Method for extracting manganese from composite manganese ore composed of multiple phases containing manganese

A composite manganese ore and multi-phase technology, applied in the direction of photography technology, equipment, photography auxiliary technology, etc., can solve the problems of no scientific and reasonable development of new manganese ore resources, no research on manganese ore resources, multi-component components, etc., to achieve power Low consumption, reduced energy consumption, and high reaction efficiency

Active Publication Date: 2015-10-14
CHANGSHA RES INST OF MINING & METALLURGY +1
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0010] From the above analysis of the manganese ore resources, it can be seen that the composite manganese ore contains not only manganese sulfide, manganese carbonate, manganese oxide, and manganese silicate, but also non-metallic elements such as carbon, sulfur, and oxygen. , silicon, and the metal elements ar

Method used

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  • Method for extracting manganese from composite manganese ore composed of multiple phases containing manganese
  • Method for extracting manganese from composite manganese ore composed of multiple phases containing manganese
  • Method for extracting manganese from composite manganese ore composed of multiple phases containing manganese

Examples

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Effect test

Embodiment 1

[0045] like figure 1 As shown, a kind of method for extracting manganese from the composite manganese ore of manganese-containing multi-phase composition, its steps are:

[0046] (1) Dry the composite manganese ore composed of manganese-containing multi-phase composition, and then, after crushing and ball milling, obtain composite mineral material less than 150 meshes, and adopt magnetic separation method to beneficiate the composite manganese concentrate to obtain composite manganese concentrate.

[0047] (2) adding the composite manganese concentrate of manganese-containing multi-phase composition into the dense moving bed, the dense moving bed is equipped with a temperature control system, a gas flow control system and a waste gas absorption system, and in the dense moving bed The direction of the gas flow in the interior is reversed to the direction of the material movement, and then the oxygen-enriched air with a pressure of 0.12Mpa is introduced into the dense moving be...

Embodiment 2

[0052] like figure 1 As shown, a kind of method for extracting manganese from the composite manganese ore of manganese-containing multi-phase composition, its steps are:

[0053] (1) Dry the composite manganese ore containing manganese multi-phase composition, and then, after crushing and ball milling, obtain composite mineral material less than 150 meshes, and adopt magnetic separation method to beneficiate the ore to obtain composite manganese concentrate.

[0054] (2) adding the composite manganese concentrate of manganese-containing multi-phase composition into the dense moving bed, the dense moving bed is equipped with a temperature control system, a gas flow control system and a waste gas absorption system, and in the dense moving bed The direction of the gas flow inside is opposite to the direction of the material movement, and then the pressure is 0.11Mpa oxygen-enriched air into the dense moving bed, and the constant temperature oxidation roasting is carried out at a...

Embodiment 3

[0059] like figure 1 As shown, a kind of method for extracting manganese from the composite manganese ore of manganese-containing multi-phase composition, its steps are:

[0060] (1) Dry the composite manganese ore composed of manganese-containing multi-phase composition, and then, after crushing and ball milling, obtain composite mineral material less than 150 meshes, and adopt magnetic separation method to beneficiate the composite manganese concentrate to obtain composite manganese concentrate.

[0061] (2) adding the composite manganese concentrate of manganese-containing multi-phase composition into the dense moving bed, the dense moving bed is equipped with a temperature control system, a gas flow control system and a waste gas absorption system, and in the dense moving bed The direction of the gas flow in the interior is reversed to the direction of the material movement, and then the oxygen-enriched air with a pressure of 0.11Mpa is introduced into the dense moving be...

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Abstract

The invention discloses a method for extracting manganese from composite manganese ore composed of multiple phases containing manganese. The method provides a new technology for processing novel manganese resources. The method includes the specific steps that the composite manganese ore is smashed and ground, and composite manganese concentrate is obtained through a magnetic separation method; then the composite manganese concentrate is placed in a roasting device, roasting temperature ranges from 200 DEG C to 600 DEG C, roasting time ranges from 1h to 4h, an obtained roasted product is leached through sulfuric acid, the weight ratio of added sulfuric acid to the roasted product is 2-10 to 1, leaching temperature ranges from 30 DEG C to 100 DEG C, leaching time is 30-240 min, filtering is carried out, the leached liquid is deironized, then sodium fluoride is added to remove calcium and magnesium, then co-precipitation is carried out for further impurity removal, the obtained filtered liquid is conveyed into an electrolytic cell to be electrolyzed, and an electrolytic metal manganese product is obtained. The method has the advantages of being high in reaction efficiency, high in speed, capable of reducing energy consumption and saving resources, high in product recovery rate and environmentally friendly.

Description

technical field [0001] The invention relates to a method for extracting metal manganese from manganese ore, in particular to a method for extracting manganese from composite manganese ore composed of manganese-containing multi-phase. Background technique [0002] Electrolytic manganese metal is widely used in metallurgy, medicine, electronics, communications and other fields, and is an indispensable and important substance in modern industry. With the development of science and technology, the application of electrolytic manganese continues to expand, and the market demand increases by about 15% annually. At present, the main method of producing electrolytic manganese metal in my country is to use manganese carbonate ore or sintered manganese ore as the main ore, and use manganese dioxide ore to remove iron to produce electrolytic manganese metal. Due to the limited resources of manganese carbonate ore in China, and the grade is decreasing year by year, coupled with the exi...

Claims

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Application Information

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IPC IPC(8): C22B1/02C22B3/08C22B3/44C25C1/10
Inventor 侯晓川曾赳雄李贺刘继军杨润德易振鸿
Owner CHANGSHA RES INST OF MINING & METALLURGY
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