Environmentally friendly polyolefin nonwoven fabric multiple times hydrophilic finishing agent

An environmentally friendly, hydrophilic finishing agent technology, applied in textiles and papermaking, fiber processing, etc., can solve problems such as difficult biodegradation

Active Publication Date: 2017-12-05
ANHUI LINGDA CHEM TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the formula design, the effectiveness of hydrophilicity, low irritation and comfort of use are mainly considered, but the environmental friendliness of the raw materials used is not taken into consideration, especially the silicone main chain and carbon contained in the latter formula. — High polymers with carbon backbones, although only low or non-toxic, are difficult to biodegrade

Method used

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  • Environmentally friendly polyolefin nonwoven fabric multiple times hydrophilic finishing agent
  • Environmentally friendly polyolefin nonwoven fabric multiple times hydrophilic finishing agent
  • Environmentally friendly polyolefin nonwoven fabric multiple times hydrophilic finishing agent

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] 1.1. Formula:

[0045] Component (A): Isooctyl polyoxyethylene ether (3) phosphate ammonium salt (molar ratio of monoester and diester is about 1:1): 28%,

[0046] Component (B): diglyceryl laurate diester polyoxyethylene ether (20) ester: 16%,

[0047] Component (C): 3-{N-(2-lauroyloxyethyl)-N,N-dimethylammonium}-2-hydroxypropyl acidic phosphate sodium betaine: 12%,

[0048] Component (D): polycondensate of dimer acid / mono-oleic acid polyoxyethylene ether (40) (m 2 ≈20, degree of condensation n 2 ≈5): 24%,

[0049] Additional water: 20%;

[0050] 1.2, the preparation of component (D):

[0051] a. Preparation of oleic acid monoglyceride polyoxyethylene ether by ethylene oxide addition polymerization method: add 354 kg of oleic acid monoglyceride and 0.7 kg of potassium hydroxide into the reaction kettle, stir and heat to 130-150 °C, and then vacuumize To -0.08~-0.09MPa, dehydrate for 20 minutes, close the vacuum valve, fill with nitrogen to 0.06MPa, then evacuate ...

Embodiment 2

[0056] 2.1. Formula:

[0057] Component (A): Isomerized tridecyl polyoxyethylene ether (5) phosphate ammonium salt (mono-diester molar ratio about 1:1): 28%,

[0058] Component (B): Dipolyglycerol diester polyoxyethylene ether (30) ester: 16%,

[0059] Component (C): 3-{N-(3-oleoyloxy-2-hydroxypropyl)-N,N-dimethylammonium}-2-hydroxypropyl acidic phosphate sodium betaine: 12% ,

[0060] Component (D): dimer acid / polyoxyethylene ether (25) condensation polymer (m 1 ≈25, degree of condensation n 1 ≈9): 24%,

[0061] Additional water: 20%;

[0062] 2.2, the preparation of component (D):

[0063] a. Preparation of polyoxyethylene ether dimer ester by addition polymerization of ethylene oxide: Add 565kg of dimer acid and 2.0kg of potassium hydroxide to the reaction kettle, stir and heat to 150-170°C, then vacuumize to -0.08 ~-0.09MPa, dehydrate for 20 minutes, close the vacuum valve, fill nitrogen to 0.06MPa, then vacuumize to -0.08MPa, fill nitrogen, repeat 3 times in total,...

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Abstract

The invention relates to an environment-friendly multi-time hydrophilic finishing agent for a polyolefin non-woven fabric. The environment-friendly multi-time hydrophilic finishing agent is characterized by containing (A) 25 to 45 percent of phosphate anionic / nonionic wetting penetrant, (B) 10 to 30 percent of gemini nonionic surfactant, (C) 15 to 25 percent of hydroxyl phosphate betaine ampholytic surfactant and (D) 20 to 40 percent of polymer nonionic surfactant. The environment-friendly multi-time hydrophilic finishing agent disclosed by the invention is prepared from a vegetable oil derivative serving a hydrophobic group main raw material, is simpler in preparation process, high in utilization rate of atoms, free from of toxic or harmful intermediate and little in adverse influence on environment, and has no stimulation on the skin in the use process; after being discarded, the environment-friendly multi-time hydrophilic finishing agent is easily biologically degraded under natural conditions and has small pollution to the environment, so the environment-friendly multi-time hydrophilic finishing agent is an environment-friendly hydrophilic agent; due to a synergistic effect of anionic, ampholytic, gemini and polymer type surfactants, the finished polyolefin non-woven fabric is enabled to have better instantaneity and more excellent multi-time water permeability.

Description

technical field [0001] The invention relates to an auxiliary agent used in the processing of disposable sanitary products, in particular to an environment-friendly polyolefin nonwoven fabric multiple times hydrophilic finishing agent. Background technique [0002] The invention and wide application of disposable medical, health care and sanitary products have brought huge benefits to human life quality and social development, and also brought people a new way of life. Absorbent disposable sanitary products, including feminine hygiene products, baby diapers, adult incontinence products, wet wipes, pet pads and other sanitary products, have continued to grow in my country's market size in recent years, from 40 billion yuan in 2010 to 621 in 2013 billion, with an average annual growth rate greater than 13%. [0003] Currently commonly used polyolefin nonwovens include polypropylene and polyethylene / polypropylene composite fiber nonwovens, which are widely used in medical and he...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06M13/463D06M13/295D06M15/53D06M101/20
CPCD06M13/295D06M13/463D06M15/53D06M2101/20
Inventor 蒋国忠张立军王力军蒋红霞刘秀伟蒋韶贤李昳邓希平
Owner ANHUI LINGDA CHEM TECH
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