mass to obtain a thick mixture;
[0038] (4) Heat the thick mixture in step (3) at 350° C. for 10 minutes in an oxygen-free environment, and grind to obtain a powder that is used as a fast adsorbent for emergency treatment of sudden environmental pollution.
[0039]The adsorption equilibrium time of the adsorbent in this example is less than 5 minutes for hexavalent chromium, and the removal cap...
Embodiment 2
[0041] (1) 4.4g of ferrous chloride tetrahydrate was dissolved in 15mL of water, and dripped with ammonia water with a mass concentration of 10% to make the pH of the solution to 8 to obtain a mixed solution;
[0042] (2) 2g of rosin was dissolved in 20mL of absolute ethanol and added dropwise to the mixed solution described in step (1) to obtain the mixture;
[0043] (3) At 85°C, volatilize the solvent in the mixture in step (2) to remove 85% of the solvent mass to obtain a thick mixture;
[0044] (4) Heat the thick mixture in step (3) at 400° C. for 5 minutes in an aerobic environment, and grind to obtain a powder that is used as a fast adsorbent for emergency treatment of sudden environmental pollution.
[0045] The adsorption equilibrium time of the adsorbent in this example is less than 5 minutes for hexavalent chromium, and the removal capacity is 141.2 mg / g; the adsorption equilibrium time for methylene blue is less than 30 minutes, and the removal capacity is 6.9 mg / g....
Embodiment 3
[0047] (1) Dissolve 4.5g of ferric sulfate in 15mL of water, and drop in urea with a mass concentration of 10% to make the pH of the solution to 9 to obtain a mixed solution;
[0048] (2) 6g of rosin was dissolved in 20mL of absolute ethanol and added dropwise to the mixed solution described in step (1) to obtain the mixture;
[0049] (3) At 85°C, volatilize the solvent in the mixture in step (2) to remove 75% of the solvent mass to obtain a thick mixture;
[0050] (4) Heat the thick mixture in step (3) at 350° C. for 8 minutes in an aerobic environment, and grind to obtain a powder that is used as a fast adsorbent for emergency treatment of sudden environmental pollution.
[0051] The adsorption equilibrium time of the adsorbent in this example is less than 5 minutes for hexavalent chromium, and the removal capacity is 152.3 mg / g; the adsorption equilibrium time for methylene blue is less than 30 minutes, and the removal capacity is 7.6 mg / g. (Experimental conditions: room t...
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