High-abrasion resistance and high temperature-resistant cable sheath material

A technology of cable sheath and high temperature resistance, which is applied in the direction of insulated cables, cables, circuits, etc., can solve the problems of poor product stability, long service life, short service life, etc., and achieve good stability, long service life, high temperature resistance and The effect of excellent wear resistance

Inactive Publication Date: 2015-11-25
ANHUI HONGHAI CABLE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] Due to its large aspect ratio, carbon nanotubes are the thinnest fiber materials known so far. They have excellent mechanical properties, unique electrical properties, and good high temperature resistance. If this carbon nanotube Tube-modified phenolic resin is made of high-temperature-resistant composite materials. Due to the scale effect of carbon nanotubes, large specific surface area and strong interfacial interaction, the heat generated can be exported through carbon nanotubes at high temperatures, thereby reducing The temperature of the product makes the performance of the phenolic resin / carbon nanotube composite material better than the physical and chemical properties of the same component conventional composite material, but the end of the carbon nanotube in the phenolic resin / carbon nanotube composite material is a region that is easy to undergo chemical reactions , leading to poor product stability and short service life, and with the increase of its content in rubber, this shortcoming is more obvious, resulting in poor product stability and long service life

Method used

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  • High-abrasion resistance and high temperature-resistant cable sheath material

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Effect test

Embodiment 1

[0021] A kind of high abrasion and high temperature resistant cable sheath material proposed by the present invention, its raw material comprises by weight: 25 parts of modified phenolic resins, 35 parts of carboxylated nitrile rubbers, 30 parts of chlorohydrin rubbers, 1,1-bis-( 1.4 parts of tert-butylperoxy)-3,3,5-trimethylcyclohexane, 0.2 parts of sulfur powder, 0.8 parts of accelerator TMTM, 1.2 parts of accelerator CZ, 20 parts of magnesium oxide, furnace carbon black 30 parts, 30 parts of sepiolite powder, 10 parts of calcium silicate, 3 parts of trimellitate (n-octyl-n-decyl ester), 4 parts of epoxy butyl cottonseed oleate, 3 parts of anti-aging agent DFC-343 parts, anti-aging agent MBZ0. 5 copies;

[0022] In the preparation process of the modified phenolic resin, 0.02 parts of carbon nanotubes were dissolved in 2 parts of dimethylformamide by weight, soaked at room temperature for 3 days, ultrasonically treated for 20 minutes, filtered, washed, and sent into 0.05 part...

Embodiment 2

[0024] A kind of high wear-resistant and high-temperature-resistant cable sheath material proposed by the present invention, its raw material comprises by weight: 32 parts of modified phenolic resins, 27 parts of carboxylated nitrile rubber, 45 parts of chlorohydrin rubber, 1,1-bis-( 1 part of tert-butylperoxy)-3,3,5-trimethylcyclohexane, 0.35 parts of sulfur powder, 0.6 parts of accelerator TMTM, 1.4 parts of accelerator CZ, 12 parts of magnesium oxide, furnace carbon black 34 parts, 23 parts of sepiolite powder, 16 parts of calcium silicate, 1.5 parts of tris(n-octyl-n-decyl) trimellitate, 4.8 parts of epoxy butyl cottonseed oleate, 1.8 parts of anti-aging agent DFC-34, anti-aging agent MBZ1. 2 copies;

[0025] In the preparation process of the modified phenolic resin, 0.01 parts of carbon nanotubes were dissolved in 4 parts of dimethylformamide by weight, soaked at room temperature for 1.5 days, ultrasonically treated for 35 minutes, filtered, washed, and sent into 0.03 par...

Embodiment 3

[0027] A kind of high wear-resistant and high-temperature-resistant cable sheath material proposed by the present invention, its raw material comprises by weight: 30 parts of modified phenolic resins, 30 parts of carboxylated nitrile rubber, 40 parts of chlorohydrin rubber, 1,1-bis-( 1.1 parts of tert-butylperoxy)-3,3,5-trimethylcyclohexane, 0.3 parts of sulfur powder, 0.65 parts of accelerator TMTM, 1.32 parts of accelerator CZ, 15 parts of magnesium oxide, furnace carbon black 33 parts, 25 parts of sepiolite powder, 15 parts of calcium silicate, 2 parts of tris(n-octyl-n-decyl) trimellitate, 4.6 parts of epoxy butyl cottonseed oleate, 2 parts of anti-aging agent DFC-342 parts, 1 part of anti-aging agent MBZ ;

[0028] In the preparation process of the modified phenolic resin, 0.015 parts of carbon nanotubes were dissolved in 3.5 parts of dimethylformamide by weight, soaked at room temperature for 2 days, ultrasonically treated for 30 minutes, filtered, washed, and sent into ...

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Abstract

The invention discloses a high-abrasion resistance and high temperature-resistant cable sheath material, which is prepared from the following raw materials in parts by weight: 25 to 35 parts of modified phenolic resin, 25 to 35 parts of carboxylic-acrylonitrile-butadiene rubber, 30 to 50 parts of epichlorohydrin rubber, 0.8 to 1.4 parts of 1,1-bis-( tertiary butyl peroxide)-3,3,5-trimethyl-cyclohexane, 0.2 to 0.4 part of brimstone powder, 0.5 to 0.8 part of accelerator TMTM, 1.2 to 1.5 parts of accelerator CZ, 10 to 20 parts of magnesium oxide, 30 to 35 parts of furnace black, 20 to 30 parts of sea-foam stone powder, 10 to 20 parts of calcium metasilicate, 1 to 3 parts of trimellitic acid-3-(n-octyl n-decyl adipate), 4 to 5 parts of epoxy-cottonseed butyl oleate, 1 to 3 parts of antiager DFC-34 and 0.5 to 1.5 parts of antiager MBZ. The high-abrasion resistance and high temperature-resistant cable sheath material disclosed by the invention has excellent high temperature resistance and abrasion resistance and is high in stability and long in service life.

Description

technical field [0001] The invention relates to the technical field of cable sheaths, in particular to a high wear-resistant and high-temperature resistant cable sheath material. Background technique [0002] With the rapid development of the cable field, the traditional rubber sheath material for cables can no longer meet the requirements of use. Due to its high temperature resistance, chemical corrosion resistance and low cost, phenolic resin is widely used in many fields such as cables, automobiles, transportation, military, etc. Fields, especially in the field of cables, in recent years, with the improvement of human fire prevention awareness and the urgent demand for flame retardant materials, various modified phenolic resins have been developed rapidly. [0003] Due to its large aspect ratio, carbon nanotubes are the thinnest fiber materials known so far. They have excellent mechanical properties, unique electrical properties, and good high temperature resistance. If t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L13/00C08L61/06C08L71/03C08K13/06C08K9/02C08K9/04C08K7/24C08K5/14C08K3/06C08K3/22C08K3/04C08K3/34C08K5/12H01B3/28H01B7/17
Inventor 石学军
Owner ANHUI HONGHAI CABLE
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